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A hydrothermal decomposition catalyst and a hydrothermal decomposition method using the catalyst

A technology for hydrothermal decomposition and catalyst, applied in the field of coal chemical industry, can solve the problems of long process flow, complicated preparation process and high requirement for condition control, and achieve the effects of good dispersibility, low catalytic cost and good catalytic effect

Active Publication Date: 2016-08-03
BEIJING SJ ENVIRONMENTAL PROTECTION & NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is to solve the problem that the preparation of the coal tar hydrogenation reaction catalyst in the prior art requires the active components to be loaded on the porous carrier by the vacuum impregnation method, and the preparation process is complex, the process is long, and the condition control requirements are high. problem, and further provide a method of using iron-based waste desulfurizer as a catalyst for coal tar hydrogenation reaction and using the catalyst to carry out coal tar hydrogenation reaction

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] In this example, the CDS-100 type desulfurizer from Sanju Environmental Protection Company is selected as the desulfurizer in the petroleum refining process, and the temperature is 400-450°C, the pressure is 6.0MPa, and the gaseous space velocity is 1000-1200h -1 Desulfurization treatment is carried out under certain conditions, and the waste desulfurizer after desulfurization is used as a medium-low temperature coal tar hydrothermal decomposition catalyst A; among them, the active component of the CDS-100 desulfurizer is amorphous iron oxyhydroxide, and the active component is amorphous The content of iron oxyhydroxide is 65-75wt%.

[0027] The method for carrying out hydrothermal decomposition using the above-mentioned amorphous iron oxyhydroxide desulfurizer waste agent as a hydrothermal decomposition catalyst comprises the following steps:

[0028] (1) 1000g of low-temperature coal tar and catalyst A with a mass of 5g of iron element are subjected to hydrogenation h...

Embodiment 2

[0032] In this example, the JX-7A desulfurizer from Sanju Environmental Protection Company was selected to operate at a temperature of 280°C, a pressure of 7.5, and a gaseous space velocity of 1600~1800h -1 The desulfurization treatment is carried out under the condition that the aspect ratio is 3, and the desulfurized desulfurizer waste agent is used as medium and low temperature coal tar hydrothermal decomposition catalyst B; wherein, the active component of the JX-7A type desulfurizer is ferric oxide, The content of the active component ferric oxide is 75-85wt%.

[0033] Use above-mentioned hydrothermal decomposition catalyst B to carry out the method for hydrothermal decomposition, comprise the steps:

[0034] (1) Combine 1,000g of low-temperature coal tar heavy oil with fractions below 350°C cut off and Catalyst B with a mass of 10g of iron element. The initial pressure of hydrogen is 5-7MPa, the reaction temperature is 350-370°C, and the volume ratio of hydrogen to oil i...

Embodiment 3

[0038] In this example, the desulfurizer with ferric oxide as the active component is selected at a temperature of 430°C, a pressure of normal pressure, and a gaseous space velocity of 2100~2300h -1 Desulfurization treatment is carried out under the condition that the aspect ratio is 5, and the desulfurized desulfurizer waste agent after desulfurization is used as a medium-low temperature coal tar hydrothermal decomposition catalyst C; wherein, the content of the active component ferric oxide in the desulfurizer is 95~100wt %.

[0039] The method for carrying out hydrothermal decomposition using the above-mentioned hydrothermal decomposition catalyst C comprises the following steps:

[0040] (1) Take 1000g of medium-temperature coal tar heavy oil with fractions below 350°C cut off, and the catalyst C with an iron element content of 15g, at an initial hydrogen pressure of 7-9MPa, and a reaction temperature of 370-390°C, hydrogen, oil Under the condition that volume ratio is 70...

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Abstract

The invention provides a hydropyrolysis catalyst for medium / low-temperature coal tar. The catalyst is an iron-sulfur serial waste desulfurizer obtained by employing an iron serial desulfurizer to perform desulphurization, and the content of the active composition in the iron serial desulfurizer is 65-100 wt%. By employing the hydropyrolysis catalyst for medium / low-temperature coal tar, preparation of the coal-tar hydropyrolysis catalyst is saved, the problems are solved that the preparation of the coal-tar hydropyrolysis catalyst is complicate in process, long in process and high in condition control requirements in the prior art, also the waste desulfurizer is effectively reasonably utilized, and the hydropyrolysis catalyst has the advantages of low catalysis cost, good catalytic effect and resource cycle utilization.

Description

technical field [0001] The invention relates to a hydrothermolysis catalyst and a hydrothermolysis method using the catalyst, in particular to a hydrothermolysis catalyst using the iron-based waste desulfurizer in the petroleum refining process as a medium-low temperature coal tar and using the hydrothermolysis catalyst The invention discloses a hydrogenation thermal decomposition method of a catalyst, which belongs to the field of coal chemical industry. Background technique [0002] Coal tar is a black or dark brown viscous liquid with a pungent odor. It is a liquid product produced during the pyrolysis of coal. It can be divided into high-temperature tar (1000°C) and medium-temperature tar ( 600~800℃) and low temperature tar (450~550℃). The relative density of low-temperature coal tar is small, and its composition includes alkanes, olefins and aromatics accounting for about 50%, phenols content up to 30%, and the rest are nitrogen-containing compounds, sulfur-containing ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/745C10G47/06
Inventor 任相坤井口宪二坂脇弘二崔永君
Owner BEIJING SJ ENVIRONMENTAL PROTECTION & NEW MATERIAL CO LTD
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