Powder paint and painted article
A powder coating and fluororesin technology, applied in powder coatings, polyester coatings, devices for coating liquid on the surface, etc., can solve problems such as insufficient weather resistance of cured films, achieve excellent surface quality, and prevent orange peel Effect
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Embodiment 1
[0258] (manufacturing of powder coatings)
[0259] 51.2 g of cyclohexyl vinyl ether, 13.3 g of 4-hydroxybutyl vinyl ether, 55.8 g of xylene, 15.7 g of ethanol, 5.82 g of potassium carbonate, terperoxide, and 0.7 g of a 50% by mass xylene solution of tert-butyl valerate and 63 g of chlorotrifluoroethylene (CTFE). The temperature was raised slowly, and after reaching 55° C., it was kept for 20 hours. Then, the temperature was raised to 65° C. and maintained for 5 hours. Next, after cooling to room temperature, 0.39 g of a hindered amine-based light stabilizer (manufactured by BASF, Tinuvin (registered trademark) 144) and 0.13 g of hydroquinone as a polymerization inhibitor were added, followed by stirring for 1 hour. Thereafter, residues were removed by filtration, followed by vacuum drying to obtain a powder coating material (1).
[0260] The content of free Cl, metal elements, light stabilizers and polymerization inhibitors in the obtained powder coating (1), the number ave...
Embodiment 2
[0277] Except having changed 5.82 g of potassium carbonates into 2.36 g of potassium hydroxides, it carried out similarly to Example 1, and obtained the powder coating material (2). The content of each component and the number average molecular weight of the fluororesin before and after melt kneading were measured to evaluate the production stability of the powder coating material (2). Furthermore, after obtaining the powder coating material (2') in the same manner as in Example 1, a test piece was prepared and the appearance of the cured film was evaluated.
Embodiment 3
[0279] Except having changed 5.82 g of potassium carbonates into 1.68 g of sodium hydroxide, it carried out similarly to Example 1, and obtained the powder coating material (3). The content of each component and the number average molecular weight of the fluororesin before and after melt kneading were measured to evaluate the production stability of the powder coating material (3). Furthermore, after obtaining the powder coating material (3') in the same manner as in Example 1, a test piece was prepared and the appearance of the cured film was evaluated.
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