Resin foam and production method therefor

A resin foam, foam forming technology, applied in the direction of chemical instruments and methods, synthetic resin layered products, packaging items, etc., can solve the problems of deterioration, reduced sealing, weak strength, etc., and achieve excellent deformation recovery , The effect of less shrinkage of the bubble structure and less shrinkage of the bubble structure

Inactive Publication Date: 2013-10-30
NITTO DENKO CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, these foams have the following disadvantages: weak strength, poor flexibility, poor cushioning properties, poor deformation recovery and reduced sealing performance especially when kept compressed at high temperature
[0007] In addition, in the above-mentioned thermoplastic resin foam based on thermoplastic polyurethane and thermoplastic elastomer, in the temperature range from the heat-resistant temperature limit of 80°C or higher, there may be cases where sufficient recovery cannot be exhibited due to plasticization of the material. , Deterioration due to heat, etc.

Method used

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  • Resin foam and production method therefor
  • Resin foam and production method therefor
  • Resin foam and production method therefor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1)

[0147] Acrylic elastomer composed of butyl acrylate: 85 parts by weight, acrylonitrile: 15 parts by weight, and acrylic acid: 6 parts by weight (acrylic acid: 5.67 wt%, weight average molecular weight (polystyrene conversion molecular weight): 2.17 million, vitrified Transition temperature: -20°C): 100 parts by weight, as an active energy ray-curable compound, polypropylene glycol diacrylate (bifunctional acrylate, trade name "ARONIX M270", manufactured by Toagosei Co., Ltd., glass transition temperature:- 32°C): 45 parts by weight, trimethylolpropane trimethacrylate (trifunctional acrylate, trade name "NK ESTER TMPT", as an active energy ray curable compound), manufactured and manufactured by Shin Nakamura Chemical Industry Co., Ltd. Glass transition temperature in homopolymer: 250°C or higher): 30 parts by weight, as inorganic particles, magnesium hydroxide (trade name "EP1-A", manufactured by Kamishima Chemical Industry Co., Ltd.): 50 parts by weight, as elasticity Hexamethy...

Embodiment 2)

[0154] Acrylic elastomer composed of butyl acrylate: 85 parts by weight, acrylonitrile: 15 parts by weight, and acrylic acid: 6 parts by weight (acrylic acid: 5.67 wt%, weight average molecular weight (polystyrene conversion molecular weight): 2.17 million, vitrified Transition temperature: -20°C): 100 parts by weight, as an active energy ray-curable compound, polypropylene glycol diacrylate (bifunctional acrylate, trade name "ARONIX M270", manufactured by Toagosei Co., Ltd., glass transition temperature:- 32°C): 30 parts by weight, trimethylolpropane trimethacrylate (trifunctional acrylate, trade name "NK ESTER TMPT", as an active energy ray curable compound, manufactured and manufactured by Shin Nakamura Chemical Industry Co., Ltd.) Glass transition temperature when homopolymer: 250°C or higher): 45 parts by weight, magnesium hydroxide as inorganic particles (trade name "EP1-A", manufactured by Kamishima Chemical Industry Co., Ltd.): 50 parts by weight, as Hexamethylene diami...

Embodiment 3)

[0161] Acrylic elastomer composed of butyl acrylate: 85 parts by weight, acrylonitrile: 15 parts by weight, and acrylic acid: 6 parts by weight (acrylic acid: 5.67 wt%, weight average molecular weight (polystyrene conversion molecular weight): 2.17 million, vitrified Transition temperature: -20°C): 100 parts by weight, ethoxylated bisphenol A diacrylate (a bifunctional acrylate, trade name "A-BPE30"," Shin Nakamura Chemical Industry Co., Ltd.) as an active energy ray curable compound Glass transition temperature at the time of manufacture and homopolymer: 250°C or higher): 30 parts by weight, as active energy ray curable compound trimethylolpropane trimethacrylate (trifunctional acrylate, trade name " "NK ESTER TMPT", manufactured by Shinnakamura Chemical Industry Co., Ltd., glass transition temperature when homopolymer is made: 250°C or more): 45 parts by weight, magnesium hydroxide as inorganic particles (trade name "EP1-A" , Kamishima Chemical Industry Co., Ltd.): 50 parts b...

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Abstract

Provided is a resin foam having excellent strain recovery, in particular having little shrinkage of the foam structure at high temperatures caused by the recovery force of the resin and excellent strain recovery at high temperatures. This resin foam is characterized by: being obtained from a resin composition including an elastomer and an active energy ray curable compound; having a glass transition temperature of 30°C or less, found by dynamic viscoelastic measurement of a measurement sample in a non-foamed state; and having a storage modulus (E') of 1.0 × 107 Pa or more at 20°C, found by dynamic viscoelastic measurement of the measurement sample in a non-foamed state.

Description

Technical field [0001] The present invention relates to a resin foam excellent in cushioning properties and deformation recovery properties (compression set properties) and a method for producing the same. In detail, it relates to internal insulators, cushioning materials, sound insulation materials, heat insulating materials, food packaging materials, clothing materials, and building materials, which are useful as internal insulators, cushioning materials, sound insulation materials, building materials for electronic devices, etc., have cushioning properties, and are particularly excellent in deformation recovery at high temperatures. Resin foam and its manufacturing method. Background technique [0002] Conventionally, foams used as internal insulators, cushioning materials, sound insulation materials, heat insulating materials, food packaging materials, clothing materials, and building materials for electronic devices, etc., have been combined as components from their tightnes...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J9/12
CPCC08J9/12C08F220/46C08J9/122B32B3/04B32B7/12B32B27/065B32B2307/304B32B2307/51B32B2307/56B32B2437/00B32B2439/70C08J2201/026C08J2201/03C08J2203/06C08J2203/08C08J2205/06C08J2300/22C08J2300/26C08J2333/08C08J2433/08B29C44/00B29K2021/00B29K2105/04C08J9/06C08J9/08C08J9/10
Inventor 金田充宏山本孝幸太田美绘河野吉纪安田广论神取佑子吉田敬
Owner NITTO DENKO CORP
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