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Composite nano high-elastic polyurethane material and its prepn process

A nano-composite material and nano-material technology, applied in the field of high-elastic nano-composite materials, can solve the problems of large fluctuations in the purity and quality of montmorillonite, poor performance reproducibility of industrialized products, etc., and achieve rich varieties, beautiful colors and easy color matching. Effect

Inactive Publication Date: 2006-01-04
苏州中科纳米高弹材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But the above-mentioned prior art only adopts adding organic montmorillonite to prepare polyurethane nanocomposites, although the modification effect on polyurethane materials is obvious, but because montmorillonite is a natural mineral, the purity and quality of montmorillonite fluctuate greatly, thereby leading to industrialization Poor product performance reproducibility

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] The invention discloses a method for manufacturing a high-elastic nanocomposite material used for laying the ground of a public place.

[0046] The preparation method of component A: based on the total weight of component A, add 40% propylene glycol polyoxypropylene ether with a molecular weight of 2500 and 37% propylene glycol polyoxypropylene ether with a molecular weight of 1000 into the reaction kettle, and heat up to 80°C under stirring. Vacuumize to about -0.1MPa, dehydrate at a temperature of 80°C for 3 hours, cool down to 35°C, slowly add 23% toluene diisocyanate dropwise under stirring, react at 70°C for 2 hours after adding the material, and vacuumize to about -0.1 MPa degassing, cooling to room temperature and discharging for later use.

[0047] The preparation method of component B is: based on the total weight of component B, add 36% glycerol polyoxypropylene ether and 5% inorganic nano-zinc oxide into the reaction kettle, stir, and then add 4% 3,3'- Dichl...

Embodiment 2

[0050] The invention discloses a method for manufacturing a high-elastic plastic nanocomposite material used for laying court ground.

[0051] The preparation method of component A: based on the total weight of component A, add 34% polyether diol with a molecular weight of 2500 and 40% propylene glycol polyoxypropylene ether with a molecular weight of 1000 into the reaction kettle, heat up to 80°C under stirring, pump Vacuum to about -0.1MPa, dehydrate at 80°C for 3 hours, cool down to 35°C, slowly add 26% diisocyanate dropwise under stirring, react at 70°C for 2.5 hours after adding, vacuumize and degas, cool down to room temperature Material spare.

[0052] The preparation method of component B: based on the total weight of component B, add 37% glycerol polyoxypropylene ether, 3% inorganic nano-zinc oxide and 1% nano-silicon oxide into the reaction kettle, stir, and then add 4% 3,3'-dichloro4,4'-diaminodiphenylmethane, 26% talcum powder, 24% chlorinated paraffin oil, 5% iro...

Embodiment 3

[0055] The preparation method of component A: based on the total weight of component A, add 34% polyether diol with a molecular weight of 2500 and 40% propylene glycol polyoxypropylene ether with a molecular weight of 1000 into the reactor, and heat up to 80°C under stirring. Vacuum down to about -0.1MPa, dehydrate at 80°C for 3 hours, cool down to 40°C, slowly add 26% diisocyanate dropwise under stirring, react at 70°C for 3 hours after adding, vacuumize and degas, cool down to room temperature The material is ready for use.

[0056] The preparation method of component B is: based on the total weight of component B, add 36% glycerol polyoxypropylene ether, 1% inorganic nano-silicon oxide and 5% organic hydrotalcite into the reaction kettle, stir, and then add 4% 3,3'-dichloro-4,4'-diaminodiphenylmethane, 27% talc, 24% chlorinated paraffin oil, 2% mixture of tartrazine and phthalocyanine green and 1% antioxidant , heated to 80°C, vacuumed to about -0.1MPa, degassed and dehydr...

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PUM

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Abstract

The present invention discloses one kind of composite nano high-elasticity polyurethane material and its preparation process. The composite nano high-elasticity polyurethane material is prepared through mixing component A and component B in the ratio of 1 / 6 to 1 / 3, adding catalyst through stirring and curing. The component A is conventional polyurethane prepolymer; and the component B is prepared through mixing SiO2, ZnO and other granular nano material, laminated nano material hydrotalcite and polyether polyol, vacuum pumping to deair and dewater and adding other assistants. The composite nano material has outstanding high elasticity and raised comprehensive mechanical performance.

Description

【Field of Invention】 [0001] The invention relates to a high-elastic nanocomposite material, in particular, the invention relates to a high-elastic polyurethane inorganic nanocomposite material, and relates to the application of the composite material in high-elastic ground materials. The invention also relates to a manufacturing method of the high elastic polyurethane inorganic nanocomposite material. 【Background technique】 [0002] Polyurethane is an emerging material that has the characteristics of rubber and plastic, and its performance can be adjusted. The range of products made of polyurethane is very wide, including a series of products such as polyurethane foam plastics, elastomers, coatings, adhesives, synthetic fibers, synthetic leather, and waterproof materials. Polyurethane synthetic materials have properties unmatched by any other commercial rubber and plastic, such as abrasion resistance, high strength (tensile strength, tear strength), high elongation, high el...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L75/08C09D175/08
Inventor 马永梅璋杨刘必前胡晓明江雷
Owner 苏州中科纳米高弹材料有限公司
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