Sn/Sb-GAC (granular activated carbon) particle and application thereof to treating 4-chlorophenol waste water through three-dimensional electrochemical reaction

A technology of chemical reaction and three-dimensional electricity, applied in the direction of sterilization/microdynamic water/sewage treatment, water/sewage treatment, water/sewage treatment equipment, etc., can solve the problems of high removal cost, limited removal rate, and difficult removal , to achieve good adsorption effect, simple operation, and increase the area

Inactive Publication Date: 2018-04-13
GUANGXI UNIV FOR NATITIES
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The present invention aims at the problems of difficult removal, limited removal rate, high removal cost and complicated operation in the traditional treatment method of phenol-containing industrial wastewater in the prior art, and provides a preparation of Sn / Sb-GAC particles and its application in three-dimensional electric Application of Chemical Reaction in Treating 4-Chlorophenol Wastewater

Method used

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  • Sn/Sb-GAC (granular activated carbon) particle and application thereof to treating 4-chlorophenol waste water through three-dimensional electrochemical reaction
  • Sn/Sb-GAC (granular activated carbon) particle and application thereof to treating 4-chlorophenol waste water through three-dimensional electrochemical reaction
  • Sn/Sb-GAC (granular activated carbon) particle and application thereof to treating 4-chlorophenol waste water through three-dimensional electrochemical reaction

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Experimental program
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Effect test

preparation Embodiment 1

[0029] (1) Pretreatment of granular activated carbon: boil the granular activated carbon with a large amount of deionized water, dry it, and set aside.

[0030] (2) Weigh SnCl in turn according to the mass ratio: 8:0.4:60 4 ·5H 2 O, SbCl 3 and the GAC.

[0031] (3) SnCl 4 ·5H 2 O, SbCl3 Dissolve in an organic alcohol solvent to obtain a mixed solution, then soak GAC in the mixed solution, and shake on a shaking table at 150r / min for 2 hours to obtain the crude product of supported Sn / Sb-GAC particles, then dry and roast at 300°C to obtain the loaded type Sn / Sb–GAC particles.

preparation Embodiment 2

[0033] (1) Pretreatment of granular activated carbon: boil the granular activated carbon with a large amount of deionized water, dry it, and set aside.

[0034] (2) According to the mass ratio: 10:1:65, weigh SnCl in sequence 4 ·5H 2 O, SbCl 3 and the GAC.

[0035] (3) SnCl 4 ·5H 2 O, SbCl 3 Dissolve in an organic alcohol solvent to obtain a mixed solution, then soak GAC in the mixed solution, and shake on a shaking table at 160r / min for 3 hours to obtain the crude product of supported Sn / Sb-GAC particles, then dry and roast at 350°C to obtain the loaded type Sn / Sb–GAC particles.

preparation Embodiment 3

[0037] (1) Pretreatment of granular activated carbon: boil the granular activated carbon with a large amount of deionized water, dry it, and set aside.

[0038] (2) Weigh SnCl in turn according to the mass ratio: 12:1.5:70 4 ·5H 2 O, SbCl 3 and the GAC.

[0039] (3) SnCl 4 ·5H 2 O, SbCl 3 Dissolve in an organic alcohol solvent to obtain a mixed solution, then soak GAC in the mixed solution, and shake on a shaking table at 170r / min for 4 hours to obtain the crude product of supported Sn / Sb-GAC particles, then dry and roast at 400°C to obtain the loaded type Sn / Sb–GAC particles.

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Abstract

The invention discloses a Sn / Sb-GAC particle. The Sn / Sb-GAC particle is a carrier type Sn / Sb-GAC particle prepared by loading and modifying granular activated carbon with metal ions of Sn and Sb through an impregnation method. The carrier type Sn / Sb-GAC particle serves as a particle electrode, a dimensionally stable anode (DSA) serves as the anode and a titanium plate serves as the cathode to structure a repolarized three-dimensional electrochemical reactor for three-dimensional electrochemical reaction under the action of electrochemical oxidation so that 4-chlorophenol can be degraded into carbon dioxide and water, when applied to treating 4-chlorophenol waste water, the Sn / Sb-GAC particle can achieve a 4-chlorophenol eliminating rate up to higher than 83%. Meanwhile, the Sn / Sb-GAC particle is simple in preparation process, reusable and capable of reducing the treating cost of the 4-chlorophenol waste water and improving the treating efficiency of the 4-chlorophenol waste water.

Description

technical field [0001] The invention belongs to the technical field of sewage treatment, in particular to the preparation of Sn / Sb-GAC particles and its application in three-dimensional electrochemical reaction treatment of 4-chlorophenol wastewater. Background technique [0002] With the rapid development of petrochemical, plastic, synthetic fiber and other industries, phenolic wastewater generated in production is discharged into nature, causing water pollution and affecting the growth and reproduction of aquatic organisms. Phenol-containing wastewater is a refractory toxic organic substance, and it is also a difficult point in environmental governance. The discharge of phenolic substances is strictly controlled at home and abroad. [0003] The treatment of phenolic industrial wastewater has also become one of the hot research topics. At present, the adsorption method can generally be used for the treatment of wastewater containing phenolic substances, and the adsorbent o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/461C02F1/467C02F101/34C02F101/36
CPCC02F1/46109C02F1/4672C02F2001/46133C02F2101/345C02F2101/36C02F2201/461
Inventor 李媚陈熠嘉覃琴廖安平谢树明蓝平谢涛
Owner GUANGXI UNIV FOR NATITIES
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