A concrete admixture for inhibiting transport of erosive media in marine environments
A concrete admixture and marine environment technology, applied in the field of concrete admixtures, can solve the problem of not fundamentally inhibiting the transmission of erosive media, and achieve the effects of inhibiting the transmission of erosive media, reducing electric flux, and avoiding agglomeration
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Embodiment 1
[0029] 1) Preparation of amino-modified polyether polysiloxane: In a reaction vessel equipped with a stirrer, a reflux condenser, and a thermometer, add 75 g of hydrogen-containing silicone oil, 3 g of allyl glycidyl ether, and 220 g of allyl polysiloxane in sequence. Oxyethylene polyoxypropylene ether, stirred with N2 for 10 minutes, heated up to 90°C, added dropwise a platinum catalyst to react for 4 hours to obtain a polyether / epoxy silicone oil intermediate. Then drop into ethylenediamine at a ratio of 1.05: 1.00 to the epoxy group molar ratio of amine and polyether / epoxy silicone oil intermediate to continue the reaction for 4h. The weight ratio is 8: 2) and the mixed solvent is washed to remove impurities to obtain a viscous liquid.
[0030] 2) Preparation of polypropylmethylsilsesquioxane: In a reaction vessel equipped with a stirrer, a reflux condenser, and a thermometer, add 140ml of methyltriethoxysilane, 60ml of propyltriethoxysilane, 0.0 1mol / L hydrochloric acid 2...
Embodiment 2
[0033] 1) Preparation of amino-modified polyether polysiloxane: In a reaction vessel equipped with a stirrer, a reflux condenser, and a thermometer, add 85g of hydrogen-containing silicone oil, 3.5g of allyl glycidyl ether, and 240g of allyl glycidyl ether in sequence. Polyoxyethylene polyoxypropylene ether, stirred with N2 for 10 minutes, heated up to 90°C, added dropwise a platinum catalyst to react for 4 hours to obtain a polyether / epoxy silicone oil intermediate. Then drop into ethylenediamine at a ratio of 1.05: 1.00 to the epoxy molar ratio of amine and polyether / epoxy silicone oil intermediate to continue the reaction for 4h. The weight ratio is 9: 1) and the mixed solvent is washed to remove impurities to obtain a viscous liquid.
[0034] 2) Preparation of polypropylmethylsilsesquioxane: In a reaction vessel equipped with a stirrer, a reflux condenser, and a thermometer, add 140ml of methyltriethoxysilane, 65ml of propyltriethoxysilane, 0.0 1mol / L hydrochloric acid 20...
Embodiment 3
[0037] 1) Preparation of amino-modified polyether polysiloxane: In a reaction vessel equipped with a stirrer, a reflux condenser, and a thermometer, add 100 g of hydrogen-containing silicone oil, 4 g of allyl glycidyl ether, and 225 g of allyl polysiloxane in sequence. Oxyethylene polyoxypropylene ether, stirred with N2 for 10 minutes, heated up to 90°C, added dropwise a platinum catalyst to react for 4 hours to obtain a polyether / epoxy silicone oil intermediate. Then drop into ethylenediamine at a ratio of 1.05: 1.00 to the epoxy group molar ratio of amine and polyether / epoxy silicone oil intermediate to continue the reaction for 4h. The mixed solvent with a weight ratio of 9:1 was washed to remove impurities to obtain a viscous liquid.
[0038] 2) Preparation of polypropylmethylsilsesquioxane: In a reaction vessel equipped with a stirrer, a reflux condenser, and a thermometer, add 140ml of methyltriethoxysilane, 60ml of propyltriethoxysilane, 0.0 1mol / L hydrochloric acid 20...
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