Optical film having improved contrast ratio, polarizing plate including same, and liquid crystal display device including same
A technology of optical film and contrast ratio, which is applied in the field of optical film and can solve problems such as degradation
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preparation example 1
[0134] Preparation Example 1: Preparation of the composition for the patterned layer
[0135]By adding 73 parts by weight of a solvent-free zirconia-containing solution HR-10-1 (Nippon Shokubai Co., Ltd.), the average particle diameter (D50) of zirconia: 11 nm, containing dispersed in acrylic benzyl 80% by weight of high refractive index compound of zirconia in ester, refractive index: 1.67) mixed with 22 parts by weight of trimethylpropane triacrylate, followed by 4.5 parts by weight of starter (TPO LG, India Globalization Capital Co., Ltd. (IGC Co., Ltd.)) and 0.5 parts by weight of a release agent (BYK 3500) were added to the mixture to prepare a composition for a patterned layer. The composition used for the patterned layer had a refractive index of 1.60. In the composition for the patterned layer, zirconia was present in an amount of 51% by weight in terms of solid content.
preparation example 2
[0136] Preparation Example 2: Preparation of Composition for Gap Filling Layer
[0137] 23 parts by weight of a photocurable compound (UP111, ENTIS Co., Ltd, solid content: 70% by weight, solvent: PGME (propylene glycol methyl ether)), 8.4 parts by weight of SR833S (Sartomer Co., Ltd. (SartomerCo., Ltd.)), 8 parts by weight of HDDA (ENTIS Co., Ltd.), 46 parts by weight of propylene glycol monomethyl ether acetate (propylene glycol monomethylether acetate; PGMEA) and 12 parts by weight of methyl isobutyl Base ketone (MIBK) was mixed and stirred. After the stirring was completed, 1.15 parts by weight of initiator (Omnirad 184, India Globalization Capital Limited), 0.03 parts by weight of UV reactive silicone additive (UV3500), 0.07 parts by weight of dispersant (Disperbyk-2163, BYK Co., Ltd.) and 0.05 parts by weight of an anti-fingerprint agent (KY1203, Shin-Etsu Co., Ltd.) were added to the mixture, whereby a solution was prepared.
[0138] Organic particles (MSX-105, refrac...
preparation example 3
[0139] Preparation Example 3: Preparation of Composition for Gap Filling Layer
[0140] A solution was prepared by the same method as in Preparation Example 2.
[0141] Organic particles (MSX-2H, refractive index: 1.495, polymethyl methacrylate particles, average particle diameter (D50): 2.7 µm, intermediate dispersion particles, Sekisui Co., Ltd.) were mixed with the solution, thereby preparing Fill layer solution. The composition for the gap-fill layer contained 6% by weight of organic particles in terms of solid content.
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