Lithium ion battery electrolyte additive, lithium ion battery electrolyte and lithium ion battery

An electrolyte additive and lithium-ion battery technology, applied in the field of lithium-ion batteries, can solve the problems of poor safety performance of non-aqueous electrolytes and achieve good cycle performance

Active Publication Date: 2020-03-24
DO FLUORIDE CHEM CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the safety performance of the non-aqueous electrolyte is poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 2

[0025] The lithium-ion battery electrolyte additive in this embodiment consists of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate. The vinyl phosphate is diethyl vinyl phosphate, and the added amount of the vinyl phosphate is 50% of the mass of the additive. The mass ratio of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate is 1:0.3:0.7.

Embodiment 3

[0027] The lithium-ion battery electrolyte additive in this embodiment consists of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate. Vinyl phosphate is a mixture of dimethyl vinyl phosphate and diethyl vinyl phosphate, and the mass ratio of the two is 1:1. The amount of vinyl phosphate added is 50% of the mass of the additive. The mass ratio of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate is 2:1:1.

[0028] The embodiment 4 of lithium ion battery electrolyte additive

[0029] The lithium-ion battery electrolyte additive in this embodiment includes vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate. The vinyl phosphate is dimethyl vinyl phosphate, and the added amount of the vinyl phosphate is 40% of the mass of the additive. The mass ratio of vinyl sulfonate, vinyl sulfonyl fluoride and fluoroethylene carbonate is 2:1:2.

[0030] The embodiment 5 of lithium ion battery electrolyte additive

[0031] The lithi...

Embodiment 7

[0035] The lithium-ion battery electrolyte additive in this embodiment consists of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate. The vinyl phosphate is dimethyl vinyl phosphate, and the added amount of the vinyl phosphate is 50% of the mass of the additive. The mass ratio of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate is 5:3:2.

[0036] Example 8 of Lithium-ion battery electrolyte additive

[0037] The lithium-ion battery electrolyte additive in this embodiment consists of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate. The vinyl phosphate is dimethyl vinyl phosphate, and the added amount of the vinyl phosphate is 50% of the mass of the additive. The mass ratio of vinyl phosphate, vinyl sulfonyl fluoride and fluoroethylene carbonate is 5:1:4.

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Abstract

The invention relates to a lithium ion battery electrolyte additive, a lithium ion battery electrolyte and a lithium ion battery, and belongs to the technical field of lithium ion batteries. The lithium ion electrolyte additive disclosed by the invention comprises vinyl phosphate and vinyl sulfonyl fluoride. The lithium ion electrolyte comprises a non-aqueous organic solvent, a lithium salt and anadditive, wherein the additive comprises vinyl phosphate and vinyl sulfonyl fluoride. The lithium ion electrolyte disclosed by the invention has relatively good flame retardance. When the lithium ionbattery adopting the electrolyte works at a high voltage, the lithium ion battery not only has good cycling stability, but also has good safety performance at a high temperature.

Description

technical field [0001] The invention relates to a lithium-ion battery electrolyte additive, a lithium-ion battery electrolyte and a lithium-ion battery, belonging to the technical field of lithium-ion batteries. Background technique [0002] Due to the advantages of high specific energy, long cycle life, and no memory effect, lithium-ion batteries are widely used in many fields such as mobile phones, computers, cameras, and electric vehicles. However, with the continuous development of science and technology, various application fields have put forward higher requirements on the performance of lithium-ion batteries. Among them, the most urgent thing is to improve the energy density of lithium-ion batteries under the premise of ensuring safety. At present, the commonly used method to increase the energy density of lithium-ion batteries is to use high-voltage cathode materials, such as LiCoPO 4 、LiNi 0.5 mn 1.5 o 4 、 LiNi 1 / 3 co 1 / 3 mn 1 / 3 o 2 and other materials. Ho...

Claims

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Application Information

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IPC IPC(8): H01M10/0567H01M10/0525H01M10/42
CPCH01M10/0525H01M10/0567H01M10/4235H01M2300/0025Y02E60/10
Inventor 侯红军薛旭金于贺华于洋王永勤张照波罗传军杨明霞施秀华施翠莲
Owner DO FLUORIDE CHEM CO LTD
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