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A kind of preparation method of water-absorbing anti-fog glass

An anti-fog glass, water absorption technology, applied in the field of automotive glass, can solve the problems of fogging, short service life of anti-fog products, not resistant to wiping, etc., and achieve good anti-fog performance, convenient application, anti-aging and anti-fog performance Effect

Active Publication Date: 2016-03-16
CHERY AUTOMOBILE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The invention designs a preparation method of water-absorbing anti-fog glass, which solves the problem of fogging of automobile glass in an environment with a large temperature and humidity difference, improves driving safety and at the same time saves energy and protects the environment; especially solves the problem of anti-fog products Short service life, not resistant to wiping and need to be used repeatedly

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] This embodiment provides a method for preparing water-absorbent anti-fog glass, comprising the following steps:

[0028] Add 5.5ml of tetraethyl orthosilicate and 2ml of distilled water into 80ml of ethyl acetate, and ultrasonically disperse to obtain a mixed solution. Dissolve 4.5ml of 25wt% saturated ammonia solution in 20ml of ethyl acetate at a speed of 3ml / min Add it into the above mixed solution at a uniform speed, keep the reaction temperature at 23-30°C during the reaction process, and keep ultrasonic action during the reaction process, and the reaction time is 3 hours to obtain nano Silica sol with a particle content of about 2.47wt% and a particle size of 2-20nm.

[0029] Dissolve 2.5g of silica sol in 2.5g of ethyl acetate, add non-ionic surfactant polyoxyethylene alkylphenol ether 0.25g, polyethylene glycol 600 (PEG600) 50mg, polyethylene glycol 400 (PEG400) 1.5 g, after stirring evenly, add 1.7 g of acrylic polyol resin and stir for 30 minutes, then add 2...

Embodiment 2

[0034] This embodiment provides a preparation method for anti-fog glass, comprising the following steps:

[0035] Add 7.5ml of tetraethyl orthosilicate and 4ml of distilled water to 80ml of acetone and mix, ultrasonically disperse to obtain a mixed solution, dissolve 6.5ml of 25wt% saturated ammonia solution in 20ml of acetone, and add it to the above mixing solution at a constant speed of 3ml / min solution, keep the reaction temperature at 23-30°C during the reaction, and keep ultrasonic in the reaction process, and the reaction time is 3 hours to obtain nano Silica sol with a particle content of about 3.27wt% and a particle size of 2-20nm.

[0036] Dissolve 2.5g of silica sol in 2.5g of acetylacetone, add non-ionic surfactant polyoxypropylene glycerol ether 0.25g, polyethylene glycol 600 (PEG600) 50mg, polyethylene glycol 400 (PEG400) 1.5g After stirring evenly, add 1.7g of acrylic polyol resin and stir for 30min, then add 2.8g of curing agent N3300, stir evenly to obtain a...

Embodiment 3

[0041] This embodiment provides a method for preparing an anti-fog composition for glass, comprising the following steps:

[0042] Add 5.5ml of tetraethyl orthosilicate and 4ml of distilled water to 85ml of isobutyl acetate and mix, ultrasonically disperse to obtain a mixed solution, dissolve 4ml, 25wt% saturated ammonia solution in 23ml of isobutyl acetate, at a speed of 3ml / min Add it into the above mixed solution at a uniform speed, keep the reaction temperature at 23-30°C during the reaction, keep ultrasonic during the reaction, and the reaction time is 3 hours to obtain nano Silica sol with a content of about 2.08wt% and a particle size of 2-20nm.

[0043] Dissolve 2.5g of silica sol in 2.5g of isobutyl acetate, add non-ionic surfactant polyoxypropylene glycerol ether 0.25g, polyethylene glycol 600 (PEG600) 50mg, polyethylene glycol 400 (PEG400) 1.5g, stir evenly, add 1.7g of acrylic polyol resin and stir for 30min, add 2.8g of curing agent N3300, stir evenly to obtain ...

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Abstract

The invention relates to a water-absorbing anti-fog glass manufacturing method. The method includes the steps that step 1, after tetraethoxysilane, organic solvent and distilled water are mixed, a basic catalyst is added into the mixture at constant speed under the ultrasonication for reaction, and a nano-silica sol is obtained after a period of ultrasonication; step 2, a surfactant is added into the nano-silica sol obtained in the first step, and the mixture of the surfactant and the nano-silica sol is stirred to be uniform to obtain a nano-silica solvent mixed solution; step 3, resin containing water absorption groups and resin capable of cross-linking and solidifying are added into the nano-silica solvent mixed solution obtained in the second step and the mixture is stirred to be uniform, a curing agent and a flatting agent are added into the mixture and the mixture is stirred to be uniform, and a water-absorbing anti-fog solution is obtained; step 4, the surface of automobile glass is pretreated, degreased and polished physically, washed with tap water and distilled water respectively and dried; step 5, the clean and dry glass surface is plated with a membrane of the water-absorbing anti-fog solution obtained in the third step, and automobile glass with the anti-fog function is obtained.

Description

technical field [0001] The invention belongs to the technical field of automobile glass, in particular to the application field of anti-fog technology of automobile glass, in particular to a preparation method of water-absorbing anti-fog glass. Background technique [0002] In winter or summer rainy days, there is a large temperature difference between the inside and outside of the car. When the temperature of the inner surface of the glass reaches the dew point temperature, water vapor will condense on the glass surface, forming densely packed small water droplets. Due to the existence of these tiny water droplets, light will be refracted and reflected when passing through the glass, which will significantly reduce the light transmittance of the glass, seriously affect the clarity of the driver's sight, and easily lead to traffic accidents. According to professional statistical comparison, the impact of the driver's sight will increase the traffic accident rate by 5 times. ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C17/00
Inventor 洪丽熊建民陈大华
Owner CHERY AUTOMOBILE CO LTD
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