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Sealing method of borosilicate glass and kovar alloy of solar collector tube

A technology of solar collector tubes and high silicon boron, applied in the field of solar energy applications, can solve the problems of reduced air tightness of the device, increased production cost of the thermal collector tubes, and unsuitability for large-scale production

Active Publication Date: 2010-07-28
北京天瑞星光热技术有限公司
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AI Technical Summary

Problems solved by technology

[0002] At present, in the manufacture of high-temperature solar vacuum heat collector tubes in metallic glass, due to the certain difference in thermal expansion coefficient between metal and glass, the sealing of metal and glass often cannot be directly sealed. To achieve matching sealing, a Or more than one transition section, the increase of the transition section increases the possibility of air leakage, resulting in a decrease in the airtightness of the entire device; the transition section is too long to increase the proportion of the transition device to the entire heat collecting tube, reducing the heat collecting tube. Heat collection efficiency; the transition glass in the middle has less domestic output and high price, which increases the production cost of heat collection tubes; the process is complicated and not suitable for large-scale production
Other non-matching sealing technologies are not yet mature, the glass tube is easy to burst, and it is difficult to meet the requirements of high temperature work

Method used

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  • Sealing method of borosilicate glass and kovar alloy of solar collector tube
  • Sealing method of borosilicate glass and kovar alloy of solar collector tube

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Embodiment Construction

[0006] see figure 1 , High borosilicate glass 1, Kovar alloy 2 are directly sealed. The expansion coefficients of borosilicate glass 1 and Kovar 2 are 4.8-5.2×10 -6 / °C and 4.7-5.5×10 -6 / °C.

[0007] The direct sealing method of two materials is as follows:

[0008] 1). Pre-oxidize the Kovar alloy 2 first, put the Kovar alloy 2 on the flame and heat and oxidize it while rotating it. At a temperature of 700°C--1000°C, heat the Kovar alloy 2 to dark red. At this time A layer of oxide is uniformly attached to the surface of Kovar 2, and the main component of the oxide is ferrous oxide. The thickness of the oxide layer is 1-2μm, and the surface density is 0.3-0.7mg / m2, which is the best.

[0009] 2). Heat the high-silicon borosilicate glass tube to 450°C-650°C while rotating it. After the glass turns red and soft, insert the oxidized Kovar 2 into the wall of the glass tube by 5-8mm to make the molten glass The tube is evenly coated on the outer wall of the metal tube, and i...

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Abstract

The invention discloses a sealing method of borosilicate glass and kovar alloy of a solar collector tube, which relates to the matching sealing between the borosilicate glass and the kovar alloy under the condition of no transitional glass, and provides a novel method for the production of the metal glass middle-high temperature vacuum solar collector tube. In the method, the difference range of expansion coefficients of the kovar alloy and the borosilicate glass is 5 to 50 percent; the heating temperature at the sealing area is 300 to 1200 DEG C; the length of the sealing interface is about 3 to 8 mm; and the annealing treatment on the borosilicate glass and the kovar alloy are undertaken,the annealing temperature is 300 to 600 DEG C, and the time is 10 to 60 minutes. The method is free from utilizing a glass transitional section, so the production cost is saved, and the utilization rate of the solar collector tube is also improved while the sealing reliability is improved.

Description

technical field [0001] The invention belongs to the field of solar energy application, and in particular relates to a sealing method of high-silicon borosilicate glass and Kovar alloy in a high-temperature solar vacuum heat collection tube in metallic glass. technical background [0002] At present, in the manufacture of high-temperature solar vacuum heat collector tubes in metallic glass, due to the certain difference in thermal expansion coefficient between metal and glass, the sealing of metal and glass often cannot be directly sealed. To achieve matching sealing, a Or more than one transition section, the increase of the transition section increases the possibility of air leakage, resulting in a decrease in the airtightness of the entire device; the transition section is too long to increase the proportion of the transition device to the entire heat collecting tube, reducing the heat collecting tube. Heat collection efficiency; the domestic output of transition glass in ...

Claims

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Application Information

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IPC IPC(8): C03C27/00F24J2/48
CPCY02E10/40
Inventor 陈步亮范兵张秀廷薛文刘雪莲
Owner 北京天瑞星光热技术有限公司
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