Circular polarizer
A circular polarizing plate and retardation layer technology, applied in optics, optical components, instruments, etc., can solve problems such as process simplification and cost competitiveness, affecting the overall durability of circular polarizing plates, and affecting display quality, etc., to achieve excellent Durability, ensuring cost competitiveness, and ensuring the effect of process simplification
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preparation example 1
[0276] Preparation Example 1. Preparation of Polymerizable Liquid Crystal Composition A
[0277] The polymerizable liquid crystal composition was prepared using LC1057 liquid crystal of BASF Corporation as a normal dispersion polymerizable liquid crystal compound and a liquid crystal compound of the following formula A as anomalous dispersion liquid crystal compound. The normal dispersion polymerizable liquid crystal compound has R(450) / R(550) at a level of about 1.09 to 1.11 and R(650) / R(550) at a level of about 0.93 to 0.95, and the liquid crystal compound of Formula A has a R(450) / R(550) is at a level around 0.84 to 0.86 and R(650) / R(550) is at a level around 1.01 to 1.03. R(450), R(550), and R(650) are the wavelengths of 450 nm, 550 nm, and 650 nm, respectively, measured for the retardation layer formed by using the normal dispersion polymerizable liquid crystal compound or the polymerizable liquid crystal compound of Formula A alone. The in-plane phase difference of ligh...
preparation example 2
[0303]Preparation Example 2. Preparation of Polymerizable Liquid Crystal Composition B A polymerizable liquid crystal composition B was prepared in the same manner as in Preparation Example 1, except that the liquid crystal compound of the following formula B was used as the anomalous dispersion polymerizable liquid crystal compound. The liquid crystal compound of Formula B has R(450) / R(550) at a level of about 0.81 to 0.83, and R(650) / R(550) at a level of about 1.01 to 1.03. R(450), R(550) and R(650) are in-plane retardation to light having wavelengths of 450 nm, 550 nm and 650 nm measured for the retardation layer formed by using the polymerizable liquid crystal compound of Formula B alone.
[0304] [Formula B]
[0305]
[0306] Here, the compound of formula B was obtained by obtaining a compound represented by the following formula A9 in the same manner as in Preparation Example 1, and then using 2-[2- (methoxyethoxy)]ethyl substituted. The NMR confirmation result of t...
preparation example 3
[0309] Preparation Example 3. Preparation of Polymerizable Liquid Crystal Composition C
[0310] A polymerizable liquid crystal composition was prepared by applying the anomalous dispersion polymerizable liquid crystal compound of formula A in the above Preparation Example 1, the same photoinitiator as used in Preparation Example 1, and the maximum absorption wavelength range as an ultraviolet absorber UV absorber (Orient Chemical Industries, BONASORB UA-3912) at about 380 nm to 390 nm. The anomalous dispersion polymerizable liquid crystal compound of formula A, a photoinitiator and an ultraviolet absorber were combined in a solvent (cyclopentanone) in a weight ratio of 20:1:1 (anomaly dispersion polymerizable liquid crystal compound:photoinitiator:ultraviolet absorber). ) to prepare polymerizable liquid crystal composition C.
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