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A glaze material manufactured by utilization of tailings and a glazing process thereof

A resource and tailings technology, applied in the field of glaze and its glazing process, can solve the problems of little change in surface color and pattern effect, unused tailings slag, environmental pollution, etc., so as to improve the comprehensive utilization rate of resources and maintain recyclability The effect of development and reduction of production cost

Active Publication Date: 2014-09-10
苏友谊
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] my country is rich in iron ore resources and has a huge reserve. After mining and purification, the tailings slag has not been used. The tailings slag produced in the country exceeds 100 million tons every year. As much as 4 million tons, these tailings are piled up like a mountain, which not only seriously pollutes the surrounding area, but also wastes a lot of resources
Tailings occupy a large amount of land, causing water and soil erosion and environmental pollution, and it is urgent to solve them. Therefore, it is urgent to develop a practical technology that can use large quantities of tailings for reproduction to solve the comprehensive utilization of tailings.
[0005] In the current production, in order to achieve stable color, no color difference, and reduce glaze defects, colored glaze ceramic products generally adopt a second firing process. The disadvantage of this production method is that the green body is first bisque fired to eliminate The structural water and organic matter in the green body make the carbonate decompose and discharge gas to avoid pinholes in the glaze layer; the surface color and pattern effect change less, because all colors are obtained by coloring the clay material, so there are fewer types of colors, plus Due to the limitation of the fabric method during production, only some fixed patterns can be produced, and the pattern changes are single

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] 52% of feldspar, 12% of quartz, 21% of iron ore tailings, 4% of limestone, 5% of kaolin and 6% of ashes, the weight ratio of the components is: 2 parts K 2 O, 6 copies of AL 2 o 3 , 63 SiO 2 , 4 copies of P 2 o 5 , 4 Na 2 O, 7 Fe 2 o 3 , 10 parts of CaO and 6 parts of MgO, put them into the ball mill for ball milling, add water, and the ball milling time is 8 hours. After uniform mixing and stirring and fully dissolving, the glaze slurry is obtained. The remaining 0.01% is sieved; the above ball-milled glaze slurry is released from the ball mill, stored in the slurry storage tank and stirred; the glaze slurry passes through a 200-mesh sieve, and the fully suspended glaze slurry is coated on the surface of the body with a concentration of 40 Baume degrees , the thickness of the glaze on the surface of the green body is 0.7mm; when the glaze slurry is applied to the surface of the green body, the green body is wiped with water and dried, and the moisture content of...

Embodiment 2

[0037] 46% feldspar, 22% quartz, 15% iron ore tailings, 5% limestone, 3% kaolin and 9% ashes, the weight ratio of the components is: 3 parts K 2 O, 7 copies of AL 2 o 3 , 58 SiO 2 , 5 copies of P 2 o 5 , 3 Na 2 O, 4 Fe 2 o 3 , 14 parts of CaO and 4 parts of MgO, put them into the ball mill for ball milling, add water, and the ball milling time is 8.5 hours. After uniform mixing and stirring and fully dissolving, the glaze slurry is obtained, and the fineness of the glaze slurry is controlled at a million-hole sieve The remaining 0.008% is sieved; release the above ball-milled glaze slurry from the ball mill, store it in the slurry storage tank and stir; pass the glaze slurry through a 200-mesh sieve, and apply the fully suspended glaze slurry on the surface of the green body with a concentration of 39 degrees Baume , the thickness of the glaze on the surface of the green body is 0.4mm; when the glaze slurry is applied to the surface of the green body, the green body is ...

Embodiment 3

[0039] 59% feldspar, 17% quartz, 17% iron ore tailings, 2% limestone, 2% kaolin and 3% ashes, the weight ratio of the components is: 2 parts K 2 O, 6 copies of AL 2 o 3 , 70 parts of SiO 2 , 3 copies of P 2 o 5 , 2 Na 2 O, 5 Fe 2 o 3 , 6 parts of CaO and 6 parts of MgO, put them into the ball mill for ball milling, add water, and the ball milling time is 9 hours. After uniform mixing and stirring and fully dissolving, the glaze slurry is obtained. The remaining 0.004% is sieved; release the above ball-milled glaze slurry from the ball mill, store it in the slurry storage tank and stir; pass the glaze slurry through a 200-mesh sieve, and apply the fully suspended glaze slurry on the surface of the body with a concentration of 42 degrees Baume , the thickness of the glaze on the surface of the green body is 0.6mm; when the glaze slurry is applied to the surface of the green body, the green body is wiped with water and dried, and the water content of the green body is cont...

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PUM

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Abstract

The invention discloses a glaze material manufactured by utilization of tailings. The glaze material comprises 40-65% of feldspar, 10-25% of quartz, 15-30% of iron ore mine tailings, 0-10% of limestone, 0-10% of kaolin and 0-10% of bone ash. The glaze material comprises following components by weight: 1-5 parts of K2O, 1-8 parts of Al2O3, 55-70 parts of SiO2, 1-5 parts of P2O5, 1-5 parts of Na2O, 1-8 parts of Fe2O3, 5-15 parts of CaO and 1-8 parts of MgO. The invention also discloses a glazing process of the glaze material manufactured by utilization of the tailings. The glazing process includes: adding the materials into a ball grinder and performing ball-milling, adding water, uniformly mixing, stirring and dissolving to obtain glaze slurry, with the fineness of the glaze slurry being controlled to be less than 0.01% of residue on sieve of a ten-thousand hole sieve; discharging the glaze slurry and stirring; sieving the glaze slurry with a sieve having a size of 200 meshes, applying the fully suspended glaze slurry onto the surface of a green body with the concentration being 38-46 baume degrees and the thickness of the glaze slurry on the surface of the green body being 0.2-1.2 mm; and subjecting the green body to high-temperature sintering, and cooling in furnace to room temperature after the sintering is finished to obtain a ceramic product. By adoption of a one-time sintering process, the product quality can reach that of secondary sintering and the product energy consumption is reduced.

Description

technical field [0001] The invention relates to raw materials for ceramic products, and more particularly relates to a glaze made from tailings resources and a glazing process thereof. Background technique [0002] With the rapid development of the economy and society, people's quality of life is improving day by day, and the concept of consumption is also constantly changing, requiring that ceramic products should not only be practical, but also artistic and ornamental. The existing glaze color can be divided into high temperature glaze and low temperature glaze according to the firing temperature; according to the appearance characteristics, it can be divided into transparent glaze, opacity glaze, colored glaze, glossy glaze, matte glaze, crackle glaze (open sheet), crystal glaze and so on. [0003] K based on ceramic production 2 O-AL 2 o 3 -SiO 2 The phase diagram of the ternary system and the color development principle of iron oxides under different conditions: th...

Claims

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Application Information

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IPC IPC(8): C04B41/86
Inventor 苏友谊
Owner 苏友谊
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