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Nanospectral long-acting medium capable of efficiently decomposing organic pollutants under dark and no light conditions, preparation method and application thereof

A kind of organic pollutant and nanotechnology, which is applied in the field of long-acting nano-spectrum media, can solve the problems of sealing agent losing its effect, the elimination reaction is difficult to complete, and it is difficult to eliminate volatile organic compounds, so as to achieve a good catalytic effect.

Active Publication Date: 2019-11-19
浙江裕文环保科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] In principle, the sealing agent blocks the source of the release of volatile organic compounds, which should be able to completely eliminate the pollution pathways of volatile organic compounds. Avoid wear and tear, and after a period of time, the original sealant will lose its original effect
However, there is a problem of elimination effect in the methods of using elimination agent and capture agent. Although the pollution can be reduced to a certain extent, because the pollution of the indoor environment is affected by many factors such as pollution degree, temperature, and air circulation, the elimination reaction is often difficult. Thoroughly, it is difficult to achieve the desired effect of eliminating volatile organic compounds

Method used

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  • Nanospectral long-acting medium capable of efficiently decomposing organic pollutants under dark and no light conditions, preparation method and application thereof
  • Nanospectral long-acting medium capable of efficiently decomposing organic pollutants under dark and no light conditions, preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Preparation of bismuth vanadate

[0043] Dissolve 0.0015 mol of sodium vanadate and 0.00 mol of bismuth nitrate in deionized water, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it in a constant temperature drying box After reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01 mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.

[0044] Preparation of nano-modified niobium oxide:

[0045] At room temperature, 8 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 15 parts by weight of bismuth vanadate, 0.08 parts by weight of sulfurous acid Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pentachloride, and the mi...

Embodiment 2

[0048] Preparation of bismuth vanadate

[0049] Dissolve 0.0015mol of sodium vanadate and 0.00mol of 1 bismuth nitrate in deionized water respectively, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it into a constant temperature drying In the box, after reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.

[0050] Preparation of nano-modified niobium oxide:

[0051] At room temperature, 5 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 10 parts by weight of bismuth vanadate, 0.05 parts by weight of sulfurous acid Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pen...

Embodiment 3

[0054] Preparation of bismuth vanadate

[0055] Dissolve 0.0015mol of sodium vanadate and 0.00mol of 1 bismuth nitrate in deionized water respectively, drop the sodium vanadate solution into the bismuth nitrate solution drop by drop, stir for 30 minutes, let it stand for 5 hours, and put it into a constant temperature drying In the box, after reacting at 160 degrees Celsius for 12 hours, after cooling to room temperature, continue to keep stirring and add 0.01mol of hydrogen peroxide, filter with suction, wash and dry to obtain bismuth vanadate powder.

[0056] Preparation of nano-modified niobium oxide:

[0057] At room temperature, 4 parts by weight of niobium pentachloride were dissolved in 100 parts by weight of absolute ethanol to obtain a niobium pentachloride ethanol solution, which was left to stand for 15 minutes; 14 parts by weight of bismuth vanadate, 0.05 parts by weight of Sodium hydrogen blocked HDI was added to the ethanol solution of niobium pentachloride, and...

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Abstract

The invention relates to a long-acting nano-spectrum medium that can efficiently decompose organic pollutants under dark and no-light conditions. The long-acting nano-spectrum medium is composed of 100 parts by weight of water and 3-20 parts by weight of nano-modified niobium oxide. Modified niobium oxide is prepared by the following steps: Dissolve 3-10 parts by weight of niobium pentachloride in 100 parts by weight of absolute ethanol at room temperature to obtain an ethanol solution of niobium pentachloride, and let it stand for 5-30 minutes; Add 5-15 parts by weight of bismuth vanadate and 0.01-0.1 parts by weight of blocked isocyanate to the ethanol solution of niobium pentachloride, and mix evenly to obtain the first mixed solution; keep stirring the first mixed solution, and add 100 parts by weight of the ethanol aqueous solution Drop into the first mixed solution at a speed of 3-10ml / min; add N, N-dimethylformamide, keep stirring the first mixed solution for 30 minutes, and let stand at room temperature to obtain the second mixed solution; after soaking and drying, The dried material is calcined in a muffle furnace at a temperature of 400-500°C to obtain nano-modified niobium oxide. Nano-spectrum long-lasting media has good catalytic effect in dark light and no light conditions.

Description

technical field [0001] The present invention relates to a nano-spectrum long-acting medium that can efficiently decompose organic pollutants under dark light and no light conditions, and also relates to a preparation method of a nano-spectrum long-acting medium that can efficiently decompose organic pollutants under dark light and no light conditions, and also relates to The application of nano-spectral long-acting media that can efficiently decompose organic pollutants under dark and dark conditions in air purification. Background technique [0002] In recent years, with the improvement of people's living standards, people's requirements for interior decoration standards have become higher and higher, and home decoration has become increasingly modernized. However, the problem of indoor air chemical pollution caused by materials and decoration has followed. These chemicals have seriously affected the health of residents, and have attracted great attention from countries aro...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/24B01J35/02B01J37/04B01J37/08B01D53/86B01D53/72B01J35/00
CPCB01D53/8668B01J27/24B01J37/04B01J37/082B01D2259/4508B01D2255/802B01J35/39B01J35/40
Inventor 郑文华刘体刚楼伟杰徐淑萍姜康义应康霖
Owner 浙江裕文环保科技有限公司
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