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Blue glass ink used for ink-jet printing and preparation method thereof

An inkjet printing and glass ink technology, applied in the field of glass decoration materials, can solve the problem that glass ink is not recorded in relevant literature, and achieve the effect of not easy flocculation or precipitation, easy to popularize and use, and low equipment requirements.

Inactive Publication Date: 2016-04-13
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In recent years, research on ceramic inks at home and abroad is relatively common, and research on glass inks has not been recorded in relevant literature.

Method used

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  • Blue glass ink used for ink-jet printing and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A blue glass ink for inkjet printing is prepared by the following method:

[0024] (1) Preparation of inorganic Co-Al blue pigment: weigh 18.45g Co 2 o 3 , 33.02gAl 2 o 3 Mix with 1.37g of ZnO and alcohol, grind for half an hour, until the alcohol is completely volatilized, the raw materials are mixed evenly, react in solid state in a high temperature environment of 1300°C, keep warm for 4 hours, and obtain inorganic Co-Al blue pigment;

[0025] (2) Bi 2 o 3 -B 2 o 3 -SiO 2 Preparation of system glass powder: weigh 200gBi 2 o 3 , 50gB 2 o 3 (Courtesy of HBO 3 Introduced), 40gAl 2 o 3 , 15gMgO, 75gSiO 2 , 10gZrO 2 , 4gTiO 2 , 30gLi 2 O (by Li 2 CO 3 introduced), 32.5gNa 2 O (by Na 2 CO 3 introduced), 32.5gK 2 O(by K 2 CO 3 introduced), mixed evenly, melted in a high-temperature environment of 950°C for 2 hours, poured the high-temperature glass liquid directly into cold water to quench, dried and ground the quenched glass to obtain Bi 2 o 3 -B...

Embodiment 2

[0030] A blue glass ink for inkjet printing is prepared by the following method:

[0031] (1) Preparation of inorganic Co-Al blue pigment: weigh 17.96g Co 2 o 3 , 32.08gAl 2 o 3 Mix with 1.28g of ZnO and alcohol, grind for half an hour, until the alcohol is completely volatilized, the raw materials are mixed evenly, react in solid phase in a high temperature environment of 1200°C, keep warm for 4 hours, and obtain inorganic Co-Al blue pigment;

[0032] (2) Bi 2 o 3 -B 2 o 3 -SiO 2 Preparation of system glass powder: weigh 180gBi 2 o 3 , 50gB 2 o 3 (Courtesy of HBO 3 Introduced), 50gAl 2 o 3 , 20gCaO, 75gSiO 2 , 10gZrO 2 , 20gLi 2 O (by Li 2 CO 3 introduced), 37.5gNa 2 O (by Na 2 CO 3 introduced), 37.5gK 2 O(by K 2 CO 3 introduced), mixed evenly, melted in a high temperature environment of 1100°C for 0.5h, poured the high temperature glass liquid directly into cold water for quenching, dried and ground the quenched glass to obtain Bi 2 o 3 -B 2 o 3 ...

Embodiment 3

[0037] A blue glass ink for inkjet printing is prepared by the following method:

[0038] (1) Preparation of inorganic Co-Al blue pigment: weigh 18.08g Co 2 o 3 , 32.77gAl 2 o 3 Mix with 1.34g of ZnO and alcohol, grind for half an hour, until the alcohol is completely volatilized, the raw materials are mixed evenly, react in solid state at 1350°C, and keep warm for 2 hours to prepare inorganic Co-Al blue pigment;

[0039] (2) Bi 2 o 3 -B 2 o 3 -SiO 2 Preparation of system glass powder: weigh 220gBi 2 o 3 , 50gB 2 o 3 (Courtesy of HBO 3 Introduced), 50gAl 2 o 3 , 15gMgO, 85gSiO 2 , 5gTiO 2 , 30gLi 2 O (by Li 2 CO 3 introduced), 35gNa 2 O (by Na 2 CO 3 introduced), 35gK 2 O(by K 2 CO 3 introduced), mixed evenly, melted in a high-temperature environment of 850°C for 2 hours, poured the high-temperature glass liquid directly into cold water to quench, dried and ground the quenched glass to obtain Bi 2 o 3 -B 2 o 3 -SiO 2 System glass powder;

[0040]...

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Abstract

The invention belongs to the field of glass decoration materials and in particular relates to blue glass ink used for ink-jet printing and a preparation method thereof. The blue glass ink comprises the following components by mass percent: 30-60% of solid components, 35-65% of a solvent, 3-5% of surfactants and 2-6% of other additives, wherein the solid components are prepared by founding, quenching and grinding an inorganic Co-Al blue pigment and Bi2O3-B2O3-SiO2 system glass powder. The blue glass ink and the preparation method have the beneficial effects that the solid components of the glass ink are uniformly dispersed in the solvent, a suspended phase is not easy to flocculate or precipitate and has good stability, and is in smaller grain sizes, the solid components can not block or abrase printer nozzles; the blue glass ink has good colour development effects; the preparation process is simple, is low in production cost and equipment requirements and is convenient to popularize and use by enterprises.

Description

technical field [0001] The invention belongs to the field of glass decoration materials, and in particular relates to a blue glass ink for inkjet printing and a preparation method thereof. Background technique [0002] With the faster and faster development of human civilization, today's design presents a more avant-garde development trend. With the advantages of strong decorative performance and powerful functions, decorative glass is used more and more in modern living space, and has developed rapidly, and is accepted and loved by most people. At present, inkjet printing, a new technology for moldless molding, is becoming a research hotspot all over the world, especially in the field of decorative ceramics, and it is emerging in the field of glass. Inkjet printing method is a new type of decoration technology with great potential. This method is to make colorants into inks of various colors for glass surface decoration, and to print multi-color inks directly on the glass ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D11/36C09D11/38C09D11/30
CPCC09D11/36C09D11/30C09D11/38
Inventor 程金树彭小晋吴亚张奇袁坚
Owner WUHAN UNIV OF TECH
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