Electrochromism-thermochromism dual-response intelligent energy saving device and preparation method thereof
An electrochromic and thermochromic technology, which is applied in building components, buildings, parallel glass structures, etc., can solve the problems of bottlenecks in the further improvement of energy-saving effects, and the preparation method of dual-response intelligent energy-saving devices has not yet been seen. The effect of improving the adjustment ability
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[0037] The preparation method of the electrochromic-thermochromic dual-response intelligent energy-saving device of the present invention comprises the following steps:
[0038] Step 1: configuring an electrochromic precursor solution with a concentration of 0.05-1.5mol / L;
[0039] Step 2: Add VO2 powder to the above solution, the ratio of VO2 powder to metal ion sol is 0.1g:1-5mL;
[0040] Step 3: Disperse the mixture obtained in the previous step for 1-24 hours;
[0041] Step 4: Apply the solution obtained in the previous step on the dual-response intelligent energy-saving film (coating film), and the thickness of the film layer is 50-5000 nm after drying;
[0042] Step 5: Annealing the dual-response intelligent energy-saving film obtained in the previous step to obtain a dual-response intelligent energy-saving film with electrochromic-thermochromic properties;
[0043] Step 6: Add electrolyte solution dropwise on the dual-response intelligent energy-saving membrane obtain...
Embodiment 1
[0050] Disperse 0.1g VO2 powder in 1mL solution with Ti ion concentration of 0.05mol / L, ultrasonicate the mixture for 1h, spin-coat on FTO glass at a spin-coating speed of 1000r / min, then raise the temperature to 300oC under an inert atmosphere, Insulate for 0.5 h; add 0.1 mol / L LiClO4 PC solution dropwise on the film, and cover another piece of FTO glass on top of the film to obtain a device.
Embodiment 2
[0052]Disperse 0.1g VO2 powder in 2mL of a solution with a W ion concentration of 0.1mol / L, and ultrasonically treat the mixture for 2h, spin-coat on ITO glass at a spin-coating speed of 2000r / min, and then heat up to 400oC under an inert atmosphere , keep warm for 2h; add 0.5mol / L LiClO4 PC solution dropwise on the film, cover another piece of ITO glass on top of the film in reverse, and obtain the device
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