Organic electroluminescent device taking anthracene as core compound, and applications thereof
A technology of electroluminescent devices and compounds, applied in the fields of electric solid devices, electrical components, organic chemistry, etc., can solve different problems
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Embodiment 1
[0078] Embodiment 1: the synthesis of intermediate VII in general formula (2):
[0079]
[0080] Take the synthesis of intermediate A1 as an example:
[0081]
[0082] 1) In a 250ml three-neck flask, under nitrogen protection, add 0.05mol 3-bromo-9H-carbazole, 0.06mol iodobenzene, 150ml toluene and stir to mix, then add 0.015mol Cu, 0.15mol potassium carbonate, and heat to 150°C , reflux reaction for 24 hours, sampling point plate, showing no 3-bromo-9H-carbazole remaining, the reaction is complete; naturally cool to room temperature, filter, and the filtrate is subjected to vacuum rotary evaporation (-0.09MPa, 85°C), over neutral Silica gel column to obtain 3-bromo-9-phenyl-9H-carbazole, HPLC purity 99.3%, yield 78.8%;
[0083] Elemental analysis structure (molecular formula C 18 h 12 BrN): Theoretical C, 67.10; H, 3.75; Br, 24.80; N, 4.35; Found: C, 67.12; H, 3.74; N, 4.34.
[0084] HPLC-MS: The molecular weight of the material is 321.02, and the measured molecular...
Embodiment 2
[0098] Embodiment 2: the synthesis of compound 2:
[0099] synthetic route:
[0100]
[0101] In a 250ml three-neck flask, under the protection of nitrogen, add 0.01mol 2,3-dimethyl-9,10-dibromoanthracene, 0.024mol intermediate A1, 150ml toluene, stir and mix, then add 0.04mol sodium tert-butoxide, 1×10 -4 molPd 2 (dba) 3 , 1×10 -4 mol of tri-tert-butylphosphine, heated to 105°C, refluxed for 24 hours, sampling plate, showed no remaining bromide, the reaction was complete; naturally cooled to room temperature, filtered, and the filtrate was rotary evaporated under reduced pressure (-0.09MPa, 85°C ), through a neutral silica gel column to obtain the target product, with a HPLC purity of 99.2%, and a yield of 66.3%;
[0102] Elemental analysis structure (molecular formula C 64 h 46 N 4 ): theoretical value C, 88.25; H, 5.32; N, 6.43; test value: C, 88.24; H, 5.34; N, 6.42.
[0103] HPLC-MS: The molecular weight of the material is 870.37, and the measured molecular we...
Embodiment 3
[0104] Embodiment 3: the synthesis of compound 6:
[0105] synthetic route:
[0106]
[0107] In a 250ml three-neck flask, under the protection of nitrogen, add 0.01mol 2,6-di-tert-butyl-9,10-dibromoanthracene, 0.024mol intermediate A1, 150ml toluene and stir to mix, then add 0.04mol sodium tert-butoxide , 1×10 -4 molPd 2 (dba) 3 , 1×10 -4 mol of tri-tert-butylphosphine, heated to 105°C, refluxed for 24 hours, sampling plate, showed no remaining bromide, the reaction was complete; naturally cooled to room temperature, filtered, and the filtrate was rotary evaporated under reduced pressure (-0.09MPa, 85°C ), through a neutral silica gel column, to obtain the target product, HPLC purity 99.1%, yield 67.6%;
[0108] Elemental analysis structure (molecular formula C 70 h 58 N 4 ): theoretical value C, 88.01; H, 6.12; N, 5.87; test value: C, 88.02; H, 6.13; N, 5.85.
[0109] HPLC-MS: The molecular weight of the material is 954.47, and the measured molecular weight is 95...
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