A method for treating coke oven gas desulfurization by-product sulfur paste
A technology for coke oven gas and by-products, applied in chemical instruments and methods, thiosulfate/dithionite/polythionite, thiocyanic acid, etc. Discharge and other issues to avoid further pollution, high recycling rate, and ensure cleaner production
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Embodiment 1
[0034] refer to figure 1 , coke oven gas desulfurization and decyanation by-product sulfur paste 1000kg (the composition content is about 42% of sulfur, 13% of sulfur salt (ammonium thiosulfate, ammonium thiocyanate, ammonium sulfate), 3% of solid impurities such as coal ash , moisture 40%, desulfurization catalyst 0.02%, a small amount of coal tar components such as naphthalene 300ppm, NH 3 1.2%)
[0035] Sulfur paste processing steps:
[0036] Step 1: Dissolving sulfur and removing impurities: 1000kg of desulfurization paste and 8000kg of tetrachlorethylene are stirred and mixed in the dissolution tank at a weight ratio of 1:8, and the temperature is raised to 110°C. After maintaining this temperature for 1 hour, the tetrachlorethylene The upper brine-containing phase is separated and introduced into the desulfurization waste liquid salt extraction process, and the remaining organic phase is subjected to heat preservation and thermal filtration to obtain sulfur-containing ...
Embodiment 2
[0041] refer to figure 1 , Coke oven gas desulfurization and decyanation by-product sulfur paste 1000kg (sulfur 39%, sulfur salt (ammonium thiosulfate, ammonium thiocyanate, ammonium sulfate) 14%, coal ash and other solid impurities 2%, moisture 43%, desulfurization catalyst 0.03%, a small amount of coal tar components such as naphthalene 400ppm, NH 3 1.5%)
[0042] Sulfur paste processing steps:
[0043] Step 1: Dissolving sulfur and removing impurities: 1000kg of desulfurization paste and 8000kg of tetrachlorethylene are stirred and mixed in the dissolution tank at a weight ratio of 1:8, and the temperature is raised to 100°C. After maintaining this temperature for 1 hour, the tetrachlorethylene The upper brine-containing phase is separated and introduced into the desulfurization waste liquid salt extraction process, and the remaining organic phase is subjected to heat preservation and thermal filtration to obtain sulfur-containing perchlorethylene filtrate and a small amo...
Embodiment 3
[0047] Embodiment 3: refer to figure 2
[0048] Waste liquid treatment:
[0049] 1000kg of waste liquid from coke oven gas desulfurization and decyanation paste (ammonium thiocyanate content 13%, ammonium thiosulfate content 9%, ammonium sulfate content 8%)
[0050] Step 1: Decolorization and impurity removal: add 1kg of 0.1% (w / w) activated carbon to the desulfurization waste liquid, keep it warm at 100°C for 30 minutes, and then filter to obtain the decolorized filtrate and activated carbon filter cake (the activated carbon filter cake will be sent to a professional recycling enterprise for regeneration treatment ).
[0051] Step 2: Concentrate the decolorized solution under reduced pressure: Concentrate the filtrate of step 1 under reduced pressure at 70°C (vacuum degree 70mmHg) until the specific gravity of the system is 1.24 (g / ml) and stop concentrating (water content is 18% (w / w) ), transfer the concentrated system to the crystallizer with heat preservation, distill...
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