High-maturity-over-maturity shale gas content evaluation method based on alkane carbon isotope inversion
A shale gas content and carbon isotope technology, applied in the field of oil and gas exploration, can solve problems such as high cost, high experimental cost, and complicated experimental process, and achieve the effects of mature experimental methods, low cost, and great economic advantages
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[0045] The technical solution provided by the invention is based on the principle that carbon isotope inversion is closely related to secondary cracking of residual liquid hydrocarbons in shale.
[0046]The carbon isotopes of alkane gas in natural gas have a certain arrangement according to the relationship between the carbon numbers in their molecules:
[0047] (1) If the carbon number of alkane gas molecules increases, δ 13 The value of C increases successively (δ 13 C 甲烷 13 C 乙烷 13 C 丙烷 13 C 丁烷 ) is called the positive carbon isotope series, which is a characteristic of alkane gas of organic origin;
[0048] (2) If the carbon number of alkane gas molecules increases, δ 13 The value of C decreases successively (δ 13 C 甲烷 >δ 13 C 乙烷 >δ 13 C 丙烷 >δ 13 C 丁烷 ) is called negative carbon isotope series.
[0049] Irregular increase or decrease that does not follow the above two rules is called carbon isotope inversion, which can be referred to as inversion for short. ...
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