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Method for preparing TiO2 slurry of organic carrier system

An organic carrier and system technology, applied in the field of solar cells, can solve problems such as difficult to realize, and achieve the effects of improving performance, enhancing absorption, and large specific surface area

Inactive Publication Date: 2009-11-04
IRICO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In recent years, there have been extensive studies on the application of nanotubes in solar cells, most of which believe that TiO 2 Nanotubes have a larger specific surface area, and the tubular structure of nanotubes is more conducive to the effective transport of electrons, but it is difficult to directly prepare nanotubes on conductive substrates.

Method used

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  • Method for preparing TiO2 slurry of organic carrier system

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] A kind of TiO of organic carrier system 2 The preparation method of slurry, comprises the steps:

[0015] 1) Preparation of organic vehicle: add 1 part of ethyl cellulose to terpineol at a ratio of 1:5 by mass and number, and stir in a water bath at 80° C. for 2 hours to form an organic vehicle with a viscosity of 6.1 Kcp;

[0016] 2) TiO 2 Preparation of nano-mixed crystals: TiO with a particle size of 25nm 2 Nanocrystalline and TiO with a particle size of 100nm 2 The nanotubes are mixed in a mass ratio of 1:3;

[0017] 3) Organic carrier system nano-TiO 2 The preparation of slurry: the TiO prepared according to step 2) method 2 Nano mixed crystals are mixed with the organic carrier prepared in step 1), wherein, TiO 2 The mass fraction of nano-mixed crystals is 18 parts, and after mixing evenly, grind for 1 hour to obtain the organic carrier system nano-TiO 2 slurry.

Embodiment 2

[0019] A kind of TiO of organic carrier system 2 The preparation method of slurry, comprises the steps:

[0020] 1) Preparation of organic vehicle: add 1 part of ethyl cellulose to terpineol at a ratio of 1:7 by mass and number, and stir in a water bath at 80° C. for 2 hours to form an organic vehicle with a viscosity of 6.0 Kcp;

[0021] 2) TiO 2 Preparation of nano-mixed crystals: TiO with a particle size of 25nm 2 Nanocrystalline and TiO with a particle size of 100nm 2 The nanotubes are mixed in a mass ratio of 1:1;

[0022] 3) Organic carrier system nano-TiO 2 The preparation of slurry: the TiO prepared according to step 2) method 2 Nano mixed crystals are mixed with the organic carrier prepared in step 1), wherein, TiO 2 The mass fraction of nano-mixed crystals is 24 parts, and after mixing evenly, grind for 1 hour to obtain the organic carrier system nano-TiO 2 slurry.

Embodiment 3

[0024] A kind of TiO of organic carrier system 2 The preparation method of slurry, comprises the steps:

[0025] 1) Preparation of the organic vehicle: add 1 part of ethyl cellulose to terpineol at a ratio of 1:10 in parts by mass, and stir in a water bath at 80° C. for 2 hours to form an organic vehicle with a viscosity of 5.9 Kcp;

[0026] 2) TiO 2 Preparation of nano-mixed crystals: TiO with a particle size of 25nm 2 Nanocrystalline and TiO with a particle size of 100nm 2 The nanotubes are mixed in a mass ratio of 1:2;

[0027] 3) Organic carrier system nano-TiO 2 The preparation of slurry: the TiO prepared according to step 2) method 2 Nano mixed crystals are mixed with the organic carrier prepared in step 1), wherein, TiO 2 The mass fraction of nano-mixed crystals is 20 parts, and after mixing evenly, grind for 1 hour to obtain the organic carrier system nano-TiO 2 slurry.

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Abstract

The invention belongs to the technical field of solar cells, and relates to a method for preparing TiO2 slurry of an organic carrier system. The method comprises the following steps of: 1) preparation of an organic carrier, namely adding ethyl cellulose into terpineol, stirring the mixture for 2 hours in water bath at the temperature of 80 DEG C, and forming the organic carrier of which the mass ratio of the ethyl cellulose to the terpineol is between 1:10 and 1:5 and the viscosity is between 5.9 and 6.1 Kcp; 2) preparation of TiO2 mixed nano crystal, namely mixing TiO2 nano crystal with the particle diameter of between 10 and 25 nm and a TiO2 nano tube with the particle diameter of between 20 and 100 nm according to the proportion of 1:1-1:3; and 3) obtaining of the nano TiO2 slurry of the organic carrier system by fully mixing the TiO2 mixed nano crystal prepared by the method in the step 2) and the organic carrier according to the proportion of 18:82-24:76 and grinding the mixture for 1 hour. TiO2 membranes prepared by the slurry have large specific surface, so that the absorption of the photo anode on sunlight is strengthened and simultaneously the electronic transmission rate is improved and the performance of the cell is effectively improved.

Description

technical field [0001] The invention belongs to the technical field of solar cells, and relates to an organic carrier system of TiO 2 Preparation method of slurry. Background technique [0002] With the depletion of global mineral energy and the aggravation of environmental pollution, the utilization of solar energy resources has attracted the attention of the world, so the research of solar cells has become a research hotspot worldwide. Among all kinds of new solar cells, dye-sensitized solar cells have been paid more and more attention due to their advantages such as simple manufacturing process, convenient mass production, and low cost. [0003] In dye-sensitized solar cells, the performance of the porous photoanode is particularly important to the performance of the cell. In order to achieve as much dye adsorption as possible, while achieving a firm contact with the conductive substrate, and to realize the transport of electrons from the excited state of the dye to the...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/042H01G9/07H01G9/20H01M14/00H01L51/48
CPCY02E10/50Y02E10/549
Inventor 姜春华李少彦刘文秀
Owner IRICO
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