Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of activated zeolite molecular sieve supported titanium dioxide photocatalysis material

A photocatalytic material, zeolite molecular sieve technology, applied in the field of preparation of activated zeolite molecular sieve loaded titanium dioxide photocatalytic material, can solve the problems of weak adsorption performance of natural zeolite and low photocatalytic efficiency

Inactive Publication Date: 2017-02-22
YANCHENG INST OF TECH
View PDF3 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the above-mentioned deficiencies in the prior art, the present invention provides a preparation method of an activated zeolite molecular sieve-loaded titanium dioxide photocatalytic material. The present invention uses activated zeolite-loaded titanium dioxide to improve the adsorption and photocatalytic performance of the photocatalytic material and solve the problem of natural zeolite Its adsorption performance is weak and its photocatalytic efficiency is low.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of activated zeolite molecular sieve supported titanium dioxide photocatalysis material
  • Preparation method of activated zeolite molecular sieve supported titanium dioxide photocatalysis material
  • Preparation method of activated zeolite molecular sieve supported titanium dioxide photocatalysis material

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0024] Such as figure 1 , figure 2 As shown, the present invention provides a kind of preparation method of activated zeolite molecular sieve loaded titanium dioxide photocatalytic material, comprises the following steps:

[0025] Step S1: Activate the natural zeolite molecular sieve to obtain the activated zeolite molecular sieve, which specifically includes, Step S1a: Pour the natural zeolite molecular sieve into a beaker, and rinse with distilled water until the rinse solution is no longer turbid; Step S1b: Wash the natural zeolite molecular sieve Put the molecular sieve together with the beaker into an oven for drying at a temperature of 75-90°C. After drying, move it into a high-temperature furnace for calcination for 0.5-2 hours, and adjust the temperature in the furnace to 170-195°C to obtain activated zeolite molecular sieves.

[0026] Step S2: Mix and stir the activated zeolite molecular sieve, tetrabutyl titanate, acetic acid, nitric acid, and absolute ethanol, and...

Embodiment 1

[0031] The preparation method of the activated zeolite molecular sieve loaded titanium dioxide photocatalytic material with a mass ratio of 1:0.5 comprises the following steps:

[0032] (1) The natural zeolite molecular sieve is activated to obtain activated zeolite molecular sieve:

[0033] Pour a certain amount of natural zeolite molecular sieve (5A) into a beaker, rinse several times with distilled water until the liquid is no longer turbid, then put the cleaned natural zeolite molecular sieve (5A) together with the beaker into an oven for drying, and the oven temperature is 80 °C, after drying, move it into a high-temperature furnace for calcination for 1 hour, and adjust the temperature in the furnace to 180 °C to finally obtain an activated zeolite molecular sieve (5A).

[0034] (2) Mix and stir the activated zeolite molecular sieve, tetrabutyl titanate, acetic acid, nitric acid and absolute ethanol, and obtain the activated zeolite molecular sieve-loaded titanium dioxide ...

Embodiment 2

[0037] The preparation method of the activated zeolite molecular sieve loaded titanium dioxide photocatalytic material with a mass ratio of 1:1 comprises the following steps:

[0038] (1) The natural zeolite molecular sieve is activated to obtain activated zeolite molecular sieve:

[0039] Pour a certain amount of natural zeolite molecular sieve (5A) into a beaker, rinse several times with distilled water until the liquid is no longer turbid, then put the cleaned natural zeolite molecular sieve (5A) together with the beaker into an oven for drying, and the oven temperature is 80 °C, after drying, move it into a high-temperature furnace for calcination for 1 hour, and adjust the temperature in the furnace to 180 °C to finally obtain an activated zeolite molecular sieve (5A).

[0040] (2) Mix and stir the activated zeolite molecular sieve, tetrabutyl titanate, acetic acid, nitric acid and absolute ethanol, and obtain the activated zeolite molecular sieve-loaded titanium dioxide ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Specific surface areaaaaaaaaaaa
Login to View More

Abstract

The invention provides a preparation method of an activated zeolite molecular sieve supported titanium dioxide photocatalysis material. The method comprises the following steps: activating natural zeolite molecular sieve to obtain activated zeolite molecular sieve; and mixing and stirring the activated zeolite molecular sieve, tetrabutyl titanate, acetic acid, nitric acid and anhydrous ethanol, and carrying out ultrasonic treatment, stirring, ageing, drying and calcining to obtain the activated zeolite molecular sieve supported titanium dioxide photocatalysis material. The activated zeolite molecular sieve supported titanium dioxide photocatalysis material has larger specific surface area than an inactivated zeolite supported titanium dioxide material, and the specific surface area of the activated zeolite molecular sieve supported titanium dioxide photocatalysis material reaches 280.1 m<2> / g; the activated zeolite molecular sieve supported titanium dioxide photocatalysis material has better adsorption performance than the inactivated zeolite supported titanium dioxide material, and the adsorption rate of the activated zeolite molecular sieve supported titanium dioxide photocatalysis material reaches 94.7%; and additionally, the activated zeolite molecular sieve supported titanium dioxide photocatalysis material has high photocatalysis performance, and the photocatalysis degradation rate reaches 98.6%. The activated zeolite molecular sieve supported titanium dioxide photocatalysis material has wider aperture distribution than the inactivated zeolite supported titanium dioxide material.

Description

technical field [0001] The invention relates to the field of inorganic non-metallic materials, in particular to a preparation method of an activated zeolite molecular sieve loaded titanium dioxide photocatalytic material. Background technique [0002] Since the 1970s, the first discovery of the phenomenon of titanium dioxide photocatalytic water splitting has opened up people's research on the photoelectric properties of various materials, especially semiconductor materials, and photoelectric materials have been widely used. Among all photocatalytic materials, titanium dioxide is widely used in various fields due to its low price, stable physical properties, strong oxidation ability, strong hydrophilicity, non-toxicity, and energy saving, and has a good application prospect. [0003] In the field of titanium dioxide photocatalysis, most studies use natural zeolite loading to improve its adsorption and photocatalytic performance, and some studies use a series of methods such ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): B01J29/06
CPCB01J21/063B01J29/061B01J35/39
Inventor 奚新国董鹏玉蔡星田浩
Owner YANCHENG INST OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com