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Device for measuring total concentration of multivalent mercury in coal-fired flue gas

A coal-fired flue gas, multi-valence technology, applied in the direction of measuring devices, instruments, scientific instruments, etc., can solve the problems of inability to directly measure the mercury concentration of coal-fired flue gas, complicated process, etc., achieve continuous measurement and simplify the system process , the effect of improving accuracy

Inactive Publication Date: 2020-07-28
NANJING UNIV OF SCI & TECH
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Problems solved by technology

[0003] Mercury in coal-fired flue gas mainly exists in three forms: oxidized mercury, particulate mercury, and elemental mercury. The problem with current measurement technology is that it cannot directly measure the mercury concentration in coal-fired flue gas. Mercury concentration methods include OHM and 30B methods. These methods require sampling before continuing to measure. The process is relatively complicated, and they all require sampling after the particle treatment device

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  • Device for measuring total concentration of multivalent mercury in coal-fired flue gas

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Embodiment Construction

[0041] Such as figure 1 As shown, the invention discloses a device for measuring the total concentration of multivalent mercury in coal-fired flue gas. The device takes advantage of the high-temperature pyrolysis of particulate mercury and the strong oxidative properties of stannous chloride hydrochloric acid solution. The device includes a gas-solid separation system, a carrier gas flow control system, a particulate mercury conversion system, an oxidized mercury conversion system, and a mercury concentration measuring system. The device for measuring the total concentration of multivalent mercury in the present invention solves the problem that the sampling device cannot be applied to flue gas with more dust by using a cyclone separator and a membrane filter device; by using an oxidized mercury conversion system and particle The mercury conversion system solves the problem that mercury in coal-fired flue gas cannot be directly measured online.

[0042] combine figure 1 The...

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Abstract

The invention belongs to the field of coal-fired flue gas mercury content measurement, and particularly relates to a device for measuring the total concentration of multivalent mercury in coal-fired flue gas. The device comprises a gas-solid separation system, a carrier gas flow control system, an oxidation-state mercury conversion system, a granular-state mercury conversion system and a mercury concentration measurement system. The gas-solid separation system is connected with the oxidation-state mercury conversion system and the granular-state mercury conversion system, the gas-solid separation system separates gas and solid in flue gas, the gas enters the oxidation-state mercury conversion system, and the solid enters the granular-state mercury conversion system. The carrier gas flow control system is connected with the granular-state mercury conversion system and is used for carrying particles and controlling the carrier gas flow to be the same as the flue gas flow. The mercury concentration measurement system is connected with the oxidation-state mercury conversion system and the granular-state mercury conversion system, and is used for measuring and recording the mercury concentrations in the two systems. According to the measuring device, the concentration of mercury in the coal-fired flue gas can be directly measured, the flue gas sampling process is omitted, the systemprocess can be simplified, and the cost is reduced.

Description

technical field [0001] The invention belongs to the field of measuring mercury content in coal-burning flue gas, and in particular relates to a device for measuring the total concentration of multivalent mercury in coal-burning flue gas. Background technique [0002] Mercury is a heavy metal element, which is toxic, can be enriched through the food chain, and can also migrate with the atmosphere. These characteristics increase the harm of mercury to the natural environment and human life and health. Mercury pollution in the atmosphere is mainly caused by human beings, and coal combustion is the main source of human-made mercury pollution. Although China has made great breakthroughs in new energy power generation technology, for a relatively long time in the future, China's energy structure will be dominated by coal. Therefore, China's mercury pollution problem should be taken seriously, and China has also formulated a series of emission standards to limit the emission conce...

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Application Information

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IPC IPC(8): G01N33/00
CPCG01N33/0045G01N33/0011G01N33/0013G01N33/0021
Inventor 王卉吴建飞沈昊天沈畅朱一铭张旭东应展烽
Owner NANJING UNIV OF SCI & TECH
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