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Universal binder resin for water-based plastic surface printing ink, preparation method thereof and printing ink using binder resin

A technology of ink linking material and plastic surface, which is applied in the field of ink to achieve the effect of bright color, good adhesion and simple preparation method

Active Publication Date: 2013-07-03
广东天龙油墨有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the above problems, the present invention provides a binder resin for plastic surface printing ink that is alcohol-water-soluble or water-soluble, does not use solvents such as benzene and ketones, and overcomes the environmental pollution problems caused by solvents such as benzene and ketones.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] React according to the formula of table 1:

[0038] Table 1

[0039] raw material name parts by weight Rosin resin 11.5 maleic anhydride 2.89 glycerin 0.62 Versamid 115 7.5 678 7.5 monoethanolamine 3 ammonia 6 Deionized water 61 Total 100

[0040] Note: Versamid 115 is Corning reactive polyamide

[0041] 678 is SC Johnson solid alkali soluble acrylic resin

[0042] a) Put the rosin into a reaction kettle equipped with a reflux condenser, protect it with nitrogen, heat to 180°C to completely melt the rosin, add maleic anhydride to react at a constant temperature of 180~200°C for 2 hours;

[0043] b) Continue to heat up to 250°C, add glycerol polyol for esterification reaction, keep the temperature at 260~275°C for 40-60 minutes;

[0044] c) After step b is completed, lower the temperature to 230~240°C, add Versamid 115 and react at constant temperature for 1~2 hours;

[0045] d) Maintain 230...

Embodiment 2

[0051] The formula of following table 2 is reacted:

[0052] Table 2

[0053] raw material name parts by weight Rosin resin 12.2 maleic anhydride 3 glycerin 0.91 Versamid 115 9.5 0663 6.35 monoethanolamine 3 ammonia 8 Deionized water 57 Total 100

[0054] Note: Versamid 115 is Corning reactive polyamide

[0055] 0663 is self-made solid alkali-soluble acrylic resin

[0056]a) Put the rosin into a reaction kettle equipped with a reflux condenser, heat to 180°C under nitrogen protection to completely melt the rosin, add maleic anhydride to react at a constant temperature of 180~200°C for 2 hours;

[0057] b) Continue to heat up to 250°C, add glycerol polyol for esterification reaction, keep the temperature at 260~275°C for 40-60 minutes;

[0058] c) After step b is completed, lower the temperature to 230~240°C, add Versamid 115 and react at constant temperature for 1~2 hours;

[0059] d) Maintain 230~240℃,...

Embodiment 3

[0064] The formula of following table 3 is reacted:

[0065] table 3

[0066] raw material name parts by weight Rosin resin 13.4 maleic anhydride 3.37 glycerin 0.72 Macromelt 6239 8.75 678 8.75 monoethanolamine 3.5 ammonia 7 Deionized water 54.5 Total 100

[0067] Note: Macromelt 6239 is a polyamide oligomer of Henkel

[0068] 678 is SC Johnson solid alkali soluble acrylic resin

[0069] a) Put the rosin into a reaction kettle equipped with a reflux condenser, heat to 180°C under nitrogen protection to completely melt the rosin, add maleic anhydride to react at a constant temperature of 180~200°C for 2 hours;

[0070] b) Continue to heat up to 250°C, add glycerol polyol for esterification reaction, keep the temperature at 260~275°C for 40-60 minutes;

[0071] c) After step b is completed, lower the temperature to 230~240°C, add Macromelt 6239 for constant temperature reaction for 1~2 hours;

[0072] ...

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Abstract

The invention specifically relates to a universal binder resin for a water-based plastic surface printing ink, a preparation method thereof and a printing ink using the binder resin, belonging to the field of printing inks. The binder resin provided by the invention is prepared through the following steps: subjecting a modified rosin resin and an amide oligopolymer to a condensation reaction so as to produce an intermediate product with a carboxyl group; allowing the intermediate product and a resin containing multiple carboxyl groups to undergo polymerization; and carrying out amination so as to obtain the water-soluble binder resin. Because of introduction of an acylamino group, the binder resin has good adhesion, luster and printing adaptability on a variety of plastic film substrates. According to the invention, the preparation method for the binder resin is simple; the prepared printing ink has good printing adaptability and is applicable to surface printing of a variety of plastic film substrates, and since water is used as a solvent, the printing ink has no irritant gas and is green and environment-friendly.

Description

technical field [0001] The invention relates to the field of inks, in particular to a general-purpose water-based plastic surface printing ink binder and a preparation method thereof, and to an ink using the binder resin. Background technique [0002] In recent years, with the continuous improvement of people's living standards, the packaging industry has developed rapidly, which has led to the continuous development of plastic gravure ink technology and the market. Its application range includes almost all packaging fields, such as food, medicine, agricultural and sideline products, and daily necessities. Various types of plastic film substrate packaging in other industries. However, the printing inks currently used in the plastic packaging industry are still traditional solvent series, which contain a large amount of toxic and harmful chemical substances, including residual solvents, organic volatiles, and polycyclic aromatic hydrocarbons. Although traditional plastic pri...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G81/00C09F1/04C09D11/08
Inventor 艾平科王大田余中华
Owner 广东天龙油墨有限公司
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