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A method for dephosphorizing molten steel

A molten steel and dephosphorization technology, applied in the field of metallurgy, can solve the problems of terminal phosphorus control, ladle blasting, and affecting production efficiency, so as to improve efficiency, reduce dephosphorization pressure, and reduce the consumption of auxiliary materials.

Active Publication Date: 2016-08-10
PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method has the following disadvantages: it is necessary to have strict requirements on the control of the oxygen content of molten steel. If the oxygen content of the tapping is too high, the phenomenon of "blasting" of the ladle may occur during the tapping process or after the tapping is completed, and there is a certain potential safety hazard. The deep dephosphorization agent must be added to the ladle before and after, and the molten steel should be weakly deoxidized. The process takes too long and affects the production efficiency.
This method has the following disadvantages: when the phosphorus content in the furnace is high, it is difficult to control the final phosphorus within 0.006% by weight by using the single slag method, and it is difficult to control the amount of slag in the tapping process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] This embodiment is used to illustrate the method for dephosphorizing molten steel of the present invention.

[0031] Control the end point of 200t converter smelting so that the phosphorus content of the obtained molten steel is 0.012% by weight, the carbon content is 0.05% by weight, and the temperature is 1640°C. Tap the obtained molten steel into the ladle, and add 6kg of active lime per ton of steel (purchased from Sichuan Panyan Technology Co., Ltd., the content of CaO in the active lime is ≥90% by weight, and the particle size of the active lime is 20mm). After tapping, add 1.5kg of fluorite per ton of steel to the slag surface of the ladle ( Purchased from Sichuan Panyan Technology Co., Ltd.), the oxygen activity of molten steel measured after tapping was 332ppm, and pre-refined after the furnace, and the intensity of argon blowing at the bottom of the ladle was 0.001m 3 / (t steel min), the pre-refining time is 8min.

[0032] The pre-refined molten steel is dire...

Embodiment 2

[0034] This embodiment is used to illustrate the method for dephosphorizing molten steel of the present invention.

[0035] Control the end point of 200t converter smelting so that the phosphorus content of the obtained molten steel is 0.010% by weight, the carbon content is 0.04% by weight, and the temperature is 1660°C. Tap the obtained molten steel into the ladle, and add 7kg of active lime per ton of steel (purchased from Sichuan Panyan Technology Co., Ltd., the content of CaO in the active lime is ≥90% by weight, and the particle size of the active lime is 15mm). After tapping, 2kg of fluorite per ton of steel (purchased In Sichuan Panyan Technology Co., Ltd.), the oxygen activity of molten steel measured after tapping was 345ppm, and it was pre-refined after the furnace, and the intensity of argon blowing at the bottom of the ladle was 0.003m 3 / (t steel min), the pre-refining time is 10min.

[0036] The pre-refined molten steel is directly sent to RH for vacuum treatment...

Embodiment 3

[0038] This embodiment is used to illustrate the method for dephosphorizing molten steel of the present invention.

[0039] Control the end point of 200t converter smelting so that the phosphorus content of the obtained molten steel is 0.011% by weight, the carbon content is 0.03% by weight, and the temperature is 1680°C. 8 kg of active lime per ton of steel (purchased from Sichuan Panyan Technology Co., Ltd., the content of CaO in the active lime is ≥ 90% by weight, and the particle size of the active lime is 10 mm). After tapping, add 2.5 kg of fluorite per ton of steel to the slag surface of the ladle ( Purchased from Sichuan Panyan Technology Co., Ltd.), the oxygen activity of molten steel measured after tapping was 389ppm, and pre-refined after the furnace, and the intensity of argon blowing at the bottom of the ladle was 0.005m 3 / (t steel min), the pre-refining time is 12min.

[0040] The pre-refined molten steel is directly sent to RH for vacuum treatment. After circu...

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Abstract

The invention discloses a method for dephosphorizing molten steel, wherein the method includes: (1) controlling the end point of converter smelting, so that the phosphorus content in the obtained molten steel is not higher than 0.012% by weight, and the carbon content is 0.03-0.05% by weight %, the temperature is 1640-1680°C; (2) tap the molten steel obtained in step (1) into a ladle, add a pre-refining agent to the ladle, and carry out argon blowing refining, wherein the pre-refining agent includes active lime and fluorite; (3) The molten steel obtained after argon blowing and refining is subjected to RH vacuum treatment, wherein a dephosphorizing agent is added during the RH vacuum treatment, and the dephosphorizing agent includes active lime and iron oxide scale. The method can achieve the purpose of dephosphorization of molten steel, so that the phosphorus content in the treated molten steel is not higher than 0.007% by weight.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, and in particular relates to a method for dephosphorizing molten steel. Background technique [0002] Phosphorus is a harmful element in most steels. It has adverse effects on the surface quality, tensile strength, and stress corrosion resistance of steel. It is easy to segregate at grain boundaries, resulting in "cold and brittle" steel, which significantly reduces the low temperature impact toughness. In recent years, as users have increasingly stringent requirements for steel performance, higher requirements have been put forward for the phosphorus content of many steel types; Steel and tinplate require phosphorus to be less than 0.010% by weight; some aviation, atomic energy, and corrosion-resistant pipeline steels require finished phosphorus to be less than 0.005% by weight. Therefore, how to reduce the phosphorus content in molten steel has become a difficult problem in the production ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C21C7/064C21C7/10
Inventor 陈均杨晓东曾建华梁新腾陈路杨森祥喻林黄生权张彦恒
Owner PANZHIHUA IRON & STEEL RES INST OF PANGANG GROUP
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