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Lubricant composition for internal combustion engines

A lubricating oil composition and the technology of the composition are applied in the field of lubricating oil compositions of gasoline and diesel engines, which can solve the problems of limited antioxidant properties, turbid additives, and high product cost, and achieve improved anti-friction and anti-wear performance, good High temperature cleaning, good economical effect

Active Publication Date: 2012-05-30
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the preparation process of alkyl salicylate is complex and the product cost is high
[0022] Calcium sulfonate and alkyl salicylate are compounded to prepare lubricating oil composition. Although the advantages of both are combined, the additives are prone to turbidity or precipitation during the storage and use of the oil, which affects its further use.
[0023] Generally, a small amount of additives such as overbasic magnesium sulfonate, overbasic sodium sulfonate or overbasic potassium sulfonate will be introduced into compositions using overbasic calcium sulfonate as a metal detergent. The introduction of overbasic magnesium salt It has a certain impact on the high-temperature detergency of the composition, and the introduction of high-basic sodium sulfonate or potassium will reduce the anti-wear performance of the lubricating oil composition. At the same time, due to the high-basicity sodium or potassium salt anti-oxidation properties Due to the limitations, more antioxidants need to be introduced, which affects the economy of the formula

Method used

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  • Lubricant composition for internal combustion engines
  • Lubricant composition for internal combustion engines

Examples

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example 1~3

[0054] Compositions of the present invention are formulated.

[0055] 150SN, 500SN, and 150BS are prepared into base oil at a mass ratio of 14:5:1, and the viscosity at 100°C is 14.5mm 2 / s, its performance meets the requirements of 15W / 40 base oil.

[0056] Sulfonate detergents, friction modifiers, antioxidants, ashless dispersants, viscosity index improvers and pour point depressants are added to the prepared base oil to prepare lubricating oil compositions. The names and indicators of the additives used are as follows:

[0057] Sulfonate detergents:

[0058] Ultra-high base value calcium sulfonate: a base value of 405 mgKOH / g, a calcium content of 14.5% by mass, and a sulfur content of 1.43% by mass.

[0059] High base value calcium sulfonate: a base value of 311 mgKOH / g, a calcium content of 10.2% by mass, and a sulfur content of 1.8% by mass.

[0060] Low base value lithium sulfonate: a base value of 135 mgKOH / g, a lithium content of 1.91% by mass, and a sulfur content...

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Abstract

A lubricant composition for internal combustion engines is provided, which comprises a lubricant base oil and a sulfonate detergent, wherein the content of the sulfonate detergent is 0.8% to 1.5% (by weight) calculated on the basis of the composition; the sulfonate detergent comprises calcium sulfonate with a ultra-high base number more than 400 mg KOH / g, calcium sulfonate with a high base number of 300 to 350 mg KOH / g and lithium sulfonate with a base number less than 150 mg KOH / g. The lubricant composition has low contents of S, P and sulfuric ash, the additives used have a low cost and are easily available, and the economical efficiency is better. The lubricant composition can not only meet the requirements for normal operation of engines but also meet the requirements for normal operation of automobile exhaust gas recirculation (EGR) systems.

Description

technical field [0001] The present invention is an internal combustion engine lubricating oil composition, specifically, a lubricating oil composition for gasoline and diesel engines. Background technique [0002] With the increase of the number of automobiles in our country, automobile exhaust emission has become the main factor of polluting the environment. The exhaust gas contains substances that seriously pollute the air such as carbon monoxide, hydrocarbons and nitrogen oxides. Therefore, it is very necessary to filter and absorb vehicle exhaust. The current method of treating automobile exhaust is to install an exhaust converter, and the three-way catalyst in the converter oxidizes carbon monoxide and hydrocarbons in the exhaust to carbon dioxide and water, and nitrogen oxides are reduced to nitrogen and oxygen. [0003] Three-way catalysts are very sensitive to sulfur, phosphorus and ash in engine lubricating oil. Excessive sulfur content will lead to an increase in...

Claims

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Application Information

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IPC IPC(8): C10M135/10C10M141/08C10M161/00C10N40/25C10N30/10C10N30/06
Inventor 刘依农段庆华
Owner CHINA PETROLEUM & CHEM CORP
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