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Catalytic cracking combined process

A combined process and catalytic cracking technology, applied in the field of catalytic cracking, can solve problems such as adverse effects of product distribution in catalytic cracking units, unsatisfactory hydrogen transfer reaction effect, and reduced hydrogen transfer reaction efficiency, etc., and achieves flexible and convenient control, reduced olefin content, The effect of suppressing excessive cracking

Inactive Publication Date: 2003-07-09
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The use of two-zone reaction provides favorable conditions for the hydrogen transfer reaction of catalytic cracking - low temperature, relatively long residence time, but due to the pressure balance problem of the catalytic cracking system, neither the middle nor the top of the riser can form Relatively high dense bed material level, so the effect of the hydrogen transfer reaction actually obtained by this method in the industrial implementation process is not ideal
In addition, since olefins mainly exist in liquefied petroleum gas and gasoline, allowing all reaction oil gases to contact and react with low-temperature catalysts not only reduces the efficiency of the hydrogen transfer reaction, but also adversely affects the product distribution of the catalytic cracking unit
[0007] To sum up, heavy oil conversion capacity and product quality are two important aspects that affect the economic benefits of catalytic units, but there is no report on the catalytic cracking process that can take into account the above two in the prior art

Method used

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Experimental program
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Effect test

Embodiment approach 1

[0017] Implementation mode one: if figure 1 As shown, when adopting the inner and outer sleeve type circulating fluidized bed reactor 14 to implement the present invention, part of the regeneration agent enters the inside of the circulating fluidized bed reactor 14 inner sleeve (i.e. the reaction zone) after being cooled by the catalyst cooler 11 , contact and react with the gasoline raw material injected through the distributor 12, and the generated reaction oil gas is sent to the gasoline conversion product separation system after the entrained catalyst particles are removed by the cyclone separators 9A and 9B. The reacted catalyst enters the annular reaction space (that is, the stripping zone) between the inner and outer sleeves from the reaction zone, and the reaction oil gas carried by the catalyst is removed by stripping. Part of the stripped catalyst returns to the reaction zone to continue to participate in the reaction, while the rest of the catalyst is transported to...

Embodiment approach 2

[0018] Implementation mode two: if figure 2 As shown, when the present invention is implemented in an internal clapboard type circulating fluidized bed reactor, part of the regeneration agent enters the reaction zone of the circulating fluidized bed reactor after being cooled by the catalyst cooler 11, and is mixed with the gasoline raw material injected through the distributor 12. After contacting and reacting, the generated reaction oil gas is sent to the gasoline conversion product separation system after the entrained catalyst particles are removed by cyclone separators 9A and 9B. The reacted catalyst enters the stripping zone from the reaction zone, and the reaction oil gas carried by the catalyst is removed by steam stripping. Part of the stripped catalyst returns to the reaction zone to continue to participate in the reaction, while the rest of the catalyst is transported to the pre-lift section 1 of the riser reactor 8, where it is mixed with the uncooled high-tempera...

Embodiment 1

[0021] This example illustrates: adopting the method provided by the present invention to carry out tests on a medium-scale riser reactor and an inner and outer sleeve type circulating fluidized bed reactor.

[0022] The principle flow of the device used in the test can be found in figure 1 . Such as figure 1 As shown, 40% by weight of the regenerated catalyst enters the reaction zone of the circulating fluidized bed reactor 14 after being cooled by the catalyst cooler 11, and contacts and reacts with the gasoline raw material injected through the distributor 12, and the generated reaction oil gas is passed through the cyclone Separators 9A and 9B remove the entrained catalyst particles and send them to the gasoline conversion product separation system. The reacted catalyst enters the stripping zone from the reaction zone, and the reaction oil gas carried by the catalyst is removed by steam stripping. 60% by weight of the stripped catalyst is returned to the reaction zone t...

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Abstract

The catalytic cracking combination process includes the following steps: cooling 10-80 wt% of regenerative agent, feeding it into reaction zone of circulating fluidized bed reactor and making it contact with gasoline to make reaction; then feeding the produced reaction oil-gas into the subsequent gasoline conversion product separation system; feeding the catalyst after which is reacted into stripper zone of the circulating fluidized bed reactor to make stripping; back returning 40-80 wt% of stripped catalyst into reaction zone for circulating use and feeding residual portion into lift pipe reaction and making it mix with non-cooled regenerative agent and can be upward flower along lift pipe under the action of prelift medium; injecting hydrocarbon raw material into lift pipe and making it contact with catalyst, react, and making reactant flow through lift pipe outlet and come into the settler.

Description

technical field [0001] The invention belongs to the catalytic cracking method of petroleum hydrocarbons under the condition of no hydrogen, more specifically, it is a novel catalytic cracking combined process method. Background technique [0002] With the enhancement of global environmental awareness and stricter environmental regulations, controlling vehicle emissions and providing environmentally friendly vehicle fuels have become severe tasks for the oil refining industry in the 21st century. The United States and Europe have proposed an international unified standard for the quality of automobile fuel, in which the benzene content of gasoline is <1v%, the aromatic content is <35v%, the olefin content is <10v%, and the sulfur content is <0.003m%. In the new gasoline specifications and standards implemented in my country, it is stipulated that the benzene content is 2v%, the aromatics content is less than 40v%, and the olefin content is less than 35v%. The cont...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10G55/06
Inventor 侯栓弟许克家武雪峰何竣钟孝湘赵俊鹏李松年俞祥麟
Owner CHINA PETROLEUM & CHEM CORP
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