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Multi-stage parallel reinforced fixed-bed reactor and using method thereof

A fixed-bed reactor, fixed-bed technology, applied in chemical instruments and methods, chemical/physical processes, etc., can solve the problems of high pressure drop, slow material flow rate, low reaction rate, etc. The effect of fast surface renewal and high reaction efficiency

Active Publication Date: 2017-07-14
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Despite such improvements, the inherent defects of the segmented series fixed-bed reactor, such as high pressure drop and low reaction rate, cannot be effectively overcome.
[0004] Whether it is an integrated or segmented series fixed bed reactor, there are basically problems such as difficult temperature control, slow material flow rate, small Reynolds number, oil-water phase separation, low mass transfer rate, and low reaction efficiency.

Method used

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  • Multi-stage parallel reinforced fixed-bed reactor and using method thereof
  • Multi-stage parallel reinforced fixed-bed reactor and using method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Refer below figure 1 , 2 Describe the multi-stage parallel reinforced fixed bed reactor according to the embodiment of the present invention and its use method

[0031] In the multi-stage parallel enhanced fixed bed reactor of the embodiment of the present invention, the reaction units are connected in parallel and the bed is divided into sections. Under the forced drive of the circulation pump, the liquid flow is evenly sent to each catalyst bed, and flows from the bottom to the bottom. Pass through the catalyst bed at a set speed and temperature. On the liquid flow input and output pipelines, install appropriate temperature control and flow control equipment and instruments, such as cold and heat exchangers, valves, flow meters, thermometers, etc. In this way, the pressure drop of the bed can be effectively reduced, the material velocity can be greatly increased, the phenomenon of oil-water phase and split flow can be eliminated, and the purpose of increasing the ma...

experiment example 1

[0057]Experimental Example 1: A manufacturer producing cyclohexanol by hydration of cyclohexene has a production capacity of 8,000t / y. Originally, a series fixed-bed reactor was used. The temperature in the tower kettle reached 200°C, and it was necessary to control the temperature to 120°C. The pressure drop is 6MPa, the pressure drop is too high, the mass flow rate is 5t / h, after 6 hours of reaction, the conversion rate of cyclohexene is 7.5%, and the selectivity of cyclohexanol is 85%. And adopt this device to produce, raw material enters each reaction unit by raw material tank, feed ratio: the mass ratio of cyclohexene and water is 1:3.2, is delivered to each reaction unit by delivery pump, and total mass flow is: F= 20t / h. According to the reaction situation and the physical properties of the materials, the manufacturer adopts 4 reaction units, and each reaction unit is connected with 5 fixed bed sections in parallel, and the feed rate of each bed section is 1t / h. The pr...

experiment example 2

[0058] Experimental example 2: A manufacturer in a certain place uses hydration of β-caryophyllene to produce β-caryophyllene alcohol with a production capacity of 1800t / y. It used to use an integrated fixed-bed reactor. ℃, the bed pressure drop is 2.5MPa, the mass flow rate is 1.2t / h, after 1 hour of reaction, the conversion rate of β-caryophyllene is 16%, and the selectivity of β-caryophyllene alcohol is 86%. And adopt this device to carry out production, raw material enters each reaction unit by raw material tank, feed ratio: the mass ratio of β-caryophyllene and water is 1:1, is transported to each reaction unit by delivery pump, and total mass flow rate is: F =3t / h. According to the reaction situation, the manufacturer adopts 2 reaction units, each reaction unit is connected with 6 fixed bed sections in parallel, and the feed rate of each bed section is 0.25t / h. The pressure drop of the reaction material passing through the catalyst bed is only 0.5MPa. After heat exchang...

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Abstract

The invention discloses a multistage parallel intensified fixed bed reactor and a using method thereof. The multistage parallel intensified fixed bed reactor comprises a raw material tank, a discharge tank, at least one parallel reaction unit, a circulation pipeline and a circulation pump, wherein each reaction unit comprises a charge pump, a charge heat exchanger, a discharge heat exchanger, a reactor shell and a plurality of fixed bed layer sections installed in the reactor shell; each fixed bed layer section is connected with a charge main pipe via a charge branch pipe; the charge main pipe is connected with the raw material tank; the charge pumps and the charge heat exchangers are arranged on the charge main pipe; each fixed bed layer section is connected with the discharge main pipe via a discharge branch pipe; the discharge main pipe is connected with a discharge tank; the discharge heat exchangers are arranged on the discharge main pipe; one end of the circulation pipeline is connected with the discharge tank, and the other end of the circulation pipeline is connected with the raw material tank; the circulation pump is arranged on the circulation pipeline. The multistage parallel intensified fixed bed reactor is compact in structure, convenient to operate and control, high in reaction efficiency, high in elasticity, convenient to maintain, and is especially suitable for modern large-scale production, and is an upgraded product of the traditional fixed bed reactor.

Description

technical field [0001] The invention relates to chemical reactor equipment, which is a multi-stage parallel reinforced fixed-bed reactor and its application method. Background technique [0002] A fixed bed reactor is a reactor packed with a catalyst to achieve a heterogeneous reaction process. Among them, the catalyst will be piled up into a bed with a certain height (or thickness). Its biggest feature is that the catalyst bed is in a static state, while the liquid material reacts through the bed. Fixed bed reactor is the most widely used and basic reactor in liquid-solid catalytic reaction. Fixed-bed reactors have many advantages, such as the minimum amount of catalyst (or reactor volume) required to complete the same production task; the residence time of materials in the bed can be strictly controlled, and the temperature distribution can be adjusted appropriately, which is conducive to improving The conversion rate and selectivity of the chemical reaction; the cataly...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J8/04
CPCB01J8/008B01J8/0449
Inventor 周政张志炳张锋王宝荣孟为民杨程罗华勋陶海聂慧琴
Owner NANJING UNIV
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