A kind of highly gloss-retaining and color-retaining acrylic acid modified polyurethane topcoat and preparation method thereof
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A polyurethane topcoat, acrylic technology, applied in the field of coatings, can solve the problems of incompatibility or fixation, no active groups, adverse effects of the coating, etc., to reduce adverse effects, good anti-ozone aging, improve anti-aging performance Effect
Active Publication Date: 2020-12-22
南京东顶新材料科技有限公司
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[0003] In order to further improve the anti-aging performance and corrosion resistance of polyurethane coatings, additives such as enhancers, anti-aging agents, and antioxidants are generally added to the coating system, but these additives are generally small molecular compounds, which are not suitable for miscibility or fixation. In the system, and generally does not contain active groups that can chemically react with the polyurethane system, so that these additives lack chemical bonding with the system, and are easy to separate out of the system, causing adverse effects on the coating
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preparation example Construction
[0038] The preparation method of highly gloss-retaining and color-retaining acrylic modified polyurethane topcoat comprises the following steps:
[0039] (1) Weigh the raw materials in component A in proportion, first add acrylate emulsion and polyurethane emulsion into the stirring tank, then add deionized water and dispersant, then add pigments and fillers, stir well and then add other additives and disinfectants Foaming agent, stir well and then add enhancer, mix well to obtain component A;
[0040] (2) Immediately after obtaining component A, add component B in proportion, mix evenly, and filter.
Embodiment 1
[0042] Component A is composed of the following raw materials in parts by weight: 45 parts of acrylate emulsion, 55 parts of polyurethane emulsion, 5 parts of reinforcing agent, 12 parts of titanium dioxide, 2 parts of BYK-2163, 0.5 parts of BYK-066N, 20 parts of deionized water; B component is water-based HDI curing agent.
[0043] The weight ratio of component A to component B is 100:25.
Embodiment 2
[0045] Component A is composed of the following raw materials in parts by weight: 50 parts of acrylate emulsion, 50 parts of polyurethane emulsion, 3 parts of reinforcing agent, 10 parts of mica, 1 part of BYK-1150, 1 part of BYK-208, 2 parts of silver sulfadiazine, 15 parts of deionized water; component B is water-based HDI curing agent.
[0046] The weight ratio of component A to component B is 100:30.
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Abstract
The invention belongs to the field of coating and particularly relates to a high light-retaining and color-retaining acrylic acid modified polyurethane finishing coat and a preparation method thereof.The finishing coat contains a component A and a component B in a weight ratio of 100 to (20-30), wherein the component A contains the following raw materials in parts by weight: 40-50 parts of an acrylate emulsion, 50-60 parts of a polyurethane emulsion, 3-6 parts of an enhancer, 10-15 parts of pigments and fillers, 1-3 parts of a dispersing agent, 0.5-1 part of a defoaming agent, 0-5 parts of other aids and the balance of deionized water; and the component B is a water-based curing agent. The adopted enhancer contains a benzophenone structure with an excellent light stabilization effect andis cable of strongly absorbing ultraviolet light, so that the damage caused by the ultraviolet light to the finishing coat is avoided; and meanwhile, the enhancer has no possibility of being decomposed and decolorized, further contains an N-cyclohexyl p-methoxyaniline structure and has good ozone aging performance, radiation aging resistance and normal aging resistance, and the structure is not decolorized after being placed in air and sunlight for a long time, so that the finishing coat with high light-retaining and color-retaining properties is obtained.
Description
technical field [0001] The invention belongs to the field of coatings, in particular to an acrylic modified polyurethane topcoat with high gloss and color retention and a preparation method thereof. Background technique [0002] Polyurethane coatings have good flexibility, impact resistance, corrosion resistance, abrasion resistance, and the appearance of the coating film is good, and it has good decorative properties. Combining it with acrylic ester can give it good adhesion at the same time and weather resistance. [0003] In order to further improve the anti-aging performance and corrosion resistance of polyurethane coatings, additives such as enhancers, anti-aging agents, and antioxidants are generally added to the coating system, but these additives are generally small molecular compounds, which are not suitable for miscibility or fixation. In the system, and generally do not contain active groups that can chemically react with the polyurethane system, so that there is...
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