Method for resisting against heavy metal Cd toxicity on basis of ZnO/GO composite nanomaterial
A technology of composite nanomaterials and heavy metals, which is applied in the field of antagonizing heavy metal toxicity materials, can solve problems such as limited antagonism ability, and achieve the effects of improved biological safety, simple and fast processing methods, and excellent antagonism effect.
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Embodiment 1
[0047] A method for antagonizing heavy metal Cd toxicity based on ZnO / GO composite nanomaterials, comprising the following steps:
[0048] Step 1, the synthesis of ZnO / GO composite nanomaterial, its synthetic method comprises the following steps:
[0049] ① Weigh 0.55g of zinc acetate and dissolve in 50mL of absolute ethanol, stir vigorously at 80°C for 20min;
[0050] ②Weigh 0.2g of lithium hydroxide and dissolve in 20mL of absolute ethanol;
[0051] ③Add the dissolved lithium hydroxide ethanol solution to 30mL 2mg / mL GO dispersion;
[0052] ④ After the reaction of the zinc acetate solution in step ① is complete, when the temperature drops to 50°C, add the mixture of lithium hydroxide and GO into the zinc acetate solution, and stir for 40 minutes;
[0053] ⑤After the reaction, add n-hexane with twice the volume of the mixture, and let stand overnight at 4°C;
[0054] ⑥ Discard the supernatant by centrifugation, wash the materials with absolute ethanol and ultrapure water, ...
Embodiment 2
[0061] A method for antagonizing heavy metal Cd toxicity based on ZnO / GO composite nanomaterials, comprising the following steps:
[0062] Step 1, the synthesis of ZnO / GO composite nanomaterial, its synthetic method comprises the following steps:
[0063] ① Weigh 0.75g of zinc acetate and dissolve in 55mL of absolute ethanol, stir vigorously at 85°C for 25min;
[0064] ② Weigh 0.25g of lithium hydroxide and dissolve in 25mL of absolute ethanol;
[0065] ③ Add the dissolved lithium hydroxide ethanol solution to 35mL 2mg / mL GO dispersion;
[0066] ④ After the reaction of the zinc acetate solution in step ① is complete, when the temperature drops to 50°C, add the mixture of lithium hydroxide and GO into the zinc acetate solution, and stir for 45 minutes;
[0067] ⑤After the reaction is finished, add n-hexane with twice the volume of the mixture, and let stand overnight at 5°C;
[0068] ⑥ Discard the supernatant by centrifugation, wash the materials with absolute ethanol and ul...
Embodiment 3
[0075] A method for antagonizing heavy metal Cd toxicity based on ZnO / GO composite nanomaterials, comprising the following steps:
[0076] Step 1, the synthesis of ZnO / GO composite nanomaterial, its synthetic method comprises the following steps:
[0077] ① Weigh 0.25g of zinc acetate and dissolve it in 15mL of absolute ethanol, stir vigorously at 80°C for 15min;
[0078] ②Weigh 0.15g of lithium hydroxide and dissolve in 15mL of absolute ethanol;
[0079] ③ Add the dissolved lithium hydroxide ethanol solution to 25mL 2mg / mL GO dispersion;
[0080] ④ After the reaction of the zinc acetate solution in step ① is complete, when the temperature drops to 50°C, add the mixture of lithium hydroxide and GO into the zinc acetate solution, and stir for 35 minutes;
[0081] ⑤ After the reaction is over, add n-hexane with twice the volume of the mixture, and let stand overnight at 3°C;
[0082] ⑥ Discard the supernatant by centrifugation, wash the materials with absolute ethanol and ult...
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