Reversible molecular electronic device based on technique of scan tunnel microscope and its manufacturing method
An electronic device and scanning tunneling technology, applied in the field of electrically reversible molecular electronic devices and their fabrication
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Embodiment 1
[0026] Embodiment 1 Prepare Ag single crystal thin film by epitaxial method on the newly stripped mica surface, then prepare vertically oriented CPVB monolayer film on the surface of Ag single crystal thin film (solvent adopts acetonitrile-benzene mixed solution, CPVB solution Concentration is 10 -5 About M, immerse the base in the base to absorb into a film). The Ag substrate is used as the substrate of STM, and the STM probe adopts Pt-Ir alloy wire. The STM instrument works in the constant high mode, and the working voltage is 0.005-0.1 volts, and the thin film device is in the "0" state at this time. A positive square wave pulse voltage (1-4 volts, the probe is positive and the substrate is negative) is applied between the STM probe and the substrate, and the CPVB molecules under the needle tip are pulled up for a certain distance, that is, the "1" state, This process is "writing". At the same position, if a reverse pulse voltage (1-4 volts, the base is positive), the CP...
Embodiment 2
[0028] Example 2 The compound uses PDVB, the solvent uses acetone, and the solution concentration is 10 -6 -10 -5 M. The preparation process of the film layer and the device assembly are the same as Example 1. The external working voltage of its reversible conversion is a square wave pulse voltage of 3-4 volts, that is, writing and erasing can be realized, and can be repeated.
Embodiment 3
[0029] Example 3 The compound uses ACVB, the solvent uses acetone-acetonitrile mixed solution, and the solution concentration is 5×10 -5 M or so. The preparation process of the film layer and device assembly are the same as Example 1. The external working voltage of its reversible conversion is a square wave pulse voltage of 3-4 volts, that is, writing and erasing can be realized, and can be repeated.
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