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A DCS-based three-stage wastewater pH control method and system

A control method and technology for wastewater, applied in water treatment parameter control, comprehensive factory control, chemical instruments and methods, etc., can solve the problems of pH value overshoot, no protection adjustment tank, inability to accurately control the pH value of wastewater, etc. The effect of reducing hysteresis, reducing pH fluctuations

Active Publication Date: 2022-07-12
WANHUA CHEM GRP CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This invention has the following disadvantages: ① neutralization is carried out through a single-stage wastewater tank, and the hysteresis of the mixing process between wastewater and neutralization is not fully considered, and the pH value of the neutralized wastewater cannot be accurately controlled; ② the wastewater pH value PID controller uses a fixed The PID parameter does not fully take into account the nonlinearity of the pH adjustment process, which may easily lead to overshooting of the pH value; ③ there is no protective adjustment pool, and the pH of the wastewater cannot be pulled back to the target value after adding too much neutralizer

Method used

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  • A DCS-based three-stage wastewater pH control method and system
  • A DCS-based three-stage wastewater pH control method and system
  • A DCS-based three-stage wastewater pH control method and system

Examples

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Embodiment 1

[0079] A chemical plant produces an alkaline wastewater with a pH between 10 and 12. 8% hydrochloric acid is used as a neutralizing agent to adjust the pH in the third-stage neutralization tank. It is hoped that the pH should be controlled at 5 to 7. In addition to this stream of wastewater, this wastewater tank also receives another alkaline wastewater with a pH value above 13 (2 to 3 times per shift), which makes the flow and composition of wastewater entering the neutralization tank fluctuate greatly. The simple designed loop cannot achieve stable pH control, requiring frequent manual intervention by the operator. The operation volume is as high as 15 times per shift, and the pH overshoot is more than ±3, which not only hinders the long-term stable operation of the wastewater treatment system, but also seriously affects the the degree of automation of the device. To this end, according to the patent, the corresponding hardware and the 5% caustic soda pipeline of the tertiar...

Embodiment 2

[0095] A chemical plant produces an acidic wastewater with a pH value between 3 and 4. 10% caustic soda is used as a neutralizing agent for pH adjustment in the neutralization tank. It is hoped that the pH value should be controlled at 6 to 8, because there is only one level of neutralization. The mixing time of acid wastewater and caustic soda is short, and the neutralization is incomplete. Therefore, the pH value of the wastewater at the outlet of the neutralization tank can only be controlled at (6-10), which affects the service life of downstream devices. To this end, according to this patent, it is transformed into a three-level protection pool, and a 10% caustic soda pipeline is added to the fine adjustment pool, and a 10% caustic soda pipeline and a 10% hydrochloric acid pipeline are added to the protection pool. The scheme is reconfigured.

[0096] After the transformation, the alkaline wastewater first enters the rough adjustment tank, and the neutralizer ratio contro...

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Abstract

The invention discloses a DCS-based three-stage wastewater pH control method and system, comprising the following steps: (1) using tools to collect process wastewater flow, pH value, and fine-tuning pool and protection pool wastewater pH value, and communicate into DCS; (2) Obtain the amount of acid / alkali entering the first-level rough adjustment tank through the preset soft instrument, multiply it by the neutralization scale factor as the set value of the neutralizer, and perform preliminary neutralization in the first-level rough adjustment tank; (3) Continue to add a neutralizer for adjustment according to the deviation between the pH value of the wastewater in the fine adjustment tank and the set value, and assign different PID parameters to the controller in different intervals of the titration curve according to the pH value of the wastewater; (4) According to the pH value of the wastewater in the protection tank Deviation from the set value, when the deviation exceeds the set range, continue to add neutralizer for adjustment. The purpose of the present invention is to improve the pH adjustment accuracy of wastewater through multi-stage adjustment, reduce the influence of pH fluctuation on the downstream device process and equipment, ensure the long-term stable operation of the device, and obtain obvious economic benefits.

Description

technical field [0001] The invention relates to a DCS-based three-stage wastewater pH control method and system. Background technique [0002] Before the acidic or alkaline process wastewater is sent to the downstream device for treatment, it is often necessary to add a neutralizing agent to adjust its pH value. The stability of the pH control of the process wastewater directly affects the stable and safe operation of the downstream device. [0003] At present, most pH automatic control adopts simple control action for adjustment, and no automatic control scheme is designed for the characteristics of strong nonlinearity and hysteresis in the pH adjustment process. As a result, the pH of the neutralized wastewater fluctuates greatly, which in turn causes the downstream devices to be too acidic or too alkaline, which affects the treatment effect of subsequent facilities such as flocculation sedimentation, catalytic oxidation, and biochemical treatment. Therefore, the inabilit...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/66
CPCC02F1/66C02F2209/06Y02P90/02
Inventor 王浩王远辉朱敏燕王亚辉田宇吴雪峰张宏科
Owner WANHUA CHEM GRP CO LTD
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