Fluorescent display screen containing up-conversion luminescent material and preparation method and application thereof
A technology of luminescent materials and display screens, applied in optics, optical components, instruments, etc., can solve the problems of high technical threshold and investment amount of OLED, great challenges of micro-display, high price, etc., and achieves long service life and preparation method. Simple, low-cost effects
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Embodiment 1
[0060] This embodiment provides a fluorescent display screen containing an up-conversion luminescent material and a preparation method thereof.
[0061] A fluorescent display containing up-converting luminescent materials, such as figure 1 As shown, it consists of a substrate (1), a red fluorescent material layer (2), a second isolation layer (3), a green fluorescent material layer (4), a first isolation layer (5), a blue fluorescent material layer (6) and The protective layer (7) is stacked sequentially.
[0062] The substrate 1 is made of glass.
[0063] The material of the red fluorescent material layer is NaYF doped with ytterbium and erbium 4 ultrafine nanocrystals. Its preparation method is, Y 2 o 3 , Yb 2 o 3 and Er 2 o 3 According to the molar ratio m(Y 3+ ):m(Yb 3+ ):m(Er 3+ )=70:28:2 was dissolved in dilute hydrochloric acid to obtain a rare earth chloride precursor. The above 1mmol rare earth chloride precursor was added dropwise to a mixed solution com...
Embodiment 2
[0080] This embodiment provides a fluorescent display screen containing an up-conversion luminescent material and a preparation method thereof.
[0081] The structure and preparation method of the fluorescent display screen containing the up-conversion luminescent material in this embodiment are the same as those in Embodiment 1, except that the red fluorescent material layer is different.
[0082] Wherein, the material of the red fluorescent material layer is KMnF doped with ytterbium, erbium and thulium 3 . The preparation method is as follows: 1.5g of KOH, 2mL of water, 4mL of ethanol and 9mL of OA (90wt%) were mixed at room temperature for ten minutes to obtain a white viscous solution. Then sequentially add 10mL of MnCl 2 Solution (0.2mol / L), 15.5mg of YbCl 3 ·6H 2 O (0.4mmol), 1.5mg of ErCl 3 ·6H 2 O (0.04mmol) and 1.5mg of TmCl 3 ·6H 2 O (0.04mmol), stirred vigorously for 20min. Add 8 mL of KF solution (1.25 mol / L) and age for 1 hour to obtain a mixture. The m...
Embodiment 3
[0087] This embodiment provides a fluorescent display screen containing an up-conversion luminescent material and a preparation method thereof.
[0088] The raw materials and preparation method of the fluorescent display screen containing up-conversion luminescent material in this embodiment are the same as those in Example 2, except that there is no second isolation layer between the green fluorescent material layer and the red fluorescent material layer in the fluorescent display screen.
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