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Special washing branding discoloration resin for synthetic leather and preparation method thereof

A synthetic leather and resin technology, applied in textiles and papermaking, etc., can solve the problems of single color and surface pattern, insufficient burnt feeling of branded parts, poor wear resistance and scratch resistance, etc., and achieve good discoloration effect, good visual effect, durable Good abrasion and scratch resistance

Active Publication Date: 2015-07-08
ZHEJIANG SUNLIGHT MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1) Wet synthetic leather contains a lot of wood powder and other fillers, and has an open cell structure, resulting in low strength, poor wear resistance and scratch resistance. It is generally used as the middle layer of synthetic leather, such as branded and discolored synthetic leather Used alone, it is difficult to meet the requirements when it is applied to occasions such as shoes and bags that require high physical properties of synthetic leather
[0005] 2) The production process of ordinary wet branded synthetic leather determines that its color and surface pattern are relatively single, which cannot meet high aesthetic requirements
[0006] 3) Ordinary wet branded synthetic leather contains a lot of wood powder and other fillers, resulting in insufficient burnt feeling on the branded part
However, wet-process synthetic leather is generally used for the middle layer of synthetic leather, and its strength is poor, so it is difficult to use directly

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Mix 30 parts of polyurethane resin, 28 parts of N,N-dimethylformamide and 30 parts of butyl acetate in the kettle, and then add 1 part of epoxy soybean oil and 2 parts of silicone while stirring. Mixing agent, 1 part of silica matting powder and 8 parts of micronized wax powder, stir for 30min to make it completely dispersed. The viscosity measured by sampling is 1200cps / 25℃, and the product is filtered and discharged.

[0032] After adding 3% color paste to the prepared water-washed branding and color-changing resin, it is applied to the surface of dry synthetic leather by roller coating, dried at 130°C, kneaded in water for 30 minutes, and taken out for drying. Then use a branding machine to brand the surface to obtain a branded and color-changing synthetic leather with a clear pattern.

Embodiment 2

[0034] Stir 35 parts of polyurethane resin, 40 parts of N,N-dimethylformamide and 12.5 parts of butyl acetate in the kettle, and then add 0.5 parts of epoxy fatty acid methyl ester and 1 part of silicone while stirring. Hand-feeling agent, 3 parts of silicon dioxide matting powder and 8 parts of micronized wax powder, stir for 30 minutes to make it completely dispersed. The viscosity measured by sampling is 2000cps / 25℃, and the product is filtered and discharged.

[0035] After adding 3% color paste to the prepared water-washed branding and color-changing resin, it is coated on the surface of dry synthetic leather by roller coating, dried at 130°C, kneaded in water for 30 minutes, and taken out for drying. Then use a branding machine to brand the surface to obtain a branded and color-changing synthetic leather with a clear pattern.

Embodiment 3

[0037] Stir 40 parts of polyurethane resin, 30 parts of N,N-dimethylformamide and 14.5 parts of butyl acetate in the kettle, and then add 1 part of epoxy fatty acid methyl ester and 0.5 parts of silicone while stirring. Feeling agent, 2 parts of silicon dioxide matting powder and 12 parts of micronized wax powder, stir for 30 minutes to make it completely dispersed. The viscosity measured by sampling is 3000cps / 25℃, and the product is filtered and discharged.

[0038] After adding 5% color paste to the prepared water-washed branding color-changing resin, it is pasted on the surface of wet synthetic leather with release paper veneer, dried at 130°C, kneaded in water for 30 minutes, and taken out for drying. Then use a branding machine to brand the surface to obtain a branded and color-changing synthetic leather with a clear pattern.

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PUM

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Abstract

The invention relates to a special washing branding discoloration resin for synthetic leather. The branding discoloration resin comprises the following components: polyurethane resin, silicon dioxide extinction powder, micronization wax powder, a plasticizing agent, an organosilicon feeling agent, butyl acetate and N, N-dimethylformamide. The method comprises the following steps: 1, adding the polyurethane resin, the N, N-dimethylformamide and the butyl acetate into a reactor, and mixing uniformly; 2, adding the plasticizing agent, the silicon dioxide extinction powder and the micronization wax powder while stirring, and stirring for 20-40 minutes so as to completely dispersing the plasticizing agent, the silicon dioxide extinction powder and the micronization wax powder; and 3, testing the viscosity of a product, filtering and discharging after qualification. The branding discoloration resin is good in physical property, good in wear resistance and scratch resistance and good in visual effect, and can be widely used in occasions such as shoes and bags with high performance requirements on the synthetic leather.

Description

technical field [0001] The invention relates to a preparation method of a special resin for synthetic leather, in particular to a resin capable of achieving the effect of branding and discoloration through washing with water and a preparation method thereof. technical background [0002] As a substitute for genuine leather, polyurethane synthetic leather has a lower cost and its performance is close to or surpasses that of similar genuine leather products. Therefore, it is widely used in various fields such as clothing, luggage, footwear and home furnishing. With the improvement of people's living standards and aesthetic concepts, the traditional single-color synthetic leather products can no longer meet people's needs. Improving the appearance and texture of synthetic leather through surface modification has become an indispensable means in the production process of synthetic leather. Brand discoloration means that the surface of synthetic leather is discolored by high-tem...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L75/06C08L75/08C08K3/36C08K5/1515C08K5/11C08J9/26D06N3/14
Inventor 朱建琴郦向宇戴文琪金朝锋杨兆荣赵叶军
Owner ZHEJIANG SUNLIGHT MATERIAL TECH CO LTD
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