Ionic polymer membrane for a carbon dioxide electrolyzer
A carbon dioxide, polymer technology, applied in the field of polymer ion exchange membrane, can solve the problem of lack of geographical storage places and so on
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Embodiment approach 1
[0060] Embodiment 1. A method for the electrochemical reduction of carbon dioxide comprising:
[0061] An electrochemical device is provided comprising an anode, a cathode, and a polymeric anion exchange membrane between the anode and the cathode, wherein the polymeric anion exchange membrane comprises an anion exchange polymer, wherein the anion exchange polymer comprises an anion exchange polymer selected from the group consisting of guanidinium, At least one positively charged group of a guanidinium derivative, an N-alkyl conjugated heterocyclic cation, or a combination thereof;
[0062] introducing a composition comprising carbon dioxide to the cathode; and
[0063] Electrical energy is applied to the electrochemical device to achieve electrochemical reduction of carbon dioxide.
Embodiment approach 2
[0064] Embodiment 2. The method of embodiment 1, wherein the guanidinium derivative is selected from the group consisting of thiouronium, uronium, or combinations thereof.
Embodiment approach 3
[0065] Embodiment 3. The method according to embodiment 1, wherein the N-alkyl conjugated heterocyclic cation is selected from the group consisting of N, N'-disubstituted imidazolium, 1,2,3-trisubstituted imidazolium, N- Substituted pyridiniums, N-substituted isoquinoliniums, N-disubstituted pyrrolidiniums, or combinations thereof.
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