Supported metallocene catalyst and preparation method and application thereof
A technology of metallocene catalysts and metallocene compounds, applied in the field of supported metallocene catalysts and their preparation and application, which can solve the problems of easy sticking of polymers, energy consumption, low catalytic activity, low polymerization temperature, etc.
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[0061] The present invention also provides a method for preparing the above-mentioned supported metallocene catalyst. The preparation method includes: ball milling anhydrous magnesium chloride and alkylaluminoxane at a temperature of 15-100°C under the protection of inert gas. After 100 hours, under the protection of inert gas, the carrier is contacted with the first solution for a third time to obtain the carrier after the third contact. The first solution contains the product obtained by ball milling and the first solvent; The first solvent on the carrier; the carrier from which the first solvent has been removed is subjected to a fourth contact with the second solution to obtain the carrier after the fourth contact, the second solution contains the metallocene compound and the second solvent, wherein, The average particle diameter of the carrier is 20-80 microns, the specific surface area is 550-650 square meters / g, the pore volume is 0.4-1.2 ml / g, and the most probable pore ...
Embodiment 1
[0099] This example is used to illustrate the supported metallocene catalyst and its preparation method according to the present invention.
[0100] 2.0 grams of triblock copolymer polyethylene oxide-polypropylene oxide-polyethylene oxide (Aldrich, P123) and 15 grams of N,N-dimethylformamide (DMF) were added to 11.2 grams of 37% by weight In a solution of hydrochloric acid and 64ml of water (pH=4.4), stir at 40°C until the polyoxyethylene-polyoxypropylene-polyoxyethylene is completely dissolved, and then 4.45g of ethyl orthosilicate is added to the above solution, 40 After stirring for 1 hour at ℃, add 1 gram of industrial 955 silica gel. After stirring for 0.3 hours at 40℃, transfer the solution to a reactor lined with polytetrafluoroethylene, crystallize in an oven at 150℃ for 24 hours and then filter. , Washed with distilled water and dried to obtain spherical mesoporous silica raw powder.
[0101] The raw spherical mesoporous silica powder obtained in the previous step is calc...
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