Schiff base mercury metal complexes emitting blue fluorescence and preparation method thereof
A technology of metal complexes and Schiff base mercury, applied in the direction of mercury organic compounds, luminescent materials, chemical instruments and methods, etc., can solve the problems of short life, poor monochromaticity, low luminous efficiency, etc., and achieve high and stable yield Strong, good monochrome performance
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specific Embodiment approach 1
[0026] Embodiment 1: In this embodiment, the blue fluorescent Schiff base mercury metal complex is [pyridine-2-methyleneaniline] HgCl 2 , the molecular formula is C 12 h 10 Cl 2 N 2 Hg, whose structural formula is
[0027]
specific Embodiment approach 2
[0028] Specific embodiment two: In this embodiment, the blue fluorescent Schiff base mercury metal complex is [(4-methylphenyl)-pyridine-2-methyleneamine]HgCl 2 , the molecular formula is C 13 h 12 Cl 2 N 2 Hg, whose structural formula is
[0029]
specific Embodiment approach 3
[0030] Specific embodiment three: the preparation method of the blue fluorescent Schiff base mercury metal complex described in specific embodiment one is carried out according to the following steps:
[0031] 1. Under the condition of nitrogen protection, mix 15-25mg of pyridine-2-methyleneaniline and 25-40mg of HgCl 2 Dissolve in a mixed organic solvent, heat to reflux, and stir for 9 hours to obtain a yellow reaction liquid;
[0032] 2. Filter the product of step 1 while it is hot, and then volatilize at room temperature for 3 to 7 days to obtain [pyridine-2-methyleneaniline] HgCl 2 ;
[0033] The mixed organic solvent used in step 1 is CH 3 OH and CH 2 Cl 2 mixed solution of CH 3 OH and CH 2 Cl 2 The volume ratio is 1:5.
[0034] The reaction equation of the present embodiment is as follows
[0035]
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