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Application and usage of vanadium series catalyst of one-class bidentate N, O coordination

A catalyst and coordination technology, which is applied in the field of copolymerization of ethylene and polar monomers with vanadium-based catalysts, can solve problems that have not been reported in the application, and achieve the effect of avoiding poisoning

Inactive Publication Date: 2009-11-11
CHANGZHOU INST OF ENERGY STORAGE MATERIALS &DEVICES
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

These three patents disclose a series of vanadium-based olefin polymerization catalysts for catalyzing ethylene homopolymerization, ethylene and α-olefin copolymerization, and ethylene and norbornene copolymerization examples, but the use of such catalysts for catalyzing ethylene and α-olefin copolymerization The application of functional monomer copolymerization has not been reported

Method used

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  • Application and usage of vanadium series catalyst of one-class bidentate N, O coordination
  • Application and usage of vanadium series catalyst of one-class bidentate N, O coordination
  • Application and usage of vanadium series catalyst of one-class bidentate N, O coordination

Examples

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Effect test

Embodiment 1

[0026] When embodiment 1 illustrates catalyst catalyzed ethylene / polar α-olefin copolymerization, the copolymerization result of different protecting agent protection 10-undecen-1-alcohols; Hexen-1-ol, Result of copolymerization of ethylene with 3-buten-1-ol, ethylene with 10-undecen-1-ol methyl ester. Example 5 illustrates the polymerization results at different temperatures. Example 6 illustrates the polymerization results after varying the comonomer concentration.

[0027]Embodiment 1a) under a nitrogen atmosphere, under stirring at room temperature, first add anhydrous toluene 50ml and 5M toluene solution 1.0ml of 10-undecen-1-alcohol in a dry 150ml polymerization reactor, then add 2M 2.5 ml of toluene solution of diethylaluminum chloride was used to pretreat 10-undecen-1-ol, and the pretreatment time was 5 minutes. In the above-mentioned pretreated 10-undecen-1-ol reactor, under an ethylene atmosphere, adjust the reaction temperature to 50°C, add 2.0ml of 2M diethylalum...

Embodiment 2

[0062] Under nitrogen atmosphere, under stirring at room temperature, first add 50ml of anhydrous toluene and 1.0ml of 5M 5-hexen-1-ol toluene solution into a dry 150ml polymerization reactor, and then add 2M diethyl chloride 2.5 ml of aluminum toluene solution pretreated 5-hexen-1-ol, and the pretreatment time was 5 minutes. In the above-mentioned pretreated 5-hexen-1-ol reactor, under an ethylene atmosphere, adjust the reaction temperature to 50°C, add 2.0 ml of a toluene solution of 2M diethylaluminum chloride, 0.5M tris 1.0ml of toluene solution of ethyl chloroacetate, and finally 1.0ml of toluene solution of 1.0M bidentate N, O coordinated vanadium olefin polymerization catalyst was added, the ethylene pressure was adjusted to 0.1MPa, and the reaction was polymerized for 10min under stirring. Pour into 0.5% hydrochloric acid ethanol solution by volume, filter, wash with 50ml of ethanol, then wash with 50ml of acetone, and dry in vacuum to obtain a copolymer product. The ...

Embodiment 3

[0075] Under nitrogen atmosphere, under stirring at room temperature, first add 50ml of anhydrous toluene and 1.0ml of 5M toluene solution of 3-buten-1-ol into a dry 150ml polymerization reactor, and then add 2M diethyl chloride 2.5 ml of aluminum toluene solution pretreated 3-buten-1-ol, and the pretreatment time was 5 minutes. In the above-mentioned pretreated 3-buten-1-ol reactor, under an ethylene atmosphere, adjust the reaction temperature to 50° C., add 2.0 ml of a toluene solution of 2M diethylaluminum chloride, 0.5 M tris 1.0ml of toluene solution of ethyl chloroacetate, and finally 1.0ml of toluene solution of 1.0M bidentate N, O coordinated vanadium olefin polymerization catalyst was added, the ethylene pressure was adjusted to 0.1MPa, and the reaction was polymerized for 10min under stirring. Pour into 0.5% hydrochloric acid ethanol solution by volume, filter, wash with 50ml of ethanol, then wash with 50ml of acetone, and dry in vacuum to obtain a copolymer product....

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Abstract

The invention provides an application and a usage of vanadium series catalyst of one-class bidentate N, O coordination. From the angle of preventing functional monomer from poisoning catalyst, the invention selects the vanadium series olefinic polymerization catalyst of one-class bidentate N, O coordination to realize the copolymerization of ethylene and polar monomer under the action of cocatalyst and promoter after different protecting agents pretreat the polar monomer. Through adjusting copolymerization conditions, the invention obtains a series of functional polyolefine with controllable comonomer insertion rate and molecular weight. Especially, the invention realizes the copolymerization between ethylene and 10-hendecene-1-alcohol, between ethylene and 5-hexene-1-alcohol, between ethylene and 3-butylene-1-alcohol or between ethylene and 10-methyl undecylenate.

Description

technical field [0001] The invention relates to the use and usage of a class of bidentate N, O coordinated vanadium catalysts, in particular to a class of bidentate N, O coordinated vanadium catalysts to realize copolymerization of ethylene and polar monomers and a method thereof. Background technique [0002] Polyolefin products are widely used in various fields, bringing revolutionary changes to people's lives. However, the low surface energy of polyolefins and the chemical inertness of the molecules make the functional properties of polyolefins (adhesion, wettability, printing and dyeing properties, gas permeability, and compatibility with other substances, etc.) poor, and it is difficult to meet Demand for ever-increasing properties of polyolefin materials. Therefore, the functionalization of polyolefin materials has been paid more and more attention by people. [0003] A lot of research has been done abroad on the functionalization of polyolefins, and progress has bee...

Claims

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Application Information

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IPC IPC(8): C08F210/02C08F4/68
Inventor 刘靖宇穆景山李悦生李彦国刘三荣
Owner CHANGZHOU INST OF ENERGY STORAGE MATERIALS &DEVICES
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