Polarizing plate
A polarizer and polarizer technology, applied in optics, optical components, polarizing components, etc., can solve problems such as reduced blocking efficiency, impact on the durability of the liquid crystal layer, and reduced orientation of liquid crystal compounds
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preparation example 1
[0200] Preparation Example 1. Preparation of Polymerizable Liquid Crystal Composition A
[0201]A polymerizable liquid crystal composition was prepared using LC1057 liquid crystal of BASF Corporation as a forward dispersion polymerizable liquid crystal compound and a liquid crystal compound of the following formula A as a reverse dispersion liquid crystal compound. The R(450) / R(550) of the forward dispersion polymerizable liquid crystal compound is at a level of about 1.09 to 1.11 and the R(650) / R(550) is at a level of about 0.93 to 0.95, and the liquid crystal compound of formula A The R(450) / R(550) is at a level of about 0.84 to 0.86 and the R(650) / R(550) is at a level of about 1.01 to 1.03. R(450), R(550) and R(650) are measured with respect to a retardation layer formed by using a forward dispersion polymerizable liquid crystal compound or a polymerizable liquid crystal compound of formula A alone at wavelengths of 450 nm, 550 nm and 650 nm, respectively. The in-plane ret...
preparation example 2
[0227] Preparation Example 2. Preparation of Polymerizable Liquid Crystal Composition B
[0228] A polymerizable liquid crystal composition B was prepared in the same manner as in Preparation Example 1, except that a liquid crystal compound of the following formula B was used as the reverse dispersion polymerizable liquid crystal compound. The liquid crystal compound of formula B has R(450) / R(550) at a level of about 0.81 to 0.83, and R(650) / R(550) at a level of about 1.01 to 1.03. R(450), R(550), and R(650) are in-plane retardations to light of wavelengths of 450 nm, 550 nm, and 650 nm measured relative to a retardation layer formed by using the polymerizable liquid crystal compound of Formula B alone.
[0229] [Formula B]
[0230]
[0231] Here, the compound of formula B was obtained by obtaining a compound represented by the following formula A9 in the same manner as in Preparation Example 1, and then replacing the hydrogen atom bonded to the nitrogen atom of the compou...
preparation example 3
[0234] Preparation Example 3. Preparation of Polymerizable Liquid Crystal Composition C
[0235] A polymerizable liquid crystal composition is prepared by applying the reverse dispersion polymerizable liquid crystal compound of the formula A in the above Preparation Example 1, the same photoinitiator as used in Preparation Example 1, and the maximum absorption wavelength range as an ultraviolet absorber UV absorber (Orient Chemical Industries, BONASORB UA-3912) at about 380 nm to 390 nm. The reverse dispersion polymerizable liquid crystal compound of formula A, the photoinitiator and the ultraviolet absorber are combined in a solvent (ring Pentanone), to prepare polymerizable liquid crystal composition C.
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