Tanning method of nano SiO2 or TiO2 tanning agents
A tanning agent and nanotechnology, applied in the field of leather tanning, can solve the problems of not meeting the physical performance requirements at the same time, achieve the effects of shortening the tanning cycle, solving the shortage of chromium resources, and reducing environmental pollution
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Embodiment 1
[0036] (1) Soaking, dehairing, liming, and softening are carried out in accordance with conventional methods;
[0037] (2) Pre-tanning
[0038] Add 100 kg of water to the drum, 100 kg of sheepskin softening skin, 2 kg of oxazolidine tanning agent, control the temperature in the drum at 30°C and turn for 2 hours, then add 2 kg of formic acid with a concentration of 85% by weight to adjust the pH of the solution 4.0, rotate for 1 hour,;
[0039] (3) Squeeze the water, shave it evenly, and control the moisture content of the crust at 40wt%;
[0040] (4) Nano SiO 2 Main tanning
[0041] Add the above-mentioned pre-tanned, squeezed and shaved skin into the drum, and nano-SiO 2 The tanning agent is 8 kg, the temperature in the drum is controlled at 30°C, and the drum is rotated for 4 hours. After the penetration is complete, 1.5 kg of formic acid with a concentration of 85% by weight and 1.5 kg of sulfuric acid with a concentration of 96% by weight are diluted with 150 kg of water and a...
Embodiment 2
[0047] (1) Soaking, dehairing, liming, and softening are carried out in accordance with conventional methods;
[0048] (2) Pre-tanning
[0049] Add 100 kg of water to the drum, 100 kg of pigskin softened skin, 5 kg of modified glutaraldehyde tanning agent, control the temperature in the drum at 33°C for 1 hour, then add 1.5 kg of formic acid with a concentration of 85% by weight to adjust the solution pH value is 4.2, rotate for 2 hours;
[0050] (3) Squeeze the water, shave it evenly, and control the moisture content of the crust at 45% by weight;
[0051] (4) Nano TiO 2 Main tanning
[0052] Add the above-mentioned pre-tanned, squeezed and shaved skin into the drum, and nano-TiO 2 7 kg of tanning agent, control the temperature in the drum at 30°C, and rotate for 5 hours. After the penetration is complete, 2 kg of 85% by weight formic acid and 2 kg of 96% by weight sulfuric acid are diluted with 200 kg of water and added to the drum to adjust the tanning liquid The pH value is 2....
Embodiment 3
[0058] (1) Water soaking, dehairing, liming, softening and pickling shall be carried out in accordance with conventional methods;
[0059] (2) Pre-tanning
[0060] Add 150 kilograms of acid pickling solution and 100 kilograms of pickled rabbit skin to the drum, add 1 kilogram of baking soda and 1.5 kilograms of baking soda, adjust the pH of the solution to 4.0, and rotate for 30 minutes; drain; wash twice with water, drain ; Add 10 kg of white tannin extract and rotate for 2 hours;
[0061] (3) Squeeze the water, shave it evenly, and control the moisture content of the crust at 40wt%;
[0062] (4) Nano SiO 2 Main tanning
[0063] Add the above-mentioned pre-tanned, squeezed and shaved skin into the drum, and nano-SiO 2 6 kg of tanning agent, control the temperature in the drum at 30°C, and rotate for 4 hours. After the penetration is complete, 1 kg of formic acid with a concentration of 85% by weight and 1 kg of sulfuric acid with a concentration of 96% by weight are diluted with ...
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Abstract
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