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Acrylate polymer high oil absorption resin and preparation method and application thereof

一种高吸油树脂、丙烯酸酯的技术，应用在化学仪器和方法、其他化学过程、吸附水/污水处理等方向，能够解决难凝聚现象、吸油倍率小、保油性欠佳等问题，达到应用范围广、纯度高的效果

Active Publication Date: 2012-09-05
SHANGHAI FINETAC PRECISION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This oil-absorbing material has obvious disadvantages such as small oil absorption ratio, poor oil-water selectivity and oil retention.
The second oil-absorbing material is to use synthetic hydrophobic materials such as polyethylene, polypropylene, polyethylene terephthalate and other fibers to prepare non-woven fabrics and mesh felts with certain physical shapes. Improved performance, but poor oil retention
Most of the free radical polymerization methods used are suspension polymerization and a small number of emulsion polymerization. The two polymerization method systems need to add water-soluble macromolecular compounds and surfactants respectively, and the coagulation phenomenon that is difficult to control in suspension polymerization, etc., resulting in Problems in the purity, performance, application range and production process of synthetic resin are difficult to control

Method used

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  • Acrylate polymer high oil absorption resin and preparation method and application thereof
  • Acrylate polymer high oil absorption resin and preparation method and application thereof
  • Acrylate polymer high oil absorption resin and preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] 1) formula (in parts by weight):

[0055]

[0056] 2) Preparation:

[0057] Add the ingredients according to the above formula, add them into the irradiation device with stirring, reflux condensation, temperature control, nitrogen gas flow and the upper cover can be opened, disperse with 40KHz ultrasonic for 20 minutes, pass high-purity nitrogen gas for 20 minutes, then seal it with nitrogen gas, put it away enter 60 The position where the absorbed dose rate of the Co radiation source is 75.5014Gy / min is taken out when the absorbed radiation dose is 7.210kGy, and a transparent gel-like acrylate polymer is obtained, which is sealed at low temperature and protected from light for future use.

[0058] Put the transparent gel-like acrylate polymer into a device with a designed shape, and dry it to constant weight at about 100°C (while recovering the solvent), to obtain the acrylate polymer super oil-absorbing resin of the present invention. After testing, the saturated...

Embodiment 2

[0060] 1) formula (in parts by weight):

[0061]

[0062] 2) Preparation:

[0063] Add the ingredients according to the above formula, add them to the irradiation device with stirring, reflux condensation, temperature control, nitrogen gas flow and the ability to uncover the top cover, stir at a speed of 80 rpm for 20 minutes, and seal after 25 minutes with high-purity nitrogen; put into a 60 The position where the absorbed dose rate of the Co radiation source is 100.1975Gy / min is taken out when the absorbed radiation dose is 2.988kGy, and a transparent gel-like acrylate polymer is obtained, which is sealed at low temperature and protected from light for future use.

[0064] Put the above-mentioned transparent gel-like acrylate polymer into a device with a designed shape, and vacuum-dry to constant weight (while recovering the solvent) to obtain the acrylate polymer super oil-absorbing resin of the present invention. After testing: the saturated oil absorption (g / g) of th...

Embodiment 3

[0066] 1) formula (in parts by weight):

[0067]

[0068] 2) Preparation:

[0069] Add the ingredients according to the above formula ratio into the reaction device with stirring, reflux condensation, temperature control, nitrogen gas flow and the ability to uncover the upper cover, stir at a speed of 80 rpm for 15 minutes, and pass high-purity nitrogen gas for 20 minutes. 60 The position where the absorbed dose rate of the Co radiation source is 20.2306Gy / min is taken out when the controlled radiation absorbed dose is 14.570kGy. A transparent gel-like polyacrylate is obtained, and the product is sealed at low temperature and protected from light for future use.

[0070] The preparation of the oil-absorbing resin is to put the product into a device with a designed shape, and dry it to a constant weight at about 80° C. (while recovering the solvent), so as to obtain the acrylate polymer super oil-absorbing resin of the present invention.

[0071] The saturated oil absorpti...

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Abstract

The invention relates to acrylate polymer high oil absorption resin and a preparation method and application thereof. The oil absorption resin comprises the following components in part by weight: 50 to 95 parts of flexible chain segment monomer, 5 to 50 parts of rigid chain segment monomer, a cross-linking agent in an amount which is 0.2 to 5 percent of the total weight of the monomers, and a solvent in an amount which is 1.5 to 4 times the total weight of the monomers. The high oil absorption resin is prepared by free radical solution polymerization at room temperature under the initiation of gamma rays. The preparation process is simple, the reaction condition is easy to control, energy consumption is saved, and the method is safe and environmental-friendly and is more suitable for industrial production. The prepared high oil absorption resin has the advantages of high purity, complete hydrophobicity, wide application range, capacity of absorbing multiple types of oil, high oil absorption multiplying power, high oil retention performance, recyclability and the like, and can be widely applied to the absorption of floating oil on the sea surface, scattered oil, cooled emulsified oil on lathes of factories, and oil and organic substances in industrial production and domestic sewage.

Description

technical field [0001] The invention relates to an oil-absorbing material and its preparation method and use, in particular to an acrylate polymer super oil-absorbing resin and its preparation method and use. Background technique [0002] High Oil-Absorbable Resin (HOAR for short) is a polymer with a moderately cross-linked three-dimensional network structure. Its oil-absorbing driving force is the mutual affinity between the lipophilic group of the resin and the oil molecule. The oil-absorbing process is The swelling and stretching process of the cross-linked three-dimensional network structure. This kind of resin has the advantages of strong oil absorption capacity and good oil retention performance, and can be used for the treatment of various oil pollution systems. As an environmentally friendly material, it is widely used in industry, agriculture, daily life and other fields. [0003] The progress of oil-absorbing materials can be divided into three types in terms of ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F220/18C08F212/08C08F218/08C08F220/44C08F2/46C02F1/28
CPCB01J20/261C08F220/10C09K3/32B01J20/267
Inventor 方月娥何向阳唐刚
Owner SHANGHAI FINETAC PRECISION TECH CO LTD
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