Organic electroluminescent device
An electroluminescent element and luminescent technology, which is applied in the fields of electrical components, organic chemistry, and electric solid-state devices, can solve problems such as difficulty in reflecting deep blue, short life, and narrow luminescence spectrum.
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Synthetic example 1-1
[0137]
[0138] After dissolving 8.9 g (20 mmol) of starting material 1 in tert-butylbenzene (250 ml), it was cooled to 0°C. Under a nitrogen atmosphere, 24.7 ml (42 mmol) of a 1.7 M tert-butyllithium (tert-butyllithium) solution (in pentane) was added, followed by stirring at 60° C. for 2 hours.
[0139] The reaction was then cooled to 0 °C again, and 4.0 ml of BBr was added 3 (42 mmol) and stirred at room temperature for 0.5 hours. The reactant was cooled to 0° C., and 7.3 ml (42 mmol) of N,N-diisopropylethylamine (N,N-diisdopropylethylamine) was added, followed by stirring at 60° C. for 2 hours.
[0140] The reaction solution was cooled to room temperature, and the organic layer was extracted with ethyl acetate and water. After removing the solvent of the extracted organic layer, it purified by the silica gel column chromatography (DCM / hexane (Hexane)) method. Then, recrystallization and purification were performed using a DCM / acetone (Acetone) mixed solvent to obtain...
Synthetic example 1-2
[0143]
[0144] Except using 9.9 g (20 mmol) of starting material 1-3 instead of starting material 1-1, the experiment was carried out in the same manner as in Synthesis Example 1-1, and 2.16 g of the compound 1-1 was obtained with a yield of 23.0%. 3.
[0145] MS (MALDI-TOF) m / z: 470[M]+
Synthetic example 1-3
[0147]
[0148] Except using 10.6 g (20 mmol) of starting material 1-5 instead of starting material 1-1, the experiment was carried out in the same manner as in Synthesis Example 1-1, and 2.3 g of the compound 1-1 was obtained with a yield of 23.2%. 5.
[0149] MS (MALDI-TOF) m / z: 502[M]+
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