A kind of organosilicon graphite composite thermal interface material and its preparation method and application

A thermal interface material and silicone technology, applied in the field of thermal interface materials, can solve the problems of low thermal conductivity, high density, low thermal conductivity, etc., and achieve the effects of high longitudinal thermal conductivity, improved tensile strength, and extended service life.

Active Publication Date: 2021-04-30
SHENZHEN INST OF ADVANCED TECH
View PDF11 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the organic silicon heat-conducting materials in the prior art are filled with high thermal conductivity ceramic particles in organic silicon, such as aluminum oxide, zinc oxide, quartz powder, aluminum nitride, boron nitride, silicon carbide, etc., which have low thermal conductivity ( Longitudinal thermal conductivity is difficult to exceed 8W·m -1 ·K -1 ), high density, high hardness, etc.
[0004] CN102746670A discloses a heat dissipation interface material used for packaging high-power LED lamps and a preparation method thereof. The heat dissipation interface material is made of a flexible AB two-component condensation type room temperature curing silicone resin as a matrix, added with dimethyl silicone oil and functionalized Graphene microflakes are fully mixed as thermal conductive fillers. During preparation, functionalized graphene microflakes and silicone resin are fully mixed on a double-roll mill, so that functionalized graphene is evenly dispersed in the silicone resin matrix, thereby preparing a performance Excellent heat dissipation interface material, although the interface contact thermal resistance is reduced, the thermal conductivity is still not high enough to meet the heat dissipation problems caused by the increase in power density brought about by the rapid development of the electronics industry
CN107686699A discloses a kind of heat conduction interface material and preparation method, and this heat conduction interface material comprises: graphene composite interface material gasket, spray resin, heat conduction insulation powder; The mixture of spray resin and heat conduction insulation powder, covers on graphene composite interface over the material spacer; it increases the insulation of the TIM, but its thermal conductivity is still low and too dense for the application

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] An organosilicon-graphite composite thermal interface material is composed of a graphite skeleton with a honeycomb structure and an organosilicon material filled in the honeycomb structure.

[0052] Wherein, the preparation raw material of organosilicon material consists of 100 parts by weight of polyvinylsiloxane, 5.5 parts by weight of methyl hydrogen polysiloxane crosslinking agent, 0.3 parts by weight of platinum catalyst, 0.2 parts by weight of butynol inhibitor and 1.5 parts by weight of KH-560 surface treatment agent.

[0053] Among them, the viscosity of polyvinylsiloxane is 1000mPa·s; the viscosity of methyl hydrogen polysiloxane crosslinking agent is 100mPa·s, and the hydrogen content is 0.8%; the Pt content of the platinum catalyst is 2000ppm.

[0054] The preparation method is as follows:

[0055] (1) Use the para-aramid fiber paper with a thickness of 50 μm as the raw material paper, apply the glue with a rubber roller coated with core strip glue, then sta...

Embodiment 2

[0060] An organosilicon-graphite composite thermal interface material is composed of a graphite skeleton with a honeycomb structure and an organosilicon material filled in the honeycomb structure.

[0061] Wherein, the preparation raw material of organosilicon material consists of 100 parts by weight of polyvinylsiloxane, 2.5 parts by weight of methyl hydrogen polysiloxane crosslinking agent, 0.05 parts by weight of platinum catalyst, 0.25 parts by weight of butynol inhibitor and 3.0 parts by weight of KH-560 surface treatment agent composition.

[0062] Among them, the viscosity of polyvinylsiloxane is 400mPa·s; the viscosity of methyl hydrogen polysiloxane crosslinking agent is 50mPa·s, and the hydrogen content is 1.5%; the Pt content of the platinum catalyst is 3000ppm.

[0063] The preparation method is as follows:

[0064] (1) Use the meta-aramid fiber paper with a thickness of 25 μm as the raw material paper, apply glue with a rubber roller coated with core strip glue, ...

Embodiment 3

[0069] An organosilicon-graphite composite thermal interface material is composed of a graphite skeleton with a honeycomb structure and an organosilicon material filled in the honeycomb structure.

[0070] Wherein, the preparation raw material of organosilicon material consists of 100 parts by weight of polyvinyl siloxane, 3.5 parts by weight of methyl hydrogen polysiloxane crosslinking agent, 0.5 parts by weight of platinum catalyst, 0.2 parts by weight of butynol inhibitor and 2.0 parts by weight of KH-560 surface treatment agent.

[0071] Among them, the viscosity of polyvinylsiloxane is 500000mPa·s; the viscosity of methyl hydrogen polysiloxane crosslinking agent is 1000mPa·s, and the hydrogen content is 1.0%; the Pt content of platinum catalyst is 5000ppm.

[0072] The preparation method is as follows:

[0073] (1) Use polyimide fiber paper with a thickness of 30 μm as the raw material paper, apply glue with a rubber roller coated with core strip glue, then stack the mul...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
viscosityaaaaaaaaaa
viscosityaaaaaaaaaa
viscosityaaaaaaaaaa
Login to view more

Abstract

The invention provides an organosilicon-graphite composite thermal interface material and its preparation method and application. The organosilicon-graphite composite thermal interface material comprises a graphite skeleton with a honeycomb structure and an organosilicon material filled in the honeycomb structure. The thermal interface material of the present invention includes organosilicon and honeycomb graphite skeleton, which not only retains the soft fit of organosilicon but also has good thermal conductivity of graphite skeleton, and the organosilicon material is filled in the honeycomb structure of graphite skeleton, making the present invention The thermal interface material has higher longitudinal thermal conductivity at a lower packing density, and the honeycomb structure can further improve the tensile strength of the silicone material and prolong the service life in harsh environments.

Description

technical field [0001] The invention belongs to the technical field of thermal interface materials, and relates to an organosilicon-graphite composite thermal interface material and a preparation method and application thereof. Background technique [0002] The fifth-generation mobile communication (5G) is a new generation of mobile communication system oriented to the needs of the information society in 2020. It has the characteristics of high spectrum utilization, large data flow, low network energy consumption, high reliability and short delay. , unmanned driving, telemedicine, artificial intelligence and other new-generation information technology application innovation foundation. The breakthrough of 5G communication technology and the expansion of application scenarios will promote the revolutionary development of smart terminals and bring new opportunities to the development of thermal interface materials industry. Especially with the continuous development of intell...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C08L83/07C08L83/05C08K3/04
CPCC08L83/04C08L2205/025C08K3/04
Inventor 张保坦孙蓉朱朋莉
Owner SHENZHEN INST OF ADVANCED TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products