Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Method for optimizing process operation of catalytic hydrogenation reaction of acetylene in industrial device

A technology for reaction process and optimized operation, which is applied in special data processing applications, instruments, electrical digital data processing, etc., and can solve problems such as model parameters that cannot be directly applied

Active Publication Date: 2011-04-27
EAST CHINA UNIV OF SCI & TECH
View PDF1 Cites 8 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the catalyst loaded in an industrial reactor will be affected by temperature, reactant concentration, etc., and such model parameters given in the literature cannot be directly applied to industrial devices, so it is necessary to obtain a catalyst kinetic model suitable for actual industrial reactors Parameters, as well as the dynamic model parameters when the catalyst is deactivated, so as to deeply understand the reaction process, and then find the best industrial operating parameters, apply to the production process, optimize production, save energy and reduce emissions

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Method for optimizing process operation of catalytic hydrogenation reaction of acetylene in industrial device
  • Method for optimizing process operation of catalytic hydrogenation reaction of acetylene in industrial device
  • Method for optimizing process operation of catalytic hydrogenation reaction of acetylene in industrial device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment Construction

[0025] The present invention will be further described below with reference to the drawings and examples.

[0026] Reaction mechanism and kinetic model

[0027] Laboratory research results of the acetylene catalytic hydrogenation reaction process show that hydrocarbons cover the surface of palladium metal to form two different catalytic centers: A center and E center. The A center is composed of a series of narrow adsorption centers, which can adsorb acetylene and hydrogen, but because they are too narrow to adsorb ethylene, ethylene hydrogenation cannot be carried out; the E center can adsorb all reactants including ethylene, due to the steady state The number of E centers on the catalyst is much smaller than the number of A centers. The hydrogenation rate of acetylene on the F center is negligible, and the main hydrogenation reaction is ethylene. A reaction of π-C2H2 hydrogenation to generate ethane will occur on the A center, and this reaction is first hydrogenated by the verti...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a method for optimizing process operation of catalytic hydrogenation reaction of acetylene in an industrial device. The method has the following beneficial effects: based on a hydrogenation reactor model, the genetic algorithm is used for fitting the parameters of a dynamic model and a deactivation model so as to achieve the aim of precisely describing the chemical reaction process, and on the basis, the genetic algorithm is reused for optimizing the process operation conditions according to the practical industrial production goal, thus the influence of each factor in an industrial reactor on the reaction process can be described; and the models have higher industrial data fitting and predicting precision and good usability, and in addition, the modeling method is suitable for various catalytic hydrogenation reactions in fixed bed reactors and has wide applicability.

Description

Technical field [0001] The invention relates to a process optimization operation method, in particular to an industrial device acetylene catalytic hydrogenation reaction process optimization operation method. Background technique [0002] Reaction process model research is the basis for process and engineering technology development and optimization, and kinetics research is the basis for reaction engineering model research. The task of kinetics research is to quantitatively understand the influence of reaction temperature, reactant concentration, catalyst and other conditions on the reaction process, and to understand its laws and mechanisms by investigating the chemical characteristics of the reaction process. Catalyst deactivation is a complex phenomenon. Through further study of the complex phenomenon of catalyst activity change and quantitative expression of the relationship between catalyst deactivation degree and service time and temperature, various effective measures to ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): G06F17/50
Inventor 钱锋蒋达杜文莉叶贞成田亮
Owner EAST CHINA UNIV OF SCI & TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products