Low-eradiation coated glass available for heat treatment and sandwich glass products thereof

A low-emissivity coating and glass technology, which is applied in the field of single silver-coated laminated glass, low-emission coated glass and its laminated glass products, can solve problems such as not suitable for oxygen atom diffusion, achieve qualified thermal stability, improve mechanical stability, The effect of high refractive index

Active Publication Date: 2015-04-15
FUYAO GLASS IND GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Although ZrO 2 It is a well-known material in the field of sputter coating and low-e thin film, but according to the general understanding of those skilled in the art, ZrO 2 It is an excellent oxygen ion conductor, not suitable as the upper dielectric layer of the low-e film layer to block the diffusion of oxygen atoms

Method used

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  • Low-eradiation coated glass available for heat treatment and sandwich glass products thereof
  • Low-eradiation coated glass available for heat treatment and sandwich glass products thereof
  • Low-eradiation coated glass available for heat treatment and sandwich glass products thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1～5

[0040] Sodium calcium silicate float white glass or green glass with a thickness of 2.1 mm is used as the substrate. After cutting, edging, washing and drying, it enters the magnetron sputtering coating line for deposition, and the background vacuum is high. at 9×10 -4 Pa. According to the different film structures shown in Table 2, they were sequentially deposited on the glass. Si 3 N 4 Using SiAl alloy target in Ar / N 2 Intermediate frequency reactive sputtering deposition in a mixed atmosphere with a flow ratio of 1 / 1, ZnSnOx using Zn50Sn50 alloy target in Ar / O 2 Intermediate frequency reactive sputtering in a mixed atmosphere with a flow ratio of 1 / 1, ZnO is a Zn98Al2 alloy target in Ar / O 2 Intermediate frequency reactive sputtering deposition in a mixed atmosphere with a flow ratio of 2 / 3, Ag and Ti were deposited by DC sputtering in an Ar atmosphere, ZrO 2 Using Zr metal target in Ar / O 2 Intermediate frequency reactive sputtering deposition in a mixed atmosphere wi...

Embodiment 6～9

[0052] Sodium calcium silicate float white glass or green glass with a thickness of 2.1 mm is used as the substrate. After cutting, edging, washing and drying, it enters the magnetron sputtering coating line for deposition, and the background vacuum is high. at 9×10 -4 Pa. According to the different film structures shown in Table 4, deposit sequentially on the glass: ZnSnOx, ZnO, Ag, Ti, ZnO, ZrO 2 and SiO 2 layer. Among them, ZnSnOx adopts Zn50Sn50 alloy target in Ar / O 2 Intermediate frequency reactive sputtering in a mixed atmosphere with a flow ratio of 1 / 1, ZnO is a Zn98Al2 alloy target in Ar / O 2 Intermediate frequency reactive sputtering deposition in a mixed atmosphere with a flow ratio of 2 / 3, Ag and Ti were deposited by DC sputtering in an Ar atmosphere, ZrO 2 Using Zr metal target in Ar / O 2 Intermediate Frequency Reactive Sputtering Deposition in a Mixed Atmosphere with a Flow Ratio of 3 / 1, SiO 2 Using SiAl alloy target in Ar / O 2 Intermediate frequency sputter...

Embodiment 10～12

[0058] Sodium calcium silicate float white glass or green glass with a thickness of 2.1 mm is used as the coating substrate. After cutting, edging, washing and drying, it enters the magnetron sputtering coating line for coating deposition. The background vacuum degrees higher than 9×10 -4 Pa, as shown in table 5, deposited film layer structure is embodiment 3 in table 2, then will be deposited with the white glass of embodiment 3 film layer structure and the white glass of 2.1 millimeters of thickness or green glass matching sheet baking It is bent and formed, and a piece of colorless PVB film with a thickness of 0.76 mm is sandwiched in the middle, and the sheets are combined in an autoclave under high pressure to finally make a laminated glass product. The structural diagram is as follows Figure 4 and Figure 5 shown.

[0059] Table 5 Embodiment 10~12 structure and its main technical indicators

[0060]

[0061]

[0062] Wherein, whether the coated glass is used as...

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Abstract

The invention relates to the field of glass coating, in particular to low-eradiation coated glass available for heat treatment and high in visible light transmission and sandwich glass products thereof. A film structure sequentially comprises a glass substrate, a first dielectric layer, an infrared reflecting layer and a second dielectric layer above the glass substrate and is characterized in that the second dielectric layer comprises a second dielectric film made of at least one of ZrO2 and ZrOxNy, a third dielectric film deposited on the second dielectric film, wherein the third dielectric film is made of at least one of metal oxides of Ti, Al, Si, Ta, Hf, Nb, Cr, Ni, Fe, Mo, W, Y and the like, or at least one of metal nitrides or metal nitrogen oxides of Ti, Al, Ta, Nb, Fe, Hf, Ni, Cr and the like. The low-eradiation coated glass has the advantages that the low-eradiation coated glass and the sandwich glass products thereof have high mechanical stability and high-temperature thermal treatment stability.

Description

Technical field: [0001] The invention relates to the field of glass coating, in particular to high visible light transmittance, heat-treatable low-radiation coated glass and its laminated glass products, especially suitable for single silver coated laminated glass on vehicles. Background technique: [0002] Low-emissivity film (low-e film) glass has the advantages of transmitting visible light and reflecting infrared rays. Therefore, as a green product, there is a huge market demand in buildings and vehicles. The core material of the low-emissivity film is one or more layers of silver (9nm to 15nm). Since the silver layer is easily corroded and oxidized, a transparent medium that can transmit visible light must be deposited on the top and bottom of the silver layer. layer; these dielectric layers can protect the silver layer from being damaged during subsequent processing, especially high-temperature heat treatment (such as tempering and baking forming); in addition, the die...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C17/34C03C17/36C03C27/12
CPCC03C17/36C03C17/3626C03C17/3644C03C17/366
Inventor 曹晖林柱袁军林朱谧何立山卢国水彭颖昊福原康太
Owner FUYAO GLASS IND GROUP CO LTD
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