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Method and device for extracting heavy metal ions from soil

A technology of heavy metal ions and heavy metals, which is applied in the field of environmental pollution control and can solve problems such as pollution

Inactive Publication Date: 2012-10-17
赵烨 +5
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims at the serious pollution of soil Cd, Cr, Cu, Hg, Pb and Zn, and provides a method and device for extracting heavy metal ions from soil, which can effectively absorb-passivate-solidify-extract soil tillage Active Cd in layer 2+ 、Cr 3+ 、Cu 2+ , Hg 2+ , Pb 2+ and Zn 2+ Plasma, and can maintain soil micro-domain moisture, and release a certain amount of K + ions, and can realize the renewal, purification and recycling treatment of the absorbent inside the heavy metal ion extraction device

Method used

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  • Method and device for extracting heavy metal ions from soil
  • Method and device for extracting heavy metal ions from soil

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0055] Embodiment 1 adopts nano-carbon fiber, activated carbon, acrylamide, potassium acrylate, and potassium sulfide to form a heavy metal ion adsorbent composition, and uses commercially available sludge particles as the carrier of the adsorbent composition, wherein the specifications of nano-carbon fiber are: OD>50nm, ID=25-40, Length=10-20um. The weight proportion of each component in this composition is:

[0056] Nano carbon fiber 0.5%

[0057] Activated carbon 10.00%

[0058] Cationic surfactant 18.00%

[0059] Acrylamide 3.00%

[0060] Potassium acrylate 5.00%

[0061] Potassium sulfide 2.5%

[0062] Sludge particles 61.00%

[0063] The above substances are thoroughly mixed to obtain an adsorbent mixture. The porous hard shell is made of transparent Teflon-FEP material with excellent chemical resistance, strong mechanical impact resistance, and its specification is a round bottom screw cap structure with a diameter of 40mm and a length of 120mm, and the thickness...

Embodiment 2

[0065] Embodiment 2 uses the composition of carbon nanofiber, activated carbon, acrylamide and potassium acrylate to form a heavy metal ion adsorbent composition, and the weight ratio of each component in the composition is:

[0066] Nano carbon fiber 0.30%

[0067] Activated carbon 8.00%

[0068] Cationic surfactant 15.00%

[0069] Acrylamide 3.00%

[0070] Potassium acrylate 3.00%

[0071] Potassium sulfide 1.80%

[0072] Sludge particles 68.90%

[0073] The above substances are fully mixed, and the porous hard shell is made of transparent polyurethane material with excellent chemical resistance, strong mechanical impact resistance, and its specification is a pipe with a diameter of 50mm and a length of 150mm, and its two ends are fastened and fixed The end cap, the tube body and the end cap are distributed with a plurality of through holes with a diameter of 1-2 mm, and the porous hard casing is filled with the heavy metal ion adsorbent composition to form a porous har...

Embodiment 3

[0074] Embodiment 3 uses the composition of carbon nanofiber, activated carbon, acrylamide and potassium acrylate to form a heavy metal ion adsorbent composition, and the weight ratio of each component in the composition is:

[0075] Nano carbon fiber 0.80%

[0076] Activated Charcoal 12%

[0077] Cationic surfactant 20.00%

[0078] Acrylamide 5.00%

[0079] Potassium acrylate 5.00%

[0080] Potassium sulfide 2.50%

[0081] Sludge particles 54.70%

[0082]The porous hard shell is made of transparent polycarbonate material with excellent chemical resistance, strong resistance to mechanical impact, and its specification is a pipe with a diameter of 30mm and a length of 100mm. A plurality of through holes with a diameter of 1-2 mm are distributed on the end cap, and the porous hard casing is filled with the heavy metal ion adsorbent composition to form a porous hard plastic capsule.

[0083] Applied experiments have shown that in various soils that have not yet reached mode...

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Abstract

The invention relates to a method and a device for extracting heavy metal ions from soil, which are used for extracting heavy metal ions from the heavy metal polluted oil. The method comprises the following steps of: forming a heavy metal ion adsorbent by adopting a compound containing carbon nano fibers, active carbon, a cationic surface active agent, acrylamide, potassium acrylate, sludge particles and potassium sulfide; putting the heavy metal ion adsorbent in a porous hard shell to form a porous hard plastic bag; and embedding the porous hard plastic bag into soil for extracting the heavymetal ions. The method and the device for extracting the heavy metal ions from soil aim at the problem of severe pollution of Cd, Cr, Cu, Hg, Pb and Zn of the soil and can effectively absorb, passivate, solidify and extract active ions such as Cd2+, Cr3+, Cu 2+, Hg2+, Pb2+, Zn2+, and the like in plow layers of the soil, maintain microzone water of the soil, release a certain K+ ions and realize the update, the purification and the circular treatment of the absorbent in the device for extracting the heavy metal ions.

Description

technical field [0001] The invention belongs to the environmental pollution control technology, and in particular relates to a method and a device capable of effectively extracting toxic heavy metal ions in soil cultivation layers. Background technique [0002] At present, in view of the prevalence and severity of soil heavy metal pollution, some developed countries have formulated corresponding soil remediation plans. The U.S. federal government has formulated a soil and groundwater remediation plan, and plans to invest tens of billions to hundreds of billions of dollars. In 1994, the United States initiated and established the "Global Soil Remediation Network (Global Soil Remediation Network)". [0003] Throughout the research on remediation of soil heavy metal pollution at home and abroad, traditional heavy metal contaminated soil treatment mainly uses physical or chemical methods such as soil solidification, vitrification, leaching, soil washing, guest soil method, and ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B09C1/00B01J20/24
Inventor 赵烨李强陈志凡朱宇恩杨旭呼红霞
Owner 赵烨
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