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Novel browning treatment fluid for printed circuit board

A treatment liquid and browning technology, which is applied in the secondary treatment of printed circuits, printed circuits, printed circuit manufacturing, etc., can solve the problems of short processing time and poor tear strength, and achieve improved peel strength and good thermal shock resistance , Improve the effect of corrosion inhibition efficiency

Active Publication Date: 2017-09-22
BOMIN ELECTRONICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

This patented technology allows creators to selectively prevent or reduce damage caused by certain substances from affecting electronic devices during manufacturing processes such as printing circuit boardings. It involves treating an acidic copper surface (Cu2O2) layer that contains nitrous oxide (NO), hydrogen peroxy radicals (HOO· ), oxygen free radicals, water vapor molecules, etc.) with specific chemical structures called chlorosulfonated polyimides (CSPI). These chemistries have powerful binding properties towards metals like iron, nickel, cobalt, chromium, silver, gold, platinum, rhodium, ruthenium, tantaluminum, lanthanum, ceramics, polymers, rubbers, plasticizers, waxes, lubricants, greases, fats, polysaccharides, proteins, nucleic acids, carbohytes, mineral oil residue, organisms, bacteria, fungi, yeast cells, tissues, tumours, cellular membranes, enzyme systems, DNA sequences, antibiotic agents, cytokines, growth factors, hormones, histochemistry techniques, environmental impact studies, gene expression analysis methods, biological research tools, pharmacy testing procedures, and other applications involving these materials.

Problems solved by technology

Technological Problem: Current methods for producing multiplayer circuits involve attaching two types of materials together at once called bimodies that help connect them well without causing damage from environmental factors like humors and oxygen. However current techniques require expensive equipment and complicated processes, making these approaches less desirable than simpler alternatives. There is therefore a technical issue related to finding ways to increase the adhesion power of both the outermost part of the dielectric layer and other parts of the device's internal layer while maintaining desired characteristics including heat dissipativity, resistive property, insulation reliability, and compatibility with electrode coatings.

Method used

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  • Novel browning treatment fluid for printed circuit board
  • Novel browning treatment fluid for printed circuit board
  • Novel browning treatment fluid for printed circuit board

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A novel browning treatment liquid, its composition is as follows:

[0041]

[0042]

[0043] According to the aforementioned browning treatment process, the browning solution is sprayed horizontally in the PVC browning tank to brown the pre-soaked PCB surface, the browning time is 50s, and the temperature is 35°C.

[0044] After testing, a uniform brown-black copper surface with a microetching depth of 1.44um can be obtained after browning. The surface roughness after browning was characterized by a TR200 roughness meter. The results are shown in Table 1. Using a SEM microscope to observe the copper surface, it can be observed that the copper surface has a fine and uniform honeycomb structure. These honeycomb structures endow the treated copper surface with better bonding force, which is conducive to increasing the copper / resin bond during the lamination process. The specific surface area of ​​the indirect contact can promote the cross-linking reaction between the...

Embodiment 2

[0046] A novel browning treatment liquid, its composition is as follows:

[0047]

[0048] According to the aforementioned browning treatment process, the browning solution is sprayed horizontally in the PVC browning tank to brown the pre-soaked PCB surface, the browning time is 40s, and the temperature is 35°C.

[0049] The results show that after browning, a uniform brown-black copper surface with a microetching depth of 1.21um can be obtained. The surface roughness after browning is characterized by TR200 roughness meter. The surface has a fine and evenly distributed honeycomb structure. These honeycomb structures endow the treated copper surface with better bonding force, which is beneficial to the pressing of multi-layer boards and prevents the occurrence of burst boards, indicating that the browning liquid has good bonding strength; after lamination, the peel strength between the copper surface and the prepreg is 5.9Ib / in; under the condition of 288 ℃, it can satisfy ...

Embodiment 3

[0051] A novel browning treatment liquid, its composition is as follows:

[0052]

[0053] According to the aforementioned browning treatment process, the browning solution is sprayed horizontally in the PVC browning tank to brown the pre-soaked PCB surface, the browning time is 50s, and the temperature is 35°C.

[0054] The results show that after browning, a uniform brown-black copper surface with a microetch depth of 1.12um can be obtained. The surface roughness after browning was characterized by a TR200 roughness meter. The results are shown in Table 1. Using SEM microscope to observe the copper surface, it can be seen that the copper surface has a fine and evenly distributed honeycomb structure. These honeycomb structures endow the treated copper surface with better bonding force, which is beneficial to the lamination of multi-layer boards and prevents the occurrence of burst boards. , indicating that the browning solution has a good bonding force; the peel strength b...

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PUM

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Abstract

The invention discloses a novel browning treatment fluid for a printed circuit board. Each liter of the browning treatment fluid comprises, by volume or mass, 35-65 ml of H2SO4, 35-60 ml of H2O2, 100-200 mg of CuSO4.5H2O, 3-6 g of ethylene glycol monomethyl ether, 5-10 g of methyl triethoxysilane, 13-19 g of benzotriazole, 0.5-10 g of an inhibitor and 1.2-1.5 g of EDTA, wherein the inhibitor comprises 2-sulfydryl-5-benzimidazole sodium sulfonate dehydrate and amino acid containing N and O heteroatoms. The cost of chemicals adopted by the browning treatment fluid is low, the reaction condition is mild, the treatment time is short, and treatment is stable; the surface of the board is high in acid resistance after the board is browned, the browning effect is good, and high peeling strength and excellent cold-heat impact resistance are achieved; and the problems of pink rings, poor tearing strength, poor acid resistance and the like of an ordinary browning treatment fluid can be effectively solved, and the novel browning treatment fluid has no pungent odor.

Description

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Claims

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Application Information

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Owner BOMIN ELECTRONICS CO LTD
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