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Conjugate polyelectrolyte photoelectric material based on poly-carbazole and application of conjugate polyelectrolyte photoelectric material based on poly-carbazole

A technology of conjugated polyelectrolyte and optoelectronic materials, applied in the direction of organic chemistry, etc., can solve the problems of low conductivity, reduce the life and stability of OLED devices, PVK hole injection/transport performance is not very good, etc., to achieve high conductivity efficiency, and the effect of avoiding adverse effects

Active Publication Date: 2014-07-23
HAIMEN BIWEI INTPROP SERVICE CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, PEDOT:PSS is the most commonly used, but PEDOT:PSS is actually an acidic solution, which has a certain corrosion effect on the ITO anode, so using PEDOT:PSS as the hole injection layer will reduce the life and stability of OLED devices.
Since PVK is a non-conjugated polymer with a main chain, its electrical conductivity is not high, so the hole injection / transport performance of PVK is not very good, which is also one of the unfavorable factors affecting the performance of OLED devices.

Method used

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  • Conjugate polyelectrolyte photoelectric material based on poly-carbazole and application of conjugate polyelectrolyte photoelectric material based on poly-carbazole
  • Conjugate polyelectrolyte photoelectric material based on poly-carbazole and application of conjugate polyelectrolyte photoelectric material based on poly-carbazole
  • Conjugate polyelectrolyte photoelectric material based on poly-carbazole and application of conjugate polyelectrolyte photoelectric material based on poly-carbazole

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Preparation of 4,4-dibromo-2-nitrobiphenyl (1)

[0024] Dissolve 4,4-dibromobiphenyl (20g, 64mmol) in glacial acetic acid (300mL), heat and stir at 110°C, add concentrated nitric acid (70%, 132mL) dropwise to glacial acetic acid, heat for 6h until solid Slowly dissolve, then cool to room temperature. The reaction solution was filtered, the solid was washed with water, and then recrystallized with ethanol to obtain a yellow solid (17.6g, yield77%). 1 H-NMR (300MHz, CDCl 3 ): (ppm) 8.32 (d, 2H), 8.29 (d, 2H), 7.77 (dd, 2H).

Embodiment 2

[0026] Preparation of 2,7-dibromocarbazole (2)

[0027] Triethyl phosphate (60 mL) added with compound 1 (16.5 g, 46.1 mmol) was heated to reflux for 18 h under nitrogen protection. The excess solvent was distilled off from the reaction liquid under reduced pressure, and the residue was dissolved with a small amount of dichloromethane, then precipitated with petroleum ether to obtain the initial product, and then a white solid (9.28 g, yield 62%) was obtained by silica gel / petroleum ether column chromatography. 1 H-NMR (300MHz, CDCl 3 ): δ (ppm) 8.20 (br, 1H, NH); 7.92 (d, 2H); 7.56 (d, 2H); 7.35 (dd, 2H).

Embodiment 3

[0029] Preparation of p-methylphenyl-1-bromo-6-hexyl ether (3)

[0030] Add p-cresol (28g), 1,6-dibromohexane (220mL), potassium carbonate (60g), tetrabutylammonium bromide (3.8g) and acetone (150mL) into a 500mL flask, heat and stir to reflux 48h. The reaction was cooled to room temperature, filtered, and the filtrate was spun with a circulating water pump until the mass was no longer reduced, then distilled under reduced pressure with an oil pump, and the fraction collected at 210°C to 220°C was a colorless oily product (53.5g, yield76.1%). 1 H-NMR (300MHz, CDCl 3 ): δ (ppm) 7.10 (d, 2H); 6.82 (d, 2H); 3.96 (t, 2H); 3.45 (t, 2H); 2.32 (s, 3H); 1.8 (br, 8H).

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Abstract

The invention discloses a conjugate polyelectrolyte photoelectric material based on poly-carbazole and an application of the conjugate polyelectrolyte photoelectric material based on the poly-carbazole in organic light emitting diode (OLED) devices. The main polymer chain of the conjugate polyelectrolyte photoelectric material based on poly-carbazole is conjugate, consists of carbazole groups with good hole injection / transmission performance, has high electric conductivity and is beneficial to the hole injection and transmission of the OLED devices.

Description

technical field [0001] The invention relates to the field of organic semiconductor photoelectric materials, in particular to a polycarbazole-based conjugated polyelectrolyte photoelectric material and its application in a hole injection layer of an OLED device. Background technique [0002] Such as figure 1 As shown, the OLED device is mainly composed of a cathode 1 , a light emitting layer 2 , a hole injection layer (HIL) 3 , an anode 4 , and a substrate 5 sequentially stacked, and a power source 6 is connected to the cathode 1 and the anode 4 . The light-emitting layer 2 is an organic material. When preparing an OLED device, usually on the substrate 5, indium tin oxide (ITO) is first set as the anode 4, then the hole injection layer (HIL) 3 is set on the ITO anode 4, and then the light emitting layer is set on the hole injection layer 3. layer 2, and finally a metal cathode 1 is vapor-deposited on the light-emitting layer 2, for example, a layer of CsF and a layer of met...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G61/12C07D209/86
Inventor 不公告发明人
Owner HAIMEN BIWEI INTPROP SERVICE CO LTD
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