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Preparation method, material and application of porous polymer

A porous polymer and polymer technology, applied in the field of polymer materials, can solve the problems of high production cost of porous materials, complex synthesis process, etc., and achieve the effects of reducing process complexity, simple synthesis method and mild reaction conditions

Active Publication Date: 2014-12-10
武汉华科中英纳米科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Aiming at the above defects or improvement needs of the prior art, the present invention provides a preparation method, material and application of a porous polymer. complex technical issues

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  • Preparation method, material and application of porous polymer
  • Preparation method, material and application of porous polymer
  • Preparation method, material and application of porous polymer

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preparation example Construction

[0061] The preparation method of porous polymer provided by the invention comprises the following steps:

[0062] (1) Preparation of raw material mixture: use aromatic compounds, their mixtures, their polymers and / or their polymer mixtures as raw materials, and uniformly disperse the raw materials in a crosslinking agent and solvent to obtain a raw material mixture. The raw material concentration is between 0.01g / ml and 10g / ml. The crosslinking agent and solvent is a mixture of one or more dihalogen substituted alkanes.

[0063] Different aromatic compounds or their polymers are used to obtain organic porous polymer materials containing different functional groups, and the content of the functional groups is regulated by changing the ratio of the various aromatic compounds or their polymers used.

[0064] (2) Preparation of porous polymer: add a catalyst to the raw material mixture obtained in step (1), and Friedel-Crafts reaction occurs to obtain a crude product through hype...

Embodiment 1

[0075] A method for preparing a porous polymer, comprising the steps of:

[0076] (1) Preparation of raw material mixture: use benzene as raw material, dichloromethane as cross-linking agent and solvent, under nitrogen protection, add raw materials and cross-linking agent and solvent in a three-necked flask equipped with a reflux condenser and a thermometer, and magnetically stir After 0.2 hours, a raw material mixture was obtained with a raw material concentration of 0.095 g / ml.

[0077] (2) Preparation of porous polymer: take anhydrous aluminum trichloride as a catalyst, add the catalyst to the raw material mixed solution obtained in step (1), so that the ratio of the molar number of benzene rings in the catalyst to the raw material is 2:1, and Friedel-Crafts reaction, hypercrosslinking to obtain the crude product.

[0078] Keep stirring continuously during the Friedel-Crafts reaction, and control the temperature after adding the catalyst. The specific process is: raise the...

Embodiment 2

[0084] A method for preparing a porous polymer, comprising the steps of:

[0085] (1) Preparation of raw material mixed solution: use biphenyl as raw material, dichloromethane as crosslinking agent and solvent, under nitrogen protection, add raw materials and crosslinking agent and solvent in a three-necked flask equipped with a reflux condenser and a thermometer, and magnetically Stir for 0.2 hours to obtain a raw material mixture with a raw material concentration of 0.095 g / ml.

[0086] (2) Preparation of porous polymer: take anhydrous aluminum trichloride as a catalyst, and then add the catalyst in the raw material mixed solution obtained in step (1), so that the ratio of benzene ring moles in the catalyst and the raw material is 2:1, A Friedel-Crafts reaction occurs, and the crude product is obtained by hypercrosslinking.

[0087] Keep stirring continuously during the Friedel-Crafts reaction, and control the temperature after adding the catalyst. The specific process is: ...

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Abstract

The invention discloses a preparation method, a material and an application of a porous polymer. The preparation method comprises the following steps: (1) evenly dispersing the raw material (aromatic compounds, mixtures of the aromatic compounds, polymers of the aromatic compounds and / or mixtures of the polymers) into a crosslinking agent and solvent, so as to obtain a raw material mixed solution, wherein the crosslinking agent solvent is one or more of alkane dihalides; (2) adding a catalyst, carrying out Friedel-Craft reaction, and carrying out super-crosslinking, so as to obtain a crude product; and (3) washing and extracting a filter cake which is obtained after the coarse product is filtered, removing a catalyst, and drying, so as to obtain a porous polymer. The preparation method disclosed by the invention is simple in process, uses easily available raw materials, the prepared porous polymer is adjustable in pore size and specific surface area, has low cost and good adaptability, and can be used as a catalyst carrier, a separation membrane, a gas storage material or an ion adsorbing material, especially, can be used as materials for storing hydrogen and capturing carbon dioxide or methane storage materials.

Description

technical field [0001] The invention belongs to the field of polymer materials, and more specifically relates to a preparation method, material and application of a porous polymer. Background technique [0002] In recent years, organic porous polymer materials (microporous organic polymers, MOPs) have been widely used in the fields of adsorption and separation, heterogeneous catalysis, gas storage, photoelectricity, drug release, biosensing, etc., and have received great attention from researchers at home and abroad. big concern. Compared with traditional activated carbon-like and zeolite-like porous materials, MOPs show advantages such as high specific surface area, high chemical and physical stability, low framework density and diverse synthesis. From the synthesis method, MOPs can be mainly divided into: Polymers of Intrinsic Microporosity (PIMs), Covalent-Organic Frameworks (COFs), Conjugated Microporous Polymers (Conjugated Microporous Polymers). , CMPs) and hypercros...

Claims

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Application Information

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IPC IPC(8): C08G61/02C08J9/28
Inventor 谭必恩王绍磊张承昕刘彩娥舒裕谭良骁
Owner 武汉华科中英纳米科技有限公司
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