A hydrothermal decomposition catalyst and a hydrothermal decomposition method using the catalyst
A technology for hydrothermal decomposition and catalyst, applied in the field of coal chemical industry, can solve the problems of long process flow, complicated preparation process and high requirement for condition control, and achieve the effects of good dispersibility, low catalytic cost and good catalytic effect
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Embodiment 1
[0026] In this example, the CDS-100 type desulfurizer from Sanju Environmental Protection Company is selected as the desulfurizer in the petroleum refining process, and the temperature is 400-450°C, the pressure is 6.0MPa, and the gaseous space velocity is 1000-1200h -1 Desulfurization treatment is carried out under certain conditions, and the waste desulfurizer after desulfurization is used as a medium-low temperature coal tar hydrothermal decomposition catalyst A; among them, the active component of the CDS-100 desulfurizer is amorphous iron oxyhydroxide, and the active component is amorphous The content of iron oxyhydroxide is 65-75wt%.
[0027] The method for carrying out hydrothermal decomposition using the above-mentioned amorphous iron oxyhydroxide desulfurizer waste agent as a hydrothermal decomposition catalyst comprises the following steps:
[0028] (1) 1000g of low-temperature coal tar and catalyst A with a mass of 5g of iron element are subjected to hydrogenation h...
Embodiment 2
[0032] In this example, the JX-7A desulfurizer from Sanju Environmental Protection Company was selected to operate at a temperature of 280°C, a pressure of 7.5, and a gaseous space velocity of 1600~1800h -1 The desulfurization treatment is carried out under the condition that the aspect ratio is 3, and the desulfurized desulfurizer waste agent is used as medium and low temperature coal tar hydrothermal decomposition catalyst B; wherein, the active component of the JX-7A type desulfurizer is ferric oxide, The content of the active component ferric oxide is 75-85wt%.
[0033] Use above-mentioned hydrothermal decomposition catalyst B to carry out the method for hydrothermal decomposition, comprise the steps:
[0034] (1) Combine 1,000g of low-temperature coal tar heavy oil with fractions below 350°C cut off and Catalyst B with a mass of 10g of iron element. The initial pressure of hydrogen is 5-7MPa, the reaction temperature is 350-370°C, and the volume ratio of hydrogen to oil i...
Embodiment 3
[0038] In this example, the desulfurizer with ferric oxide as the active component is selected at a temperature of 430°C, a pressure of normal pressure, and a gaseous space velocity of 2100~2300h -1 Desulfurization treatment is carried out under the condition that the aspect ratio is 5, and the desulfurized desulfurizer waste agent after desulfurization is used as a medium-low temperature coal tar hydrothermal decomposition catalyst C; wherein, the content of the active component ferric oxide in the desulfurizer is 95~100wt %.
[0039] The method for carrying out hydrothermal decomposition using the above-mentioned hydrothermal decomposition catalyst C comprises the following steps:
[0040] (1) Take 1000g of medium-temperature coal tar heavy oil with fractions below 350°C cut off, and the catalyst C with an iron element content of 15g, at an initial hydrogen pressure of 7-9MPa, and a reaction temperature of 370-390°C, hydrogen, oil Under the condition that volume ratio is 70...
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