A kind of preparation method of carbon material for supercapacitor

A technology of supercapacitors and carbon aerogels, applied in the manufacture of hybrid/electric double layer capacitors, hybrid capacitor electrodes, etc., can solve the problems of excessive use of organic chemical reagents, small specific volume of electrode materials, and no practical application value, etc., to achieve Easy to prepare in large quantities and industrialized production, increase the specific volume, the effect of large specific volume

Active Publication Date: 2017-02-08
JIANGSU SUPERBIO LIFE SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It can be seen that the current preparation of carbon aerogels has many problems such as the use of organic chemical reagents, heavy pollution, high production costs, and complicated processes. If some cheap biomass can be used as raw materials and a clean and simple process can be used to prepare carbon aerogels Rubber materials, not only can reduce production costs, but also meet the sustainable development strategy of environmental protection
Moreover, carbon aerogels that only contain carbon have a small specific capacity (usually less than 200 F / g) as electrode materials for supercapacitors, and have basically no practical application value.

Method used

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  • A kind of preparation method of carbon material for supercapacitor
  • A kind of preparation method of carbon material for supercapacitor
  • A kind of preparation method of carbon material for supercapacitor

Examples

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Effect test

Embodiment 1

[0022] A kind of preparation method of carbon material for supercapacitor is characterized in that, comprises following operation:

[0023] ①Water heat: Make the volume 3cm 3 The radish pieces are completely immersed in a reaction kettle filled with 30ml of 10% thiourea solution in mass percent concentration, the reaction kettle is sealed and placed in an oven at 200°C for 6 hours, then cooled to room temperature, and the block water is taken out. gel;

[0024] ②Removal of impurities: Soak the massive hydrogel obtained in ① in absolute ethanol and pure water for 3 times, each time for 8 hours, to remove impurities;

[0025] ③Freeze-drying: pre-freeze the block hydrogel obtained in ② at -50°C for 6 hours, then freeze-dry at -60°C and 1Pa pressure for 48 hours to obtain block airgel;

[0026] ④Calcination: Calcinate the bulk airgel obtained in ③at 850°C for 1.5 hours in an argon atmosphere, and grind the airgel into gel powder after cooling;

[0027] ⑤Activation: Mix the gel ...

Embodiment 2

[0030] A kind of preparation method of carbon material for supercapacitor is characterized in that, comprises following operation:

[0031] ①Water heat: Make the volume 4cm 3 The chunky pomelo peels are completely immersed in a reaction kettle filled with 60ml of 5% thiourea solution by mass percentage, the reaction kettle is sealed and placed in an oven at 220°C for 4 hours, then cooled to room temperature, and the block is taken out. shaped hydrogel;

[0032] ②Removal of impurities: Soak the massive hydrogel obtained in ① in absolute ethanol and pure water for 3 times, each time for 8 hours, to remove impurities;

[0033] ③Freeze-drying: pre-freeze the block hydrogel obtained in ② at -50°C for 6 hours, then freeze-dry at -60°C and 1Pa pressure for 48 hours to obtain block airgel;

[0034] ④Calcination: calcining the massive airgel obtained in ③at 800°C for 2 hours in an argon atmosphere, and grinding the airgel into gel powder after cooling;

[0035] ⑤Activation: Mix the ...

Embodiment 3

[0038] A kind of preparation method of carbon material for supercapacitor is characterized in that, comprises following operation:

[0039] ①Water heat: Make the volume 6cm 3 The sweet potato pieces are completely immersed in a reaction kettle filled with 30ml of 15% thiourea solution by mass percentage, the reaction kettle is sealed and placed in an oven at 190°C for 8 hours, then cooled to room temperature, and the block water is taken out. gel;

[0040] ②Removal of impurities: Soak the massive hydrogel obtained in ① in absolute ethanol and pure water for 3 times, each time for 8 hours, to remove impurities;

[0041] ③Freeze-drying: pre-freeze the block hydrogel obtained in ② at -50°C for 6 hours, then freeze-dry at -60°C and 1Pa pressure for 48 hours to obtain block airgel;

[0042] ④Calcination: calcining the bulk airgel obtained in ③at 900°C for 1 hour in an argon atmosphere, and grinding the airgel into gel powder after cooling;

[0043] ⑤Activation: Mix the gel powder ...

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Abstract

The invention provides a preparation method of a supercapacitor carbon material. In the method, cheap and easily available biomass such as pericarp, vegetables and the like is taken as raw materials, and the supercapacitor carbon material is obtained through steps including thiourea hydro-thermal processing, impurity removing processing, freeze drying processing, calcining processing, alkali / microwave activation processing and the like. The material has the characteristics of a layered structure and a large specific surface area. Since a thiourea hydro-thermal step is carried out in a preparation process, S and N in thiourea molecules are introduced, the specific volume of the material is effectively improved, and an electrode prepared by use of the material has the advantages of large specific volume and good circulating stability. According to the invention, wastes such as watermelon peel, shaddock peel and the like and cheap vegetables such as sweet potatoes, radishes and the like are taken as the raw materials, such that the production cost is decreased, and the preparation method also accords with the strategy of sustainable development for environmental protection and has an important popularization value.

Description

technical field [0001] The invention belongs to the field of supercapacitor electrode materials, and in particular relates to a preparation method of a carbon material for supercapacitors. Background technique [0002] Supercapacitors are a new type of green energy storage device between batteries and traditional capacitors. They have the advantages of high power density, short charging time, and long cycle life. They are widely used as driving power for electric vehicles and backup power for mobile communication equipment. Wait. The performance of supercapacitors mainly depends on their electrode materials. Commonly used supercapacitor electrode materials mainly include carbon materials, transition metal (hydr) oxides, and some conductive polymers, among which carbon materials have attracted extensive attention because of their good charge-discharge stability. At present, the carbon materials used in supercapacitors mainly consist of activated carbon, carbon nanotubes, ca...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01G11/86H01G11/26
CPCY02E60/13
Inventor 雷惊雷李凌杰徐静张洁葛梦琪黄涛潘复生
Owner JIANGSU SUPERBIO LIFE SCI CO LTD
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