A kind of antistatic high wear-resistant tire tread rubber and preparation method thereof
A tire surface, high wear-resistant technology, applied in the field of tire materials
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Embodiment 1
[0032](1) Mix the low DBP value nano carbon black and the high DBP value nano carbon black according to the mass ratio of 3:1, the DBP value of the high DBP value nano carbon black is 360, and the DBP value of the low DBP value nano carbon black is 240 ;
[0033] (2) 10 parts of step (1) gained mixed carbon black is added the aqueous dispersion of 50 mass parts graphene oxide, carry out high-speed shear dispersion by emulsifying homogenizer, the mass concentration of graphene oxide aqueous dispersion is 1%; The lateral size of graphene oxide is 3-10 μm, the vertical size is 0.3-1.2 nm, and the carbon-oxygen ratio is 2.5.
[0034] (3) Put the dispersion obtained in step (2) in a hydrothermal reaction kettle, react at 180° C. for 2 hours, cool to room temperature, take out the reactant and dry it by infrared to obtain a graphene-based composite additive.
[0035] (4) Mix the graphene-based composite additive obtained in step (3) with conventional tread rubber, and carry out mix...
Embodiment 2
[0040] (1) Mix the low DBP value nano carbon black and the high DBP value nano carbon black according to the mass ratio of 3:1, the DBP value of the high DBP value nano carbon black is 400, and the DBP value of the low DBP value nano carbon black is 240 ;
[0041] (2) 10 parts of step (1) gained mixed carbon black is added the aqueous dispersion of 50 mass parts graphene oxide, carry out high-speed shear dispersion by emulsifying homogenizer, the mass concentration of graphene oxide aqueous dispersion is 3%; The lateral size of graphene oxide is 3-10 μm, the vertical size is 0.3-1.2 nm, and the carbon-oxygen ratio is 6.
[0042] (3) Put the dispersion obtained in step (2) in a hydrothermal reaction kettle, react at 180° C. for 2 hours, cool to room temperature, take out the reactant and dry it by infrared to obtain a graphene-based composite additive.
[0043] (4) Mix the graphene-based composite additive obtained in step (3) with conventional tread rubber, and carry out mixi...
Embodiment 3
[0048] (1) Mix the low DBP value nano carbon black and the high DBP value nano carbon black according to the mass ratio of 3:1, the DBP value of the high DBP value nano carbon black is 380, and the DBP value of the low DBP value nano carbon black is 280 ;
[0049] (2) 10 parts of step (1) gained mixed carbon black is added the aqueous dispersion of 50 mass parts graphene oxide, carry out high-speed shear dispersion by emulsifying homogenizer, the mass concentration of graphene oxide aqueous dispersion is 6%; The lateral size of graphene oxide is 3-10 μm, the vertical size is 0.3-1.2 nm, and the carbon-oxygen ratio is 4.
[0050] (3) Put the dispersion obtained in step (2) in a hydrothermal reaction kettle, react at 180° C. for 2 hours, cool to room temperature, take out the reactant and dry it by infrared to obtain a graphene-based composite additive.
[0051] (4) Mix the graphene-based composite additive obtained in step (3) with conventional tread rubber, and carry out mixi...
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