Natural compound flocculant of chitosan, producing method and uses of the same
A technology of chitosan and flocculant, which is applied in the field of high ammonium nitrogen wastewater treatment, can solve the problems of long hydraulic retention time, difference in flocculation effect, high COD value, etc., and achieve low treatment cost, good pertinence, and good flocculation performance Effect
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[0055] The invention provides a kind of preparation method of chitosan natural composite flocculant, comprising the following steps:
[0056] 1. Select one or several natural materials containing silicates as the main body for mixing;
[0057] 2. Screening, drying, and grinding natural materials containing silicate as the main body into particles with a particle size of 1-300 mesh, and set aside;
[0058] 3. Choose one or several kinds of chitosans with different degrees of polymerization to mix;
[0059] 4. Choose one or several kinds of alkaline substances to mix.
[0060] Instructions:
[0061] 1. First use alkaline substances to adjust the pH value of the monosodium glutamate sewage between 1 and 4;
[0062] 2. Add flocculation aid;
[0063] 3, according to different water quality, will contain silicate class natural material directly add with powder form by the quantity of regulation, and standard addition is based on 5-30% that is equivalent to chemical oxygen demand...
Embodiment 1
[0069] The invention uses meadow soil, chitosan (polymerization degree=90%) and calcium chloride as raw materials. Among them, meadow soil is the main component, particle size: 200-300 mesh, chitosan is the auxiliary flocculant, calcium hydroxide and calcium chloride are the regulator of pH value and flocculation aid respectively. The mass ratio of meadow soil to chitosan was 5:3, and calcium chloride accounted for 2% of the mass of meadow soil.
[0070] Its usage method is:
[0071] (1) Adjust the pH value of monosodium glutamate sewage to about 4.0 with calcium hydroxide.
[0072] (2) Add calcium chloride.
[0073] (3) Add the prepared meadow soil into the sewage based on 30% of the mass number of the chemical oxygen demand (COD) of the sewage, and perform rapid stirring for about 5 minutes (80-100 rpm).
[0074] (4) Add chitosan.
[0075] (5) First stir rapidly (80-100 rpm) for 3 minutes, then stir at medium speed (40-60 rpm) for 10 minutes, then stir slowly (20-30 rpm)...
Embodiment 2
[0079] The invention uses red soil, chitosan (polymerization degree=90%) and calcium chloride as raw materials. Among them, red soil is the main component, particle size: 100-200 mesh, chitosan is the auxiliary flocculant, sodium hydroxide and calcium chloride are the regulator of pH value and flocculation aid respectively. The mass ratio of red soil to chitosan is 1.5:1, and calcium chloride accounts for 0.2% of the mass of red soil.
[0080] Its usage method is:
[0081] (1) Use sodium hydroxide to adjust the pH value of monosodium glutamate sewage to about 2.0.
[0082] (2) Add calcium chloride.
[0083] (3) Add the prepared red soil into the sewage based on 25% of the mass number of the chemical oxygen demand (COD) of the sewage, and perform rapid stirring for about 3 minutes (100-120 rpm).
[0084] (4) Add chitosan.
[0085] (5) First stir rapidly (100-120 rpm) for 5 minutes, then stir at medium speed (40-60 rpm) for 10 minutes, then stir slowly (10-20 rpm) for 30 min...
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